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Section 1 - Chemical Product and Company Identification |
MSDS Name: 3,4-Dichlorobenzotrifluoride, 97%
Catalog Numbers:
AC216560000, AC216560100, AC216560500
Synonyms:
3,4-Dichloro-alpha, alpha, alpha-trifluorotoluene; 3,4-DCBTE
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 328-84-7 |
3,4-Dichlorobenzotrifluoride |
97.0 | 206-337-1 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: 65 deg C.
Caution! Causes eye and skin irritation.
Combustible liquid and vapor. May cause respiratory
tract irritation. The toxicological properties of this material have
not been fully investigated.
Target Organs: None known.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause
irritation and/or dermatitis.
Ingestion:
The toxicological properties of this substance have not been fully
investigated. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
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Section 4 - First Aid Measures
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Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
Flash Point: 65 deg C ( 149.00 deg F)
Autoignition Temperature: > 600 deg C (> 1,112.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
Not published.
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep away from heat, sparks
and flame. Avoid ingestion and inhalation. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| 3,4-Dichlorobenzotrifluoride
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none listed
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none listed
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2.5 mg/m3 TWA (as dust) (listed under Fluorides).
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OSHA Vacated PELs:
3,4-Dichlorobenzotrifluoride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear, colorless
Odor: aromatic odor
pH: Not available.
Vapor Pressure: 2 mm Hg @25C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 173 - 174 deg C @ 760.00mm Hg
Freezing/Melting Point:-13 - -12 deg C
Decomposition Temperature:Not available.
Solubility: Negligible.
Specific Gravity/Density:1.4780g/cm3
Molecular Formula:C7H3Cl2F3
Molecular Weight:215.00
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents,strong alkalis.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen fluoride
gas.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 328-84-7:
CZ5527510
LD50/LC50:
CAS# 328-84-7:
Oral, rat: LD50 =
1960 uL/kg;
Skin, rabbit: LD50 = >5
gm/kg;
.
LC50 RAT >2,000 PPM/1HR, LD50 RAT 1.15 G/KG
Carcinogenicity:
CAS# 328-84-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. |
No information available. |
| Hazard Class: |
8 |
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| UN Number: |
UN3265 |
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| Packing Group: |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 328-84-7 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 328-84-7: Effective 5/8/85, Sunset 11/9/93
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 328-84-7 can be found on the
following state right to know lists: California, (listed as
Fluorides), Pennsylvania, (listed as Fluorides), Minnesota, (listed
as Fluorides).
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection)
CAS# 328-84-7: 1
Canada - DSL/NDSL
CAS# 328-84-7 is listed on Canada's NDSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 328-84-7 is not listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997
Revision #5 Date: 4/27/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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