MATERIAL SAFETY DATA SHEET
26/36 FungicideTM Page 1 of 4
Please read the entire document. This Material Safety Data Sheet contains important environmental,
health and toxicology information for your employees, and anyone who will use, transport, store,
dispose of or handle this product. Please make sure this information is given to them. It also contains
information to help you meet community right-to-know/emergency response reporting requirements
under SARA Title III and many other laws. If you resell this product, this MSDS must be given to the
buyer or the information contained herein must be incorporated in your MSDS.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 26/36 Fungicide
EPA REGISTRATION NUMBER(S): 432-1414-1001
CHEMICAL NAME: Iprodione and Thiophanate-methyl
PRODUCT USE: A Fungicide for the prevention and control of certain diseases
of turfgrass and ornamentals.
EMERGENCY TELEPHONE NUMBERS
COMPANY
CLEARY CHEMICAL CORP. PROSAR:
Cleary Chemical M-F 9-5 EST (800) 324-7598
178 Ridge Road, Suite A (800) 524-1662 OR CHEMTREC 24 HOUR:
Dayton, New Jersey 08810 (732) 329-8399 (800) 424-9300
SECTION 2: INFORMATION ON INGREDIENTS
Active Ingredient(s)/ % by Wt. CAS# ACGIH OSHA
Hazardous Inert Ingredient(s) TLV PEL
Iprodione 19.65 36734-19-7 NA NA
Thiophanate-methyl 19.65 23564-05-8 NA NA
SECTION 3: HEALTH HAZARD INFORMATION
Routes of Exposure: Inhalation, Ingestion, Eye Contact, Skin Absorption
Ingestion: Harmful if swallowed. Do not take internally.
Eye: Cause substantial but temporary eye injury. May cause eye irritation. Do not get in eyes.
Skin: Harmful if absorbed through skin. Avoid contact with skin and clothing.
Inhalation: Harmful if inhaled. Avoid breathing spray mist.
SECTION 4: FIRST AID MEASURES
General: Have the product container or label with you when calling a poison control center or doctor or
going for treatment.
Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a
glass of water if able to swallow. DO NOT induce vomiting unless directed to do so by a physician or
poison control center. Never give anything by mouth to an unconscious person.
Eye: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if pres-
ent, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
continued on next page
Document Number: 6.20.05 Issue Date: 3.18.05
NDA = No Data Available NA = Not Applicable
26/36 FungicideTM Page 2 of 4
SECTION 4: FIRST AID MEASURES (continued from page 1)
Skin: Take off all contaminated clothing immediately. Rinse immediately with plenty of water for at least
15 minutes. Call a poison control center or doctor for treatment advice.
Inhalation: Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respira-
tion, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.
NOTES TO PHYSICIAN
Hazards: May pose an aspiration pneumonia hazard. Contains petroleum distillates.
Treatment: There is no specific antidote. Appropriate supportive and symptomatic treatment as indicted
by the patient's condition is recommended.
SECTION 5: FIRE AND EXPLOSION INFORMATION
Flash Point & Method: >93.3癈/>199.9癋; Method: Setaflash
Suitable Extinguishing Media: water spray, foam, carbon dioxide (CO2), dry chemical
Special Fire Fighting Procedures: Keep out of smoke. Fight fire from upwind position. Cool closed
containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or
water courses. Equipment or materials involved in pesticide fires may become contaminated.
Wear self-contained breathing apparatus and protective suit.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled
product or contaminated surfaces.
Methods for Cleaning Up: Take up with absorbent material (e.g. sand, earth or a proprietary
absorbent material). Keep in suitable, closed containers for disposal. Clean contaminated floors and
objects thoroughly with water and detergents, observing environmental regulations.
Additional Advice: Use personal protective equipment. Avoid breathing vapors and avoid skin contact.
Do not allow material to enter streams, sewers, or other waterways.
SECTION 7: HANDLING AND STORAGE
Handling Procedures: Handle and open container in a manner as to prevent spillage.
Storing Procedures: Do not contaminate water, food, or feed by storage or disposal. Store in a cool,
dry place and in such a manner to prevent cross contamination with other pesticides, fertilizers, food,
and feed. Store in original container and out of the reach of children, preferably in a locked storage area.
Work/Hygienic Procedures: Wash hands before eating, drinking, chewing gum, using tobacco or using
the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean
clothing. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before
removing gloves clean them with soap and water. As soon as practical, wash thoroughly and change
into clean clothing.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Maintain exposure levels below the exposure limit through the use of general
and local exhaust ventilation.
Eye/Face Protections: Wear tightly fitting safety goggles.
Hand Protection: Chemical resistant gloves.
Body Protection: Wear long-sleeved shirt and long pants and shoes plus socks.
Respiratory Protection: When respirators are required, select NIOSH approved equipment based on
actual or potential airborne concentrations and in accordance with the appropriate regulatory standards
and/or Industry recommendations.
General Protection: Follow all label instructions. Educate and train employees in safe use of the product.
Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables,
use detergent and hot water. Keep and wash PPE separately from other laundry.
Exposure Limits:
1,2-Propanediol 57-55-6
WEEL TWA 50 ppm Form of Exposure: Total vapor and aerosol.
WEEL TWA 10 mg/m3 Form of Exposure: Aerosol.
Document Number: 6.20.05 Issue Date: 3.18.05
NDA = No Data Available NA = Not Applicable
26/36 FungicideTM Page 3 of 3
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: opaque beige
Physical State: liquid, viscous
pH: 6.9 at 25癈; Aqueous suspension
Density: 1/17 g/ml
Bulk Density: 9.74 lbs/gal
SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: Stable under normal conditions.
Incompatibility: strong acids and strong bases; strong oxidizing agents
Hazardous: Thermal decomposition
Decomposition Products: hydrogen chloride (HCI); nitrogen oxides (NOx)
SECTION 11: TOXICOLOGICAL INFORMATION
Only acute toxicity studies have been conducted on this product as formulated. The non-acute informa-
tion pertains to the technical-grade active ingredients, iprodione and thiophanate methyl.
Acute Oral Toxicity: male/female rat: LD50: >5,000 mg/kg
Acute Dermal Toxicity: male/female rat: LD50: >5,000 mg/kg
Acute Inhalation Toxicity: male/female rat: LD50: >2.01 mg/l
Exposure time: 4 h
Determined in the form of liquid aerosol.
Maximum attainable concentration.
No deaths
male/female rat: LC50: >8.04 mg/l
Exposure time: 1h
Determined in the form of liquid aerosol.
Extrapolated from the 4 hr LC50.
Skin Irritation: rabbit: Slight irritation
Eye Irritation: rabbit: Moderate eye irritation
Sensitization: guinea pig: Non-sensitizing
Chronic Toxicity: Iprodione caused effects in the liver, adrenal, ovary, and testes in chronic feeding
studies. Thiophanate methyl caused mild anemia and effects in liver and thyroid in chronic feeding stud-
ies. In addition, transient neurological effects (tremors) were observed in dogs.
Assessment Carcinogenicity: Iprodione produced benign testicular tumors in rats and benign liver
and ovary tumors in mice when tested at a maximum tolerated dose. Thiophanate methyl produced
benign liver tumors in mice and thyroid tumors in rats.
ACGIH: None; NTP: None; IARC: None; OSHA: None
Reproductive & Developmental Toxicity: REPRODUCTION: Neither iprodione nor thiophanate
methyl caused reproductive toxicity in multi-generation studies in rats.
DEVELOPMENTAL TOXICITY: Neither iprodione nor thiophanate methyl are primary developmental toxicants
as only minor delays or variations in fetal development were observed only at doses that caused maternal toxicity.
Neurotoxicity: Iprodione is not considered to be a neurotoxicant. No results of specific neurotoxicity
testing are available for thiophanate methyl.
Mutagenicity: Based on the overall weight of evidence, neither iprodione nor thiophanate methyl were
genotoxic in a battery of in vitro and in vivo studies.
SECTION 12: ECOLOGICAL INFORMATION
Environmental Precautions: This product is toxic to invertebrates. Do not apply directly to water, to
areas where surface water is present or to intertidal areas below the mean high water mark. Drift and
runoff from treated areas may be hazardous to fish/aquatic organisms in adjacent sites. Do not contaminate
surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water.
Document Number: 6.20.05 Issue Date: 3.18.05
NDA = No Data Available NA = Not Applicable
26/36 FungicideTM Page 4 of 4
SECTION 13: DISPOSAL CONSIDERATIONS
Pesticide Disposal: Pesticide Disposal: Wastes resulting from the use of this product may be disposed
f on site or at an approved waste disposal facility.
Container Disposal: Triple rinse containers. Puncture container to avoid re-use. Then dispose of empty
container in a sanitary landfill or by incineration, or, if allowed by State and local authorities, by burning.
If burned, stay out of smoke.
RCRA Classification: 23564-05-8 Thiophanate-methyl - US. EPA Resource Conservation and
Recovery Act (RCRA) Composite List of Hazardous Wastes and Appendix VIII Hazardous Constituents
(40 CFR 261): U409
23564-05-8 Thiophanate-methyl - US. EPA Resource Conservation and
Recovery Act (RCRA) U List of Hazardous Wastes (40 CFR 261.33(f) and 40 CFR 302 [CERCLA]): U409
SECTION 14: TRANSPORTATION INFORMATION
Transportation Classification: Not regulated for all modes of Transportation
Freight Classification: Insecticides or Fungicides, N.O.I.; other than poison
SECTION 15: REGULATORY INFORMATION
US Federal Regulations:
TSCA list; None.
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707,
Subpt D): None.
SARA Title III - Section 302 - Notification and Information: None
SARA Title III - Section 313 - Toxic Chemical Release Reporting:
Thiophanate-methyl 23564-05-8 1.0%
US States Regulatory Reporting
CA Prop65:
This product contains a chemical known to the State of California to cause cancer.
Iprodione 36734-19-7
This product contains a chemical known to the State of California to cause birth defects or other
reproductive harm. Thiophanate-methyl 23564-05-8 Female reproductive toxin.
Thiophanate-methyl 23564-05-8 Male reproductive toxin.
US State Right-To-Know Ingredients: Thiophanate-methyl 23564-05-8 NJ
Canadian Regulations
Canadian Domestic Substance List: Thiophanate-methyl 23564-05-8
Environmental
CERCLA: Thiophanate-methyl 23564-05-8 1 lbs
Clean Water Section 307 Priority Pollutant: None
Safe Drinking Water Act Maximum Contaminant Levels: None
International Regulations
European Inventory of Existing Commercial Substances (EINECS): Iprodione 36734-19-7
Thiophanate-methyl 23564-05-8
SECTION 16: OTHER INFORMATION
NFPA: Health=2, Fire=1, Reactivity=1, Others=none
0=minimal hazard, 1=slight hazard, 2=moderate hazard, 3=severe hazard, 4=extreme hazard
Please note: Cleary Chemical Corp. believes that the information and recommendations contained here-
in are accurate as of the date hereof. The information provided herein applies only to the specific prod-
uct designated and may not be valid where said product is used in combination with any other material
or in any process. It is the users responsibility to determine the suitability of the information for their pur-
poses. No warranty of fitness for any particular purpose, warranty of merchantability, or any other war-
ranty, expresser or implied, is made concerning the information provided.
Reason for issue: New MSDS for initial product registration Effective date: 3.18.05
Prepared by: Bayer Corp. Replaces: NA
Document Number: 6.20.05 Issue Date: 3.18.05
NDA = No Data Available NA = Not Applicable
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