MATERIAL SAFETY DATA SHEET
Section I
Company Name: Future Graphics, LLC.
Address: 1175 Aviation Place
City,State,Zip Code: San Fernando, CA 91340
Phone for Information: 818 / 837-8100
EMERGENCY CONTACT: FUTURE GRAPHICS 818 / 837-8100, 800 / 394-9900
Product Code: EXPANDFOAM
Description: SEALANT REFILL HP42/4300
Date Revised: 7/23/2004
Product Type: Urethane resin system
Section II: HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
Hazardous Components CAS # OSHA PEL ACGIH TLV % ( Optional )
Polyol Prepolymer Mixture N/A N/A
4,4' Diphenylmethane Dilsocyanate (MDI) 00101-68-8 20ppb 5ppb
MDI Isomers and Homologues 09016-87-9 N/A N/A
1,1,1,2 Tetrafluoroethane 00811-97-2 N/A N/A
Isobutane 00075-28-5 N/A N/A
Dimethyl Ether 00115-10-6 N/A N/A
This product contains 10-25% 4,4' Diphenylmethane Dilsocyanate which is subject to reporting under Section 313 of SARA Title III(40 CFR Part372)
Section III: PHYSICAL / CHEMICAL CHARACTERISTICS
Boiling Point (C): Not determined.
Specific Gravity (Water = 1): 1.1
Vapor Pressure (mm HG): 72 psi @ 68F
Vapor Density (Air = 1): >1 (MDI Polymer)
Evaporation Rate (Ether =1): <0.1
Solubility in Water: Not soluble.
Appearance & Odor: Dark brown liquid, mild odor.
Section IV: FIRE & EXPLOSION HAZARD DATA
Flash Point: 40F (propellants)
Flammable Limits: 3.4-6%
Extinguishing Media: Carbon dioxide, dry chemical, foam.
Special Fire Fighting Procedures: Isocyanates are not compatible with water.
Unusual Fire and Explosion Hazards: Extremely flammable. Contains flammable propellants under pressure. Aerosol
cans exposed to fire or direct heat can rupture from pressure build-up and be
propelled through the air. CAUTION: Do not heat cold cans with a torch or flame
to raise temperature. This may cause the can to burst.
Section V: REACTIVITY DATA
Stability: Reacts (i.e. expands at a ratio of >40:1 to form a polyurethane foam) upon
contact with air. Contact with moisture or water will also cause material to
polymerize (non-violently).
Conditions to Avoid: Temperature extremes will shorten product shelf life; i.e. below 40F/ above 100F.
Contact with air. Contact with moisture or water will also cause material to
polymerize (non-violently).
Incompatibility (Materials to Avoid): Alcohols, strong bases, alkali metal compounds. Reacts with water (non-violently).
Hazardous Decomposition or Byproducts: CO, CO2, CN, Isocyanates, NOx, Cl, POx
Hazardous Polymerization: Will Occur: Will Not Occur: X
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MATERIAL SAFETY DATA SHEET
From page1, Section I
Company Name: Future Graphics, LLC.
Address: 1175 Aviation Place
City,State,Zip Code: San Fernando, CA 91340
Phone for Information: 818 / 837-8100
EMERGENCY CONTACT: FUTURE GRAPHICS 818 / 837-8100, 800 / 394-9900
Product Code: EXPANDFOAM
Description: SEALANT REFILL HP42/4300
Date Revised: 7/23/2004
Product Type: Urethane resin system
Section VI: HEALTH HAZARD DATA
Routes of Entry: Eye/skin: May cause irritation.
Inhalation: May cause irritation.
Ingestion: May cause gastrointestinal irritation, vomiting, nausea and diarrhea.
Health Hazards (Acute or Chronic): Sensitization.
Carcinogenicity: Not recognized as a carcinogen by the IRAC, NTP, or OSHA.
Signs or Symptoms of Exposure: Eyes: can adhere to cornea. Skin: can adhere to the skin. Inhalation: vapor
generated when heated to temperature >100F can cause irritation of the breathing
tract. Some individuals can develop an allergic (asthmatic-like) response. Should
this occur, immediately move to fresh air. Those individuals who develop an
allergic reaction should avoid future use of this product. Ingestion: effects of
ingestion have not been determined. Not a likely route of exposure.
Medical Conditions Aggravated by Exposure: Eye, skin and respiratory conditions.
EMERGENCY AND FIRST AID PROCEDURES:
EYES: Flush eyes thoroughly with water. Seek medical attention if irritation persists.
INHALATION: Remove victim to fresh air.
SKIN: Wash contaminated areas with soap and water.
INGESTION: Do NOT induce vomiting. Call doctor and contact local poison control center
immediately.
Section VII: PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to be Taken in Case Material is Released: Wear appropriate personal protective equipment. EXPANDFOAM will polymerize upon
contact with air/moisture. Allow product to cure, then remove for disposal.
Waste Disposal Method: Dispose of in accordance with federal, state, and local regulations.
Precautions to be Taken in Handling or Storage: Avoid contact. Material will adhere to eyes and skin. Contents under pressure.
Extremely flammable. Do not apply direct heat to the cans. Before using, remove
ignition sources. Store in a cool dry place. Do not store in direct sunlight. Keep from
freezing. Store between 40F and 100F. Always wash thoroughly after handling
chemical products. For industrial use only. Keep out of reach of children. Follow
label/use instructions. Storage classification: NFPA=Level 2; OSHA=Class 1A.
Section VIII: CONTROL MEASURES
Respiratory Protection: None required.
Ventilation: Local: General.
Mechanical: Acceptable
Special: No Data
Protective Gloves: Cotton gloves are suitable.
Eye Protection: Goggles or safety glasses with side shields.
Work / Hygienic Practices: Avoid contamination of food, drink, etc. No smoking when handling.
SPECIAL INSTRUCTIONS
This information is believed to be true and accurate. It represents the best information currently available to us. We make no warranty , expressed or implied with regard to
such information. We make no liability resulting from its use. Users should make their own investigations to determine the suitability for their particular purposes.
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