Page 1 of 6
MATERIAL SAFETY DATA SHEET CND-N-014
Prepared to OSHA, ACC, ANSI and WHMIS Standards MSDS Revision Date 11/01/2002
1. PRODUCT IDENTIFICATION
1.1 Product Name:
MASSAGE SILK
1.2 Chemical Name:
BUTYLENE GYCOL SOLUTION
1.3 Synonyms:
1.4 Trade Names:
1.5 Product Use:
COSMETIC USE ONLY
1.6 Manufacturer's Name:
CREATIVE NAIL DESIGN, INC.
1.7 Manufacturer's Address:
1125 JOSHUA WAY, VISTA, CA 92083
1.8 Emergency Phone:
ROCKY MOUNTAIN POISON CONTROL CENTER: 1-303-623-5716
1.9 Business Phone:
1-800-833-NAIL (6245)
2. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR
ACGIH OSHA OTHER
TLV STEL PEL STEL IDLH
CHEMICAL NAME(S) CAS NO. % ppm ppm ppm ppm ppm
107-88-0 50 - 60 NE NE NE NE NE
BUTYLENE GLYCOL
25322-68-3 < 40.0 NE NE NE NE NE
PEG-8
NA < 2.0 NE NE NE NE NE
FRAGRANCE
143-28-2 < 1.0 NE NE NE NE NE
OLEYL ALCOHOL
NA = Not Available; ND = Not Determined; NE = Not Established; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-1998 format.
Page 2 of 6
MATERIAL SAFETY DATA SHEET CND-N-014
Prepared to OSHA, ACC, ANSI and WHMIS Standards MSDS Revision Date 11/01/2002
3. HAZARD IDENTIFICATION
3.1 Hazard Identification:
NO NO YES
Inhalation: Absorption: Ingestion:
3.2 Routes of Entry:
3.3 Effects of Exposure:
INGESTION: If product is swallowed, may cause nausea, vomiting and/or diarrhea.
SKIN & EYES: Slightly irritating to the eyes. May be irritating to skin in some sensitive individuals, especially after prolonged contact.
INHALATION: Inhalation is unlikely, however, vapors of this product may be slightly irritating to some sensitive individuals.
3.4 Symptoms of Overexposure:
Symptoms of overexposure may include redness, itching, and irritation.
3.5 Acute Health Effects:
Redness, itching, and irritation of skin at the site of contact for some sensitive individuals.
3.6 Chronic Health Effects:
No chronic health effects are known, although symptoms and discomfort may occur for several days following overexposure
following ingestion.
3.7 Target Organs:
Eyes, skin and respiratory system.
4. FIRST AID MEASURES
4.1 First Aid:
INGESTION: If ingested, do not induce vomiting. Drink plenty of water or milk IMMEDIATELY. If the patient is vomiting, continue to
offer plenty of water or milk. Never give water or milk to an unconscious person. Contact Rocky Mountain Poison
Control at 1-303-623-5716 or the nearest Poison Control Center or local emergency number. Provide an estimate of
the time and amount of the substance that was swallowed.
EYES: Immediately flush eyes with plenty of lukewarm water for an extended time, not less than fifteen minutes. Flush longer
if there is any indication of residual chemical in the eye. Ensure adequate flushing by separating the eyelid(s) with
fingers and roll eyes in a circular motion. If problem persists, seek medical attention.
SKIN: If redness, dryness or other signs of irritation to the skin develop, wash affected skin areas with plenty of warm water
and soap. Remove contaminated clothing and wash thoroughly before reuse. If irritation persists, consult a physician.
INHALATION: Remove victim to fresh air at once. If breathing has stopped, administer artificial respiration. Seek immediate medical
attention.
HEALTH 1
4.2 Medical Conditions Aggravated by Exposure:
Individuals with pre-existing skin disorders, eye problems, or impaired respiratory
FLAMMABILITY 1
function may be more susceptible to the effects. None known.
REACTIVITY 0
PROTECTIVE EQUIPMENT
Page 3 of 6
MATERIAL SAFETY DATA SHEET CND-N-014
Prepared to OSHA, ACC, ANSI and WHMIS Standards MSDS Revision Date 11/01/2002
5. FIREFIGHTING MEASURES
5.1 Flashpoint & Method:
Non-flammable.
5.2 Autoignition Temperature:
NA
Lower Explosive Limit (LEL): NA Upper Explosive Limit (UEL): NA
5.3 Flammability Limits:
5.4 Fire & Explosion Hazards:
RED = FLAMMABILITY
This product is non-flammable. BLUE = HEALTH
1 YELLOW = REACTIVITY
5.5 Extinguishing Methods:
WHITE = SPECIAL MEASURES
Water, Foam, CO2 and Dry Chemical
1 0 0 = NO HAZARD
5.6 Firefighting Procedures:
1 = MINIMAL HAZARD
NA. 2= SLIGHT HAZARD
3 = MODERATE HAZARD
4 = SEVERE HAZARD
6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment.
For small spills (e.g., <1 gallon) wear appropriate personal protective equipment (e.g., goggles, gloves). Maximize ventilation (open doors and windows)
and secure all sources of ignition. Remove spilled material with absorbent material and place into appropriate closed container(s) for disposal. Dispose
of properly in accordance with local, state and federal regulations. Wash all affected areas and outside of container with plenty of warm water and
soap. Remove any contaminated clothing and wash thoroughly before reuse.
For spills 1 gallon, deny entry to all unprotected individuals. Dike and contain spill with inert material (e.g., sand or earth). Use ONLY non-sparking tools
for recovery and cleanup. Transfer liquid to containers for recovery or disposal and solid diking material to separate containers for proper disposal.
Remove contaminated clothing promptly and wash affected skin areas with soap and water. Keep spills and cleaning runoffs out of municipal sewers
and open bodies of water.
7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Avoid eye contact. Wash all affected areas thoroughly with soap and warm water after use.
7.2 Storage & Handling:
Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans). Keep away from excessive heat, open
flames, sparks, and other possible sources of ignition. Do not store in damaged or unmarked containers or storage devices. Keep
containers securely closed when not in use. Open slowly on a level, stable surface.
7.3 Special Precautions:
Spilled material may present a slipping hazard if left unattended. Clean all spills promptly.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Ventilation & Engineering Controls:
General mechanical (e.g., local exhaust ventilation, fans) or natural ventilation is sufficient when this product is in use.
8.2 Respiratory Protection:
If handled at elevated temperature or under mist conditions, NIOSH/MSHA approved respiratory protection equipment should be
used. None required if used in a well-ventilated area.
8.3 Eye Protection:
Avoid eye contact. None required under normal conditions of use. However, may cause irritation in some sensitive individuals.
When handling large quantities (e.g., 1 gallon), safety glasses with side shields should be used.
8.4 Hand Protection:
None required under normal conditions of use. However, may cause skin irritation in some sensitive individuals.
When handling large quantities (e.g., 1 gallon), wear rubber or plastic impervious gloves.
8.5 Body Protection:
No apron required when handling small quantities.
When handling large quantities (e.g., 1 gallon), eye wash stations and deluge showers should be available. Upon completion of
work activities involving large quantities of this product, wash any exposed areas thoroughly with soap and water.
Page 4 of 6
MATERIAL SAFETY DATA SHEET CND-N-014
Prepared to OSHA, ACC, ANSI and WHMIS Standards MSDS Revision Date 11/01/2002
9. PHYSICAL & CHEMICAL PROPERTIES
ND
9.1 Density:
ND
9.2 Boiling Point:
ND
9.3 Melting Point:
ND
9.4 Evaporation Rate:
ND
9.5 Vapor Pressure:
ND
9.6 Molecular Weight:
Colorless, viscous hygroscopic liquid with a sweet, flowery odor.
9.7 Appearance & Color:
ND
9.8 Odor Threshold:
Slightly soluble
9.9 Solubility:
ND
9.10 pH
ND
9.11 Viscosity:
NA
9.12 Other Information:
10. STABILITY & REACTIVITY
This product is stable.
10.1 Stability:
Oxides of carbon and nitrogen.
10.2 Hazardous Decomposition Products:
Will not occur.
10.3 Hazardous Polymerization:
Open flames, sparks, high heat and direct sunlight.
10.4 Conditions to Avoid:
None known.
10.5 Incompatible Substances:
11. TOXICOLOGICAL INFORMATION
This product has not been tested on animals to obtain toxicological data. There are toxicology data
11.1 Toxicity Data:
for the components of this product, which are found in the scientific literature. These data have not
been presented in this document.
See Section 3.5
11.2 Acute Toxicity:
See Section 3.6
11.3 Chronic Toxicity:
NE
11.4 Suspected Carcinogen:
None
11.5 Reproductive Toxicity:
This product is not reported to produce mutagenic effects in humans.
Mutagenicity:
This product is not reported to produce embryotoxic effects in humans.
Embryotoxicity:
This product is not reported to produce teratogenic effects in humans.
Teratogenicity:
This product is not reported to produce reproductive effects in humans.
Reproductive Toxicity:
See Section 3.3
11.6 Irritancy of Product:
NE
11.7 Biological Exposure Indices:
Treat symptomatically.
11.8 Physician Recommendations:
12. ECOLOGICAL INFORMATION
This product will slowly volatile from soil. Components of this product will slowly decompose into
12.1 Environmental Stability:
organic compounds.
There is no specific data available for this product.
12.2 Effects on Plants & Animals:
There is no specific data available for this product.
12.3 Effects on Aquatic Life:
13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Dispose of in accordance with federal, state or local regulations.
13.2 Special Considerations:
NA
Page 5 of 6
MATERIAL SAFETY DATA SHEET CND-N-014
Prepared to OSHA, ACC, ANSI and WHMIS Standards MSDS Revision Date 11/01/2002
14. TRANSPORTATION INFORMATION
The basic description (proper shipping name, hazard class & division, ID Number, packing group) is shown for each mode of transportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
NOT REGULATED
14.2 IATA (AIR):
NOT REGULATED
14.3 IMDG (OCN):
NOT REGULATED
14.4 TDGR (Canadian GND):
NOT REGULATED
15. REGULATORY INFORMATION
15.1 SARA Reporting Requirements:
Not applicable.
15.2 SARA Threshold Planning Quantity:
Not applicable.
15.3 TSCA Inventory Status:
All chemical substances of this product are listed on the TSCA inventory or are otherwise exempted from inventory status.
15.4 CERCLA Reportable Quantity (RQ):
Not applicable.
15.5 Other Federal Requirements:
NA
15.6 Other Canadian Regulations:
This product has been classified according to the hazard criteria of the CPR and the
MSDS contains all of the information required by the CPR.
15.7 State Regulatory Information:
NA
16. OTHER INFORMATION
16.1 Other Information:
Use only as directed. Avoid eye contact. If contact occurs, flush eye thoroughly with running water for at least 15 minutes. Seek
medical attention. If redness or other signs of adverse reaction occur, discontinue use immediately. If irritation persists, seek medical
attention. KEEP OUT OF REACH OF CHILDREN.
16.2 Terms & Definitions:
See page 6 of this MSDS.
16.3 Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard, 29 CFR ?910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & Creative Nail Design's
knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness
are not guaranteed and no warranties of any type, either expressed or implied, are provided. The information contained herein
relates only to the specific product(s). If this product(s) is combined with other materials, all component properties must be
considered. Data may be changed from time to time. Be sure to consult the latest edition.
16.4 Prepared for:
Creative Nail Design, Inc.
1125 Joshua Way
Vista, CA 92083
800-833-NAIL (6245) phone
760-599-4005 fax
http://www.creativenaildesign.com/
16.5 Prepared by:
ShipMate, Inc.
18436 Hawthorne Blvd., Suite 201
Torrance, CA 90504
310-370-3600 phone
310-370-5700 fax
http://www.shipmate.com/
Page 6 of 6
MATERIAL SAFETY DATA SHEET CND-N-014
Prepared to OSHA, ACC, ANSI and WHMIS Standards MSDS Revision Date 11/01/2002
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies FLAMMABILITY LIMITS IN AIR:
each constituent. Much of the information related to fire and explosion is derived from the
National Fire Protection Association (NFPA). Flash Point ?minimum
EXPOSURE LIMITS IN AIR: temperature at which a liquid gives off sufficient vapors to form an ignitable
ACGIH ?The American Conference on Governmental Industrial Hygienists, a mixture with air. Autoignition Temperature: The minimum temperature
professional association that establishes exposure limits. required to initiate combustion in air with no other source of ignition. LEL ?br>
TLV ?Threshold Limit Value ?an airborne concentration of a substance that the lowest percent of vapor in air, by volume, that will explode or ignite in
represents conditions under which it is generally believed that all workers may the presence of an ignition source. UEL ?the highest percent of vapor in air ,
be repeatedly exposed without adverse effect. The duration must be by volume, that will explode or ignite in the presence of an ignition source.
considered, including the 8-hour Time Weighted Average (TWA), the 15-
minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin TOXICOLOGICAL INFORMATION:
absorption effect must also be considered. Human and Animal Toxicology: Possible health hazards as derived from
OSHA ?U.S. Occupational Safety and Health Administration human data, animal studies, or from the results of studies with similar
PEL ?Permissible Exposure Limit ?This exposure value means exactly the same compounds are presented. Definitions of some terms use dint his section are:
as TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure LD50 ?Lethal Dose (solids & liquids) which kills 50% of the exposed animals;
Limits are based in the 1989 PELs and the June 1993 Air Contaminants Rule LC50 ?Lethal concentration (gases) which kills 50% of the exposed animals;
(Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and ppm ?concentration expressed in parts of material per million parts of air or
the vacated PELs are indicated. The phrase "Vacated 1989 PEL," is placed water; mg/m3- concentration expressed in weight of substance per volume
next to the PEL which was vacated by Court Order. of air; mg/kg quantity of material, by weight, administered to a test subject,
IDLH ?Immediately Dangerous to Life and Health ?This level represents a based on their body weight in kg. Other measures of toxicity include TDlo,
concentration from which one can escape within 30-minutes without suffering the lowest dose to cause a symptom and TCLo the lowest concentration to
escape-preventing or permanent injury. The DFG ?MAK is the Republic of cause a symptom; TDlo, LDlo, and LDo, or TC, TCo, LClo, and LCo, the lowest
Germany's Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the dose (or concentration) to cause lethal or toxic effects. Cancer Information:
National Institute of Occupational Safety and Health, which is the research The sources are: IARC ?the International Agency for Research on Cancer;
arm of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH NTP ?the National Toxicology Program, RTECS ?the Registry of Toxic Effects of
issues exposure guidelines called Recommended Exposure Levels (RELs) When Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals
no exposure guidelines are established, an entry of NE is made for reference. on a scale of decreasing potential to cause human cancer with rankings
from 1 to 4. Sub rankings (2A, 2B, etc.) are also used. Other Information: BEI
FIRST AID MEASURES: ?ACGIH Biological Exposure Indices, represent the levels of determinants
CPR: Cardiopulmonary resuscitation. Method in which a person whose heart which are most likely to be observed in specimens collected from a health
has stopped receives manual chest compressions and breathing to circulate worker who has been exposed to chemical to the same extent as a worker
blood and provide oxygen to the body. with inhalation exposure to the TLV. Ecological Information: EC is the effect
concentration in water. BCF ?Bioconcentration Factor, which is used to
HAZARD RATINGS: determine if a substance will concentrate in life forms that consume
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: This rating system was contaminated plant or animal matter. TLm ?median threshold limit;
developed by the National Paint and Coating Association and has been Coefficient of Oil/Water Distribution is represented by log KOW or log KOC and
adopted by industry to identify the degree of chemical hazards. Health is used to assess a substance's behavior in the environment.
Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or
chronic exposure hazard); 2 (moderate acute or significant chronic exposure REGULATORY INFORMATION:
hazard); 3 (severe acute exposure hazard; onetime overexposure can result in U.S. and CANADA: This section explains the impact of various laws and
permanent injury and may be fatal); 4 (extreme acute exposure hazard; regulation of the material. EPA is the U.S. Environmental Protection Agency.
onetime overexposure can be fatal). Flammability hazard: 0 (minimal WHMIS is the Canadian Workplace Hazardous Material Information System.
hazard); 1 (materials that require substantial pre-heating before burning; 2 DOT and TC are the U.S. Department of Transportation and Transport
(combustible liquids or solids; liquids with a flashpoint of 38-93C [100-200F]); 3 Canada, respectively. Superfund Amendments and Reauthorization Act
(Class 1B and 1C flammable liquids with flash points below 38C [100F]; 4 (Class (SARA); the Canadian Domestic/Non-Domestic Substance List (DSL/NDSL);
1A flammable liquids with flash points below 23C [73F] and boiling points the U.S. Toxic Substance Control Act (TSCA); Marine Pollutant status
below 38C [100F]. Reactivity Hazard: 0 (normally stable); 1 (materials that according to the DOT; the Comprehensive Environmental Response,
can become unstable at elevated temperatures or which can react slightly Compensation, and Liability Act (CERCLA or Superfund); and various state
with water); 2 (materials that are unstable but do not detonate when initiated regulations. This section also includes information on the precautionary
or which can react violently with water); 3 (materials that can detonate when warnings that appear on the material's package label.
initiated or which can react explosively with water); 4 (materials that can EUROPEAN and INTERNATIONAL: EC is the European Community, formerly
detonate at normal temperatures or pressures). PPE Rating A: Eye protection known as the EEC, European Economic Community). EINECS: This is the
is required for routine chemical use. European Inventory of Now-Existing Chemical Substances. AICS is the
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 (material that on Australian Inventory of Chemical Substances. MITI is the Japanese Minister of
exposure under fire conditions would offer no hazard beyond that of ordinary International Trade and Industry. ECL is the Korean Existing Chemicals List.
combustible materials); 1 (materials that on exposure under fire conditions IMO is the International Maritime Organization and IATA is the International
could cause irritation or minor residual injury); 2 (materials that on intense or Air Transport Association. The ARD is the European Agreement Concerning
continued exposure under fire conditions could cause temporary the International Carriage of Dangerous Goods by Road and the RID are the
incapacitation or possible residual injury); 3 (materials that can on short International Regulations Concerning the Carriage of Dangerous Goods by
exposure could cause serious temporary or residual injury); 4 (material that Rail.
FLAMMABILITY
under very short exposure could cause death or major residual injury).
Flammability Hazard and Reactivity Hazard: Refer to definitions for
HEALTH
"Hazardous Materials Identification System." REACTIVITY
SPECIAL
PRECAUTIONS
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