Section 1 - Chemical Product and Company Identification |
MSDS Name: 2-Iodoxybenzoic acid, stabilized
Catalog Numbers:
AC374650000, AC374650010, AC374650100, AC374650500
Synonyms:
SIBX; Dess Martin analogue.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
61717-82-6 |
2-Iodoxybenzoic acid |
ca 47% | unlisted |
121-91-5 |
Isophtalic acid |
ca 30% | 204-506-4 |
65-85-0 |
Benzoic acid |
ca 23% | 200-618-2 |
64297-64-9 |
2-Iodoxybenzoic acid, stabilized |
| 264-773-8 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white to off-white solid.
Danger! Risk of explosion if heated under
confinement. Harmful if swallowed, inhaled, or absorbed through the
skin. Causes eye, skin, and respiratory tract irritation. May cause
sensitization by inhalation and by skin contact.
Target Organs: Respiratory system,
gastrointestinal system, eyes, skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May
cause sensitization by skin contact.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. May cause
respiratory sensitization.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in
sensitive individuals.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Call a poison
control center.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Violently decomposes when heated under confinement.
Containers may explode if exposed to fire. Risk of explosion if
heated under confinement.
Extinguishing Media:
Use dry powder or carbon dioxide.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 1; Instability: 2
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Wear a self contained breathing apparatus and appropriate
personal protection. (See Exposure Controls, Personal Protection
section). Avoid generating dusty conditions. Provide ventilation. Do
not let this chemical enter the environment.
Section 7 - Handling and Storage
|
Handling:
Minimize dust generation and accumulation. Use spark-proof tools and
explosion proof equipment. Do not get in eyes, on skin, or on
clothing. Do not ingest or inhale. Use only in a chemical fume hood.
Keep away from heat, sparks and flame.
Storage:
Keep away from heat and flame. Store in a cool, dry place. Do not
store in direct sunlight. Store in a tightly closed container.
Corrosives area.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use only under a chemical fume hood.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
2-Iodoxybenzoic acid
|
none listed
|
none listed
|
none listed
|
Isophtalic acid
|
none listed
|
none listed
|
none listed
|
Benzoic acid
|
none listed
|
none listed
|
none listed
|
2-Iodoxybenzoic acid, stabilized
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
2-Iodoxybenzoic acid:
No OSHA Vacated PELs are listed for this chemical.
Isophtalic acid:
No OSHA Vacated PELs are listed for this chemical.
Benzoic acid:
No OSHA Vacated PELs are listed for this chemical.
2-Iodoxybenzoic acid, stabilized:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: white to off-white
Odor: Not available.
pH: 1.8
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:280 deg C(decom)
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:C7H5IO5
Molecular Weight:280.01
Section 10 - Stability and Reactivity
|
Chemical Stability:
Light sensitive. Risk of explosion if heated under confinement.
Conditions to Avoid:
Incompatible materials, light, dust generation, temperatures above
100°C.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, reducing agents, bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen iodide, iodine.
Hazardous Polymerization: Has not been reported
Section 11 - Toxicological Information
|
RTECS#:
CAS# 61717-82-6
unlisted.
CAS# 121-91-5:
NT2007000
CAS# 65-85-0:
DG0875000
CAS# 64297-64-9
unlisted.
LD50/LC50:
Not available.
CAS# 121-91-5: Draize test,
rabbit, eye: 500 mg/24H Mild;
Oral, rat: LD50 = 10400
mg/kg; .
CAS# 65-85-0: Draize test,
rabbit, eye: 100 mg Severe; Draize
test, rabbit, skin: 500 mg/24H Mild;
Inhalation, rat: LC50 = >26
mg/m3/1H; Oral, mouse: LD50 = 1940
mg/kg; Oral, rat: LD50 = 1700
mg/kg; Skin, rabbit: LD50 = >10
gm/kg; .
CAS# 64297-64-9: .
Carcinogenicity:
CAS# 61717-82-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 121-91-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 65-85-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 64297-64-9:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
Do not empty into drains.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. |
No information available. |
Hazard Class: |
8 |
|
UN Number: |
UN3261 |
|
Packing Group: |
III |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 61717-82-6 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 121-91-5 is listed on the TSCA inventory.
CAS# 65-85-0 is listed on the TSCA inventory.
CAS# 64297-64-9 is not listed on the TSCA inventory.
It is for research and development use only.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 65-85-0: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 121-91-5: immediate.
CAS # 65-85-0: immediate.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 65-85-0 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 61717-82-6 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 121-91-5 can be found on the
following state right to know lists: Minnesota.
CAS# 65-85-0 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Massachusetts.
CAS# 64297-64-9 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with skin and if
swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 42/43 May cause sensitization by inhalation and skin contact.
R 44 Risk of explosion if heated under confinement.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 61717-82-6: No information available.
CAS# 121-91-5: 0
CAS# 65-85-0: 1
CAS# 64297-64-9: No information available.
Canada - DSL/NDSL
CAS# 121-91-5 is listed on Canada's DSL List.
CAS# 65-85-0 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1B, D2B, D2A, F.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 121-91-5 is listed on the Canadian Ingredient Disclosure List.
CAS# 65-85-0 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 9/20/2004 Revision #3 Date: 10/23/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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