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MSDS Material Safety Data Sheet
CAS

75-45-6 9016-87-9 101-68-8 26447-40-5

File Name: 75-45-6_9016-87-9_101-68-8_26447-40.asp

         Material Safety Data Sheet
NFPA HMIS PPE Transport Symbol




Issuing Date 27-Feb-2007 Revision Date Revision Number 0


1. PRODUCT AND COMPANY IDENTIFICATION

Product Name Touch 'n Foam Professional Quick Cure Polyurethane Insulating Sealant
Touch `n Seal Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)

Recommended Use Insulation

Supplier Address Convenience Products, division of Clayton Corp.
866 Horan Drive
Fenton, MO 63026-2416 USA
TEL: (636) 349-5855

Emergency Telephone Number Chemtrec 1-800-424-9300
(703) 527-3887 outside US

2. HAZARDS IDENTIFICATION

WARNING!
Emergency Overview
Contents under pressure.
May be harmful if swallowed, inhaled, or absorbed through skin
May cause sensitization by skin contact
May cause allergic respiratory reaction.
Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not
work with isocyanates.
Vapors may be irritating to eyes, nose, throat, and lungs.
May cause drowsiness and dizziness.
Appearance Pale Amber Physical State Aerosol Liquid Odor Faint hydrocarbon

Potential Health Effects
Principle Routes of Exposure Inhalation, Skin contact, Eye contact.

Acute Toxicity
Eyes Irritating to eyes. Risk of serious damage to eyes.
Skin Harmful in contact with skin. Will bond to skin. May cause sensitization by skin contact.
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons.
Inhalation Harmful by inhalation. Irritating to respiratory system. May cause allergic respiratory reaction.
Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal.
Inhalation of vapors in high concentration may cause shortness of breath (lung edema). May
cause allergy or asthma symptoms or breathing difficulties if inhaled.
Ingestion May be harmful if swallowed. May cause additional affects as listed under "Inhalation".
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Product may
cure in the gastrointestinal tract and form an obstruction. May cause adverse cardiac effects,
blood disturbances, and metabolic acidosis.

Page 1 / 8
WPS-CC-016 - Touch 'n Foam Professional Quick Cure Polyurethane Insulating Sealant (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
_________________________________________________________________________________


Chronic Effects Repeated or prolonged exposure may cause central nervous system damage. Intentional
misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic
hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac
arrest. Repeated or prolonged contact causes sensitization, asthma and eczemas.

Aggravated Medical Conditions Allergies. Skin disorders. Respiratory disorders. Central nervous system. Preexisting eye
disorders. Kidney disorders. Liver disorders.

Interactions with Other Chemicals Irritants. Sensitizers. Epoxies. Use of alcoholic beverages may enhance toxic effects.

Environmental Hazard See Section 12 for additional Ecological information

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No Weight %
Chlorodifluoromethane 75-45-6 10-30
Flame Retardant Proprietary 5-10
Polymethylene polyphenylene isocyanate 9016-87-9 10-30
Methylene bisphenyl isocyanate (MDI) 101-68-8 10-30
Polyol blend Proprietary 10-30
Methylenediphenyl diisocyanate 26447-40-5 1-5


4. FIRST AID MEASURES

General Advice Call 911 or emergency medical service. Remove and isolate contaminated clothing and shoes.

Eye Contact In case of contact with substance, immediately flush skin or eyes with running water for at least
20 minutes.

Skin Contact Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes. Remove and wash contaminated clothing before re-use. Wash off immediately with
plenty of water. If skin irritation persists, call a physician.

Inhalation Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen
if breathing is difficult.

Ingestion Call a physician or Poison Control Center immediately. Do not induce vomiting. Rinse mouth.
Drink plenty of water. Never give anything by mouth to an unconscious person.

Notes to Physician May cause sensitization of susceptible persons. Treat symptomatically. Keep victim warm and
quiet.

Protection of First-aiders Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. FIRE-FIGHTING MEASURES

Flammable Properties Containers may explode when heated.


Flash Point None
Suitable Extinguishing Media Dry chemical, CO2, water spray or regular foam. Water spray, fog
or regular foam. Move containers from fire area if you can do it
without risk. Dike fire-control water for later disposal.

Unsuitable Extinguishing Media Do not scatter spilled material with high pressure water streams.



Page 2 / 8
WPS-CC-016 - Touch 'n Foam Professional Quick Cure Polyurethane Insulating Sealant (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
_________________________________________________________________________________

Explosion Data
Sensitivity to mechanical impact None
Sensitivity to static discharge None

Specific Hazards Arising from the Chemical
Ruptured cylinders may rocket.

Protective Equipment and Precautions for Firefighters
Wear self-contained breathing apparatus and protective suit.

NFPA Health Hazard 2 Flammability 1 Stability 1 Physical and Chemical
Hazards -

HMIS Health Hazard 2* Flammability 1 Stability 1 Personal Precautions -


6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Do not touch or walk through spilled material. Stop leak if you can do it without risk.

Methods for Containment If possible, turn leaking containers so that gas escapes rather than liquid. Allow substance to
evaporate. Dike to collect large liquid spills.

Methods for Cleaning Up Soak up with inert absorbent material. Sweep up and shovel into suitable containers for
disposal. Do not direct water at spill or source of leak.

Other Information Ventilate the area.

7. HANDLING AND STORAGE

Handling Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Remove and
wash contaminated clothing before re-use. Do not breathe vapors or spray mist. Do not eat,
drink or smoke when using this product. Use only in area provided with appropriate exhaust
ventilation. Ensure adequate ventilation. Avoid breathing vapors or mists. Contents under
pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into
opening on top of can.

Storage Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated
place. Keep at temperatures below 48.8 癈 / 120 癋.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Chlorodifluoromethane TWA: 1000 ppm TWA: 1000 ppm
3
TWA: 3500 mg/m
3
Methylene bisphenyl isocyanate TWA: 0.005 ppm Ceiling: 0.02 ppm 75 mg/m
3
(MDI) Ceiling: 0.2 mg/m

NIOSH IDLH: Immediately Dangerous to Life or Health

Engineering Measures Showers
Eyewash stations
Ventilation systems

Personal Protective Equipment
Eye/Face Protection Tightly fitting safety goggles.
Skin and Body protection Lightweight protective clothing. Impervious gloves.

Page 3 / 8
WPS-CC-016 - Touch 'n Foam Professional Quick Cure Polyurethane Insulating Sealant (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
_________________________________________________________________________________

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory
protection should be worn. Respiratory protection must be provided in accordance with
current local regulations.

Hygiene Measures When using, do not eat, drink or smoke. Wear suitable gloves and eye/face protection.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Odor
Pale Amber Faint hydrocarbon

Odor Threshold Physical State
No information available Aerosol Liquid

pH No information available

Flash Point Autoignition Temperature
None Not applicable

Decomposition temperature Boiling Point/Range
No data available -41癈 / -42癋

Melting Point/Range No data available

Flammability Limits in Air Explosion Limits
No data available No data available

Specific Gravity Water Solubility
1.2 Not Compatible

Solubility Evaporation Rate
Compatible. No data available

Vapor Pressure Vapor Density
No data available No data available

VOC Content EPA VOC (g/l)
Not applicable 0

Partition Coefficient (n- No data available
octanol/water)

10. STABILITY AND REACTIVITY

Stability Stable under recommended storage conditions

Conditions to Avoid Keep away from open flames, hot surfaces and sources of ignition.
Temperatures above 48.8 癈 / 120 癋.

Incompatible Products Water. Alcohols. Strong bases. Strong oxidizing agents. Finely
powdered metals.

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Nitrogen oxides
(NOx), Hydrogen cyanide.

Hazardous Polymerization Hazardous polymerization does not occur

11. TOXICOLOGICAL INFORMATION
Acute Toxicity

Product Information Product does not present an acute toxicity hazard based on known or supplied information

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Chlorodifluoromethane 220000 ppm ( Rat ) 4 h

Flame Retardant 1850 mg/kg ( Rat ) 2000 mg/kg ( Rat ) 5.22 mg/L ( Rat ) 4 h
23700 mg/kg ( Rabbit )



Page 4 / 8
WPS-CC-016 - Touch 'n Foam Professional Quick Cure Polyurethane Insulating Sealant (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
_________________________________________________________________________________

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
3
Polymethylene polyphenylene 49 g/kg ( Rat ) 9400 mg/kg ( Rabbit ) 490 mg/m ( Rat ) 4 h
isocyanate
Methylene bisphenyl isocyanate 9200 mg/kg ( Rat )
(MDI)
Polyol blend 64 mL/kg ( Rat ) 20 mL/kg ( Rabbit )
Methylenediphenyl diisocyanate 6200 mg/kg ( Rabbit ) 0.369 mg/L ( Rat ) 4 h

Subchronic Toxicity (28 days)

Chronic Toxicity

Chronic Toxicity Repeated or prolonged exposure may cause central nervous system damage. Intentional
misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic
hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac
arrest. Repeated or prolonged contact causes sensitization, asthma and eczemas.

Carcinogenicity There are no known carcinogenic chemicals in this product.

Mutagenicity

Reproductive Toxicity This product does not contain any known or suspected reproductive hazards

Target Organ Effects Central nervous system (CNS), Eyes, Respiratory system, Central Vascular System (CVS),
Kidney, Liver, spleen.

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

12. ECOLOGICAL INFORMATION

Ecotoxicity
Ecotoxicity effects.

Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea)
Flame Retardant EC50 > 10 mg/L 72 h EC50 3.9 - 5.5 mg/L 48 h
Methylenediphenyl EC50 = 3230 mg/L 96 h EC50 > 1000 mg/L 24 h
diisocyanate

Chemical Name Log Pow
Chlorodifluoromethane 1.08


13. DISPOSAL CONSIDERATIONS

Waste Disposal Method This material, as supplied, is not a hazardous waste according to state and federal regulations
(40 CFR 261)

Contaminated Packaging Dispose of in accordance with local regulations

14. TRANSPORT INFORMATION
DOT
Proper Shipping Name Consumer commodity
Hazard Class ORM-D
Description Consumer commodity,ORM-D,
TDG
Proper Shipping Name Aerosols
Hazard Class 2.2
UN-No UN1950
Description AEROSOLS,2.2,UN1950


Page 5 / 8
WPS-CC-016 - Touch 'n Foam Professional Quick Cure Polyurethane Insulating Sealant (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
_________________________________________________________________________________

14. TRANSPORT INFORMATION
MEX
Proper Shipping Name Aerosols
Hazard Class 2.2
UN-No UN1950
Description UN1950 Aerosols,2.2,
ICAO
UN-No UN1950
Proper Shipping Name Aerosols
Hazard Class 2.2
Description Aerosols,UN1950
IATA
UN-No UN1950
Proper Shipping Name Aerosols, non-flammable
Hazard Class 2.2
ERG Code 2L
Description UN1950,Aerosols, non-flammable,2.2
IMDG/IMO
Proper Shipping Name Aerosols
Hazard Class 2
UN-No UN1950
EmS No. F-D, S-U
Description UN1950, Aerosols,2
RID
Proper Shipping Name Aerosols
Hazard Class 2
UN-No UN1950
Classification Code 5A
Description UN1950 Aerosols,2,,RID
ADR/RID-Labels 2
ADR
Proper Shipping Name Aerosols
Hazard Class 2
UN-No UN1950
Classification Code 5A
ADR/RID-Labels 2
ADN
Proper Shipping Name Aerosols
Hazard Class 2
Classification Code 5A
Special Provisions 63, 190, 191, 277, 913
Description UN1950 Aerosols,2
Hazard Labels 2
Limited Quantity See SP277




Page 6 / 8
WPS-CC-016 - Touch 'n Foam Professional Quick Cure Polyurethane Insulating Sealant (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
_________________________________________________________________________________

15. REGULATORY INFORMATION

International Inventories

TSCA Complies
DSL Complies
EINECS/ELINCS Complies
ENCS Complies
CHINA Complies
KECL Complies
PICCS Complies
AICS Complies

U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

Chemical Name CAS-No Weight % SARA 313 - Threshold
Values
Chlorodifluoromethane 75-45-6 10-30 1.0

Polymethylene polyphenylene isocyanate 9016-87-9 10-30 1.0
Methylene bisphenyl isocyanate (MDI) 101-68-8 10-30 1.0
Methylenediphenyl diisocyanate 26447-40-5 1-5 1.0

SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard Yes
Reactive Hazard No

Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR
122.42).

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs


Methylene bisphenyl isocyanate (MDI) 5000 lb



U.S. State Regulations

California Proposition 65
This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations
Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Methylene bisphenyl X X X X X
isocyanate (MDI)
Chlorodifluoromethane X X X X



International Regulations



Page 7 / 8
WPS-CC-016 - Touch 'n Foam Professional Quick Cure Polyurethane Insulating Sealant (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant RX (cylinder)
Touch `n Seal Quick Cure Polyurethane Foam Sealant HY (cylinder)
_________________________________________________________________________________

Mexico - Grade
The exposure limits values for 101-68-8 are listed under two synonyms:
3
Diphenylmethane diisocyanate - 0.02 ppm TWA; 0.2 mg/m TWA
Methylene bisphenyl isocyanate - 0.005 ppm TWA; 0.051 mg/m3 TWA


Chemical Name Carcinogen Status Exposure Limits
3
Methylene bisphenyl isocyanate (MDI) Mexico: TWA= 0.2 mg/m
Mexico: TWA= 0.02 ppm
Mexico: TWA= 0.005 ppm
3
Mexico: TWA= 0.051 mg/m
3
Chlorodifluoromethane Mexico: TWA= 3500 mg/m
Mexico: TWA= 1000 ppm
Mexico: STEL= 1250 ppm
3
Mexico: STEL= 4375 mg/m

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.

WHMIS Hazard Class
A Compressed gases
D2A Very toxic materials




Chemical Name NPRI
Methylene bisphenyl isocyanate (MDI) X
Chlorodifluoromethane X

Legend
NPRI - National Pollutant Release Inventory

16. OTHER INFORMATION

Issuing Date 27-Feb-2007

Revision Date

Revision Note No information available

Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any other material or in any
process, unless specified in the text.

End of MSDS




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