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MSDS  
:
 Sodium periodate
CAS  
:
 7790-28-5
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification

MSDS Name: Sodium periodate
Catalog Numbers: AC198380000, AC198380050, AC198381000, AC198385000, AC419610000, AC419610050, AC419615000, S398-100, S398-50
Synonyms:
Sodium metaperiodate; Periodic acid (HIO4), sodium salt.
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7790-28-5 Sodium metaperiodate 99 232-197-6

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white crystalline powder.
Danger! Strong oxidizer. Contact with other material may cause a fire. Causes eye, skin, and respiratory tract irritation. May be harmful if swallowed, inhaled, or absorbed through the skin.
Target Organs: Respiratory system, eyes, skin.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation: Causes respiratory tract irritation. May be harmful if inhaled.
Chronic: Prolonged or repeated skin contact may cause dermatitis.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire.
Extinguishing Media: Use water only! May require flooding with water in order to eliminate hazardous reactions since the materials generate their own oxygen. Do NOT use dry chemicals, CO2, Halon or foams.
Flash Point: Not applicable.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0; Special Hazard: OX

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. Keep combustibles (wood, paper, oil, etc.,) away from spilled material.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid contact with clothing and other combustible materials. Keep from contact with clothing and other combustible materials. Avoid breathing dust.
Storage: Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from reducing agents.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Sodium metaperiodate none listed none listed none listed

OSHA Vacated PELs: Sodium metaperiodate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Crystalline powder
Appearance: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:300 deg C (dec)
Decomposition Temperature:300 deg C
Solubility: 80 g/l @ 20°C
Specific Gravity/Density:Not available.
Molecular Formula:INaO4
Molecular Weight:213.89

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Dust generation.
Incompatibilities with Other Materials: Strong reducing agents, combustible materials.
Hazardous Decomposition Products: Hydrogen iodide, sodium oxide, iodine.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7790-28-5: SD4550000
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 7790-28-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: OXIDIZING SOLID, N.O.S. OXIDIZING SOLID NOS (SODIUM PERIODATE)
Hazard Class: 5.1 5.1
UN Number: UN1479 UN1479
Packing Group: II II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7790-28-5 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 7790-28-5: fire.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7790-28-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN O
Risk Phrases:

     R 20/21/22 Harmful by inhalation, in contact with skin and if
     swallowed.
     R 36/37/38 Irritating to eyes, respiratory system and skin.
     R 8 Contact with combustible material may cause fire.

Safety Phrases:

     S 17 Keep away from combustible material.
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
     otection.

WGK (Water Danger/Protection)

     CAS# 7790-28-5: 1
Canada - DSL/NDSL
     CAS# 7790-28-5 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of C.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 9/15/1998
Revision #4 Date: 3/15/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
Sodium metaphosphate 10124-56-8
trans-2-Pentenoic acid 13991-37-2
3-Acetylindole, 97% 703-80-0
Sodium sulfhydrate 497-19-8
Sodium Hydrosulfite 7775-14-6SODIUM DITHIONITE<-td>
Sodium hydroxide, solid 497-19-8
3,5-Dimethyl-2-cyclohexen-1-one, 99% 1123-09-7
Sodium hypophosphite monohydrate 10039-56-2
Sodium iodate 7681-55-2
Sodium Iodide, Anhydrous, 99+% 7681-82-5
1,1'-(4-Chlorobutylidene)bis-(4-fluorobenzene) tech. 90+% 3312-04-7
Sodium Lactate 7732-18-5
Sodium arsenite, powder, certified 7784-46-5
Sodium metabisulfite 7681-57-4
2,6-Dichloropyrazine, 99+% 4774-14-5
Sodium methoxide, anhydrous powder 1310-73-2
Potassium Hydroxide 0.2N Solution in Methanol Not available
Sodium Nitrate 7631-99-4
Octanoic acid 124-07-2
Sodium nitrite 7632-00-0
1-Phenyl-1-cyclopropanecarboxylic acid, 97% 6120-95-2
4,4'-Dimethoxybenzhydrol, 98+% 728-87-0
1,1-Dimethylpropargylamine 7732-18-5
Diethyldithiocarbamic Acid, Sodium Salt Trihydrate, Reagent ACS <-td>
Vinyltriphenylphosphonium bromide, 97% 5044-52-0
Sodium Vanadate 13721-39-6
Mucic Acid, 98% 526-99-8
Sodium oxalate 62-76-0
2-Hydroxyethylhydrazine, 90% 109-84-2
Methyl benzilate 76-89-1
Methyl (r)-(+)-Lactate 17392-83-5
2-Thiophenecarboxylic acid hydrazide, 97% 2361-27-5
Acetonyltriphenylphosphonium chloride, 99% 1235-21-8
3,5-Dinitro-2-Methylbenzyl Alcohol, 97% 80866-93-9
Sodium perchlorate monohydrate 7791-07-3
Sodium periodate 7790-28-5
2,2,5,5-Tetramethyl-4-methylene-3-formyl-imidazolidine-1-oxyl, free radical, 98% 82814-77-5
Sucrose Diacetate Hexaisobutyrate (Pract) 126-13-6
Sodium peroxide 1310-73-2
Sodium phosphate dibasic heptahydrate 7782-85-6
Dichloromethane-D2, 100.0 Atom % D 1665-00-5
6-Hydroxydopamine hydrobromide 636-00-0
Hepta-O-Acetyl-Cellobiosyl-Betha-Azide, 99% 33012-50-9
4-Fluorophenyl isocyanate, 99% 1195-45-5
Potassium sodium tartrate tetrahydrate 6381-59-5
3,4-Dihydroxycinnamic acid, 99+%, predominantly trans isomer 331-39-5
Sodium pyrophosphate decahydrate 13472-36-1
Salicylic acid, sodium salt 54-21-7
Paraldehyde, 99.5% (gc) 123-63-7
4-Chloro-3-nitrobenzenesulfonyl chloride 97-08-5



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