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Section 1 - Chemical Product and Company Identification |
MSDS Name: Ethylenediaminetetraacetic acid, disodium salt, standard solution
Catalog Numbers:
SS221-4
Synonyms:
Disodium ethylenediaminetetraacetate standard solution; 0.01M
Solution; Sodium EDTA Standard Solution.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7732-18-5 |
Water |
>97.9 | 231-791-2 |
| 1310-73-2 |
Sodium hydroxide |
<1.0 | 215-185-5 |
| 6381-92-6 |
Disodium ethylenediaminetetraacetate dihydrate |
<1.0 | unlisted |
| 7791-18-6 |
Magnesium chloride, hexahydrate |
<0.10 | unlisted |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless liquid.
Caution! May cause eye, skin, and respiratory
tract irritation.
Target Organs: None known.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
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Section 4 - First Aid Measures
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Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Non-combustible, substance itself does not burn but
may decompose upon heating to produce irritating, corrosive and/or
toxic fumes.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Substance is noncombustible; use agent most
appropriate to extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
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Section 7 - Handling and Storage
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Handling:
Use with adequate ventilation. Avoid contact with skin and eyes.
Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Good general ventilation should be sufficient to control airborne
levels. Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Water
|
none listed
|
none listed
|
none listed
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| Sodium hydroxide
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2 mg/m3 Ceiling
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10 mg/m3 IDLH
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2 mg/m3 TWA
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| Disodium ethylenediaminetetraacetate dihydrate
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none listed
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none listed
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none listed
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| Magnesium chloride, hexahydrate
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none listed
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none listed
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none listed
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| Disodium EDTA anhydrous
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Water:
No OSHA Vacated PELs are listed for this chemical.
Sodium hydroxide:
No OSHA Vacated PELs are listed for this chemical.
Disodium ethylenediaminetetraacetate dihydrate:
No OSHA Vacated PELs are listed for this chemical.
Magnesium chloride, hexahydrate:
No OSHA Vacated PELs are listed for this chemical.
Disodium EDTA anhydrous:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: 14 mm Hg
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: >1 (ether=1)
Boiling Point: 100 deg C
Freezing/Melting Point:0 deg C
Decomposition Temperature:Not available.
Solubility: Completely soluble in water.
Specific Gravity/Density:1.02
Molecular Formula:Mixture
Molecular Weight:Not available.
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizers.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide, toxic fumes of
sodium oxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 1310-73-2:
WB4900000
CAS# 6381-92-6:
AH4410000
CAS# 7791-18-6:
OM2975000
CAS# 139-33-3:
AH4375000
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 =
>90 mL/kg;
.
CAS# 1310-73-2:
Draize test,
rabbit, eye: 400 ug Mild;
Draize
test, rabbit, eye: 1% Severe;
Draize test, rabbit, eye: 50 ug/24H
Severe;
Draize test, rabbit, eye:
1 mg/24H Severe;
Draize test,
rabbit, skin: 500 mg/24H Severe;
.
CAS# 6381-92-6:
.
CAS# 7791-18-6:
Oral, mouse:
LD50 = 7600 mg/kg;
Oral, rat: LD50
= 8100 mg/kg;
.
CAS# 139-33-3:
Oral, mouse:
LD50 = 2050 mg/kg;
Oral, rabbit:
LD50 = 2300 mg/kg;
Oral, rat: LD50
= 2 gm/kg;
.
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 1310-73-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 6381-92-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7791-18-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 139-33-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
Not regulated as a hazardous material |
No information available. |
| Hazard Class: |
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| UN Number: |
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| Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 1310-73-2 is listed on the TSCA inventory.
CAS# 6381-92-6 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 7791-18-6 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 139-33-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 1310-73-2: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 1310-73-2: immediate, reactive.
CAS # 6381-92-6: immediate.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 1310-73-2 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 1310-73-2 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 6381-92-6 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7791-18-6 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 139-33-3 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 1310-73-2: 1
CAS# 6381-92-6: 2
CAS# 7791-18-6: 0
CAS# 139-33-3: 2
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 1310-73-2 is listed on Canada's DSL List.
CAS# 6381-92-6 is listed on Canada's DSL List.
CAS# 139-33-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 1310-73-2 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997
Revision #7 Date: 11/06/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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