Section 1 - Chemical Product and Company Identification |
MSDS Name: Kerosene Odorless
Catalog Numbers:
AC611030010, 1498316, 14997, 14998, 15-021C, 15035, 61103-0040, K10-200,
K10-200LC, K10-4, NC9191501, S800451, ZZK102011
Synonyms:
Coal oil; Fuels, kerosine; Kerosine (petroleum).
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
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CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
64742-14-9 |
Kerosene |
>99 | 265-114-7 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: pale yellow liquid. Flash Point: 71.1 deg C.
Warning! May be harmful or fatal if inhaled or
swallowed. Combustible liquid and vapor. Causes eye and skin
irritation. Aspiration hazard if swallowed. Can enter lungs and
cause damage. May cause respiratory tract irritation. May cause
blood abnormalities. May cause central nervous system depression.
May cause liver and kidney damage.
Target Organs: Central nervous system, lungs,
respiratory system, eyes, skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may
cause defatting of the skin and dermatitis. May be absorbed through
damaged or abraded skin in harmful amounts.
Ingestion:
Aspiration hazard. May cause severe digestive tract irritation with
abdominal pain, nausea, vomiting and diarrhea. Aspiration of
material into the lungs may cause chemical pneumonitis, which may be
fatal. May cause central nervous system depression.
Exposure by ingestion may also cause adverse effects in the liver,
kidneys, pancreas, and
Inhalation:
Causes respiratory tract irritation. Irritation may lead to chemical
pneumonitis and pulmonary edema. Exposure produces central nervous
system depression. Aspiration may cause respiratory swelling and
pneumonitis. Aspiration may lead to pulmonary edema.
Chronic:
Prolonged or repeated inhalation of dusts may cause neurological
damage. Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause anemia and other blood cell abnormalities.
Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Potential for aspiration if swallowed. Get medical aid immediately.
Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. If
vomiting occurs naturally, have victim lean forward.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Containers
may explode in the heat of a fire. Liquid will float and may reignite
on the surface of water. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Combustible liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. For large fires,
use water spray, fog or regular foam. For small fires, use dry
chemical, carbon dioxide, water spray or regular foam. Cool
containers with flooding quantities of water until well after fire is
out.
Flash Point: 71.1 deg C ( 159.98 deg F)
Autoignition Temperature: 210 deg C ( 410.00 deg F)
Explosion Limits, Lower:0.7
Upper: 5.0
NFPA Rating:
(estimated) Health: 2; Flammability: 2; Instability: 0
Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Wear a self contained breathing apparatus and appropriate personal
protection. (See Exposure Controls, Personal Protection section).
Scoop up with a nonsparking tool, then place into a suitable
container for disposal. Remove all sources of ignition. Absorb spill
using an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust.
Provide ventilation. Water spray may reduce vapor but may not prevent
ignition in closed spaces.
Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Do not ingest or inhale. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Kerosene
|
none listed
|
none listed
|
none listed
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OSHA Vacated PELs:
Kerosene:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: pale yellow
Odor: odorless
pH: Not available.
Vapor Pressure: 5 mm Hg @ 38C
Vapor Density: 4.5 (air=1)
Evaporation Rate:Not available.
Viscosity: >1.3 CST @ 40C
Boiling Point: 151.1-301.1 deg C
Freezing/Melting Point:-17.8 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:0.8 (water=1)
Molecular Formula:Not applicable.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
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Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizers.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrocarbons.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
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RTECS#:
CAS# 64742-14-9
unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 64742-14-9:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Ingestion of kerosene has been known to produce rapid death
by gross aspiration and occlusion of the respiratory
system. Even when death does not occur promptly, there is
abundant evidence that the pneumonia commonly seen in
children who swallow kerosene usually results from
aspiration. The aspiration usually occurs at the moment of
ingestion or as the result of vomiting within the first
hour
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
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Ecotoxicity:
No data available.
Bluegill (fresh water) TLm=2990ppm/24H
Environmental:
Biological Oxygen Demand (BOD): 53%, 5 days.
Physical:
No information available.
Other:
None.
Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
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US DOT |
Canada TDG |
Shipping Name: |
Not Regulated |
Not Regulated |
Hazard Class: |
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UN Number: |
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Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 64742-14-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 64742-14-9 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 65 Harmful: may cause lung damage if swallowed.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24 Avoid contact with skin.
S 62 If swallowed, do not induce vomiting: seek medical advice immed
iately and show this container or label.
WGK (Water Danger/Protection)
CAS# 64742-14-9: No information available.
Canada - DSL/NDSL
CAS# 64742-14-9 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B3, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997 Revision #8 Date: 6/12/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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