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Material Safety Data Sheet MSDS# J00530610_05262005
Section 1. Chemical Product and Company Identification
JACAAB-ETHOMEEN C/15
Product name
: Surfactant.
Material Uses In Case of Emergency
Jacaab LLC CHEMTREC: 800-424-9300
Supplier/
4155 Manchester Avenue
Manufacturer
St. Louis, MO 63110
Information: 314-533-4662
Section 2. Composition, Information on Ingredients
Name CAS # % by Weight
Amines, coco alkyl, ethoxylated 61791-14-8 98-100
Amines, coco alkyl 61788-46-3 0.001-2
Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy- 25322-68-3 0.001-2
Section 3. Hazards Identification
Liquid.
Physical State
Colorless to light yellow.
Color
Amine like.
Odor
DANGER!
Emergency Overview
CAUSES EYE BURNS.
VERY TOXIC TO AQUATIC ORGANISMS.
CAUSES SEVERE SKIN IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
Do not get in eyes. Do not ingest. Avoid breathing vapor or mist. Avoid contact with skin and clothing.
Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid
contact of spilled material and runoff with soil and surface waterways.
Amines, coco alkyl, ethoxylated: IARC, NTP, OSHA, ACGIH: Not listed.
Possible Carcinogenic
Amines, coco alkyl: IARC, NTP, OSHA, ACGIH: Not listed.
Effects
Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-: IARC, NTP, OSHA, ACGIH: Not listed.
Absorbed through skin. Eye contact.
Routes of Entry
See Toxicological Information (section 11)
Section 4. First Aid Measures
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
Eye Contact
water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
Skin Contact
contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly
clean shoes before reuse. Get medical attention immediately.
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ETHOMEEN C/15
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
Inhalation
oxygen. Get medical attention.
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth
Ingestion
to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin
Medical Conditions
irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading
Aggravated by
to frequent attacks of bronchial infection.
Overexposure
Section 5. Fire Fighting Measures
May be combustible at high temperature.
Flammability of the
Product
The lowest known value is >150癈 (302癋) (Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-).
Auto-ignition
Temperature
Closed cup: >100癈 (212癋).
Flash Points
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Products of Combustion
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
Be sure to use an approved/certified respirator or equivalent.
Protective Clothing (Fire)
Section 6. Accidental Release Measures
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste
Small Spill and Leak
disposal container. If necessary: Use suitable protective equipment (Section 8). Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get
Large Spill and Leak
water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift.
Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.
Call for assistance on disposal. Use suitable protective equipment (Section 8). Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the sanitary system.
Section 7. Handling and Storage
Do not ingest. Avoid breathing vapors or spray mists. Avoid contact with skin and clothing. Do not get in
Handling
eyes. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling.
Avoid contact of spilled material and runoff with soil and surface waterways.
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Section 8. Exposure Controls, Personal Protection
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors
Engineering Controls
below their respective occupational exposure limits. Ensure that eyewash stations and safety showers
are proximal to the work-station location.
Personal Protection
Face shield.
Eyes
Full suit.
Body
Wear appropriate respirator when ventilation is inadequate.
Respiratory
Gloves.
Hands
Boots.
Feet
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ETHOMEEN C/15
-
Protective Clothing
(Pictograms)
Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult
Personal Protection in
a specialist BEFORE handling this product.
Case of a Large Spill
Ingredient Name Exposure Limits United States
Amines, coco alkyl, ethoxylated Not available.
Amines, coco alkyl Not available.
Poly(oxy-1,2-ethanediyl), Not available.
a-hydroxy-w-hydroxy-
Section 9. Physical and Chemical Properties
Liquid.
Physical State
Colorless to light yellow.
Color
Amine like.
Odor
Not applicable.
Molecular Weight
Not applicable.
Molecular Formula
Basic.
pH
>300癈 (572癋)
Boiling/Condensation
Point
-9癈 (15.8癋)
Melting/Freezing Point
-1oC
Cloud Point
-7oC
Pour Point
0.976 g/cm3 (25癈 / 77癋)
Density
<0.01 kPa (<0.1 mmHg) (at 20癈)
Vapor Pressure
The highest known value is >10 (Air = 1) (Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-).
Vapor Density
Weighted average: 0.89compared to Butyl acetate.
Evaporation Rate
Partially soluble in cold water.
Solubility
Dispersion Properties
Viscosity = 150cp @ 20oC.
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Reactive with oxidizing agents, acids.
Incompatibility with
Various Substances
Will not occur.
Hazardous
Polymerization
Section 11. Toxicological Information
Toxicity to Animals
Ingredient Name or Product Test Result Route Species
name
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JACAAB-ETHOMEENC/15
ETHOMEEN?C/15 LD50 750 mg/kg Oral Rat
Amines, coco alkyl, ethoxylated LD50 >200 mg/kg Oral Rat based on data for:
(similar material)
Amines, coco alkyl LD50 1300 mg/kg Oral Rat
LD50 >2000 mg/kg Dermal Rabbit
Poly(oxy-1,2-ethanediyl), LD50 28000 mg/kg Oral Rat
a-hydroxy-w-hydroxy- LD50 31000 mg/kg Oral Mouse
LD50 14000 mg/kg Oral Rabbit
LD50 >20000 mg/kg Dermal Rabbit
Amines, coco alkyl: INHALATION LC50 > 0.099 mg/L, 1 hour(s) Rat
Special Remarks on
Toxicity to Animals
Severely irritating to the skin. Practically non-toxic in contact with skin.
Acute Effects Skin
Corrosive to the eyes.
Acute Effects Eyes
:
Special Remarks on
Other Toxic Effects on
Humans
Section 12. Ecological Information
Ecotoxicity
Ingredient Name or Product name Species Period Result
ETHOMEEN?C/15 daphnia (EC50) 48 hours 1.41 mg/l
Zebrafish (LC50) 96 hours 0.66 mg/l
Amines, coco alkyl daphnia based on data for: 48 hours 0.032 mg/l
(similar material) (EC50)
Poly(oxy-1,2-ethanediyl), Daphnia (EC50) 48 hours >10000 mg/l
a-hydroxy-w-hydroxy- Fish (LC50) 24 hours >5000 mg/l
Biodegradability and 28% @ 28 day(s); 67% @ 214 day(s) CBT based on data for: (similar material)
Ecotoxicity Remarks
Inherently biodegradable.
Biodegradable/OECD
These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2...).
Products of Degradation
Section 13. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control
Waste Information
regulations.
Consult your local or regional authorities.
Section 14. Transport Information
Regulatory UN Proper shipping name Class Packing Label Additional information
Information number Group
Not - - -
DOT
Classification regulated.
-
Not - - -
TDG
Classification regulated.
-
-
Not - -
IMDG Class
regulated.
-
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JACAAB-ETHOMEEN C/15
Not -
- -
IATA-DGR
regulated.
Class
-
Section 15. Regulatory Information
Irritating material
HCS Classification
TSCA: All intentionally present components are listed on the TSCA inventory.
U.S. Federal Regulations
DSL: All intentionally present components are listed on the DSL.
CERCLA: Hazardous substances.: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
SARA 313 Form R Reporting Requirements
No products were found.
SARA 313 Supplier Notification
No products were found.
No products were found.
State Regulations
California prop. 65: No products were found.
Class D-2B: Material causing other toxic effects (TOXIC).
WHMIS (Canada)
CEPA DSL: Amines, coco alkyl, ethoxylated; Amines, coco alkyl; Poly(oxy-1,2-ethanediyl),
a-hydroxy-w-hydroxy-
Component EC Number EC Status EC Annex
European Union Amines, coco alkyl, ethoxylated Not available. Not available. Not available.
Amines, coco alkyl 262-977-1 Not available. Not available.
Poly(oxy-1,2-ethanediyl), Not available. Not available. Not available.
a-hydroxy-w-hydroxy-
Australia (NICNAS): Amines, coco alkyl, ethoxylated; Amines, coco alkyl; Poly(oxy-1,2-ethanediyl),
Other International Lists
a-hydroxy-w-hydroxy-
Japan (MITI): Amines, coco alkyl; Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-
Korea (TCCL): Amines, coco alkyl, ethoxylated; Amines, coco alkyl; Poly(oxy-1,2-ethanediyl),
a-hydroxy-w-hydroxy-
Philippines (RA6969): Amines, coco alkyl, ethoxylated; Amines, coco alkyl; Poly(oxy-1,2-ethanediyl),
a-hydroxy-w-hydroxy-
Section 16. Other Information
Hazardous Material 3 National Fire
Health
Fire Hazard
1
Information System Protection
1
Fire Hazard
3 0
Health Reactivity
(U.S.A.) Association
0
Reactivity
(U.S.A.) Specific Hazard
Personal Protection
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JACAAB-ETHOMEEN C/15
Validation date: 05/26/2005
Phone Number 314-533-4662
Notice to Reader
The information in the material safety data sheet should be provided to all who will use, handle, store, transport or otherwise be exposed
to this product. All information concerning this product and/or suggestions for handling and use contained herein are offered in good
faith and are believed to be reliable as of the date of publication. However, no warranty is made as to the accuracy of and/or sufficiency of
such information and/or suggestions or as to the product's merchantability or fitness for any particular purpose, or that any suggested
use will not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent. Buyer
must determine for himself, by preliminary tests or otherwise, the suitability of this product for his purposes, including mixing with other
products. The information contained herein supersedes all previously issued bulletins on the subject matter covered. If the date on this
document is more than three years old, call to make certain that this sheet is current.
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