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MSDS  
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 (4(S)-TRANS)-4,5-DIHYDROXY-3-OXO-          CYCLOHEXENE-1-CARBOXYLIC ACID, 98+% (HPLC)
CAS  
:
 2922-42-1
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification
MSDS Name: (4(S)-TRANS)-4,5-DIHYDROXY-3-OXO- CYCLOHEXENE-1-CARBOXYLIC ACID, 98+% (HPLC)
Catalog Numbers: AC42513, AC425130000
Synonyms:

Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
2922-42-1 (4(S)-TRANS)-4,5-DIHYDROXY-3-OXO- CYCLOHEXENE-1-CARBOXYLIC ACID, 98+% (HPLC) 98+ unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Not available.
Target Organs: None.


Potential Health Effects The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent opportunities for direct contact with the skin or eyes and to prevent inhalation.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use agent most appropriate to extinguish fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: ; Flammability: ; Instability:

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Keep container closed when not in use. Deep freeze (below -20°C).

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
(4(S)-TRANS)-4,5-DIHYDROXY-3-OXO- CYCLOHEXENE-1-CARBOXYLIC ACID, 98+% (HPLC) none listed none listed none listed

OSHA Vacated PELs: (4(S)-TRANS)-4,5-DIHYDROXY-3-OXO- CYCLOHEXENE-1-CARBOXYLIC ACID, 98+% (HPLC): No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: white to off-white
Odor: amine-like
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:146.00 - 147.00 deg C
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:C7H8O5
Molecular Weight:172.14

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Strong oxidants.
Incompatibilities with Other Materials: Not available.
Hazardous Decomposition Products: Strong oxidants.
Hazardous Polymerization: Not available.

Section 11 - Toxicological Information


RTECS#:      
CAS# 2922-42-1 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 2922-42-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: Not regulated as a hazardous material No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 2922-42-1 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 2922-42-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:


Safety Phrases:

     S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)

     CAS# 2922-42-1: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     WHMIS: Not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #5 Date: 3/26/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
Magnesium bis(diisopropylamide), 0.7M solution in THF 513-35-9
Zinc chloride, 0.7M solution in THF 7646-85-7
Ethyl 2-methyl-4-phenyl-1,3-thiazole-5-carboxylate 32043-95-1
[4-(Pyrrolidin-1-ylmethyl)phenyl]methanol 91271-60-2
N-{[5-(2-Furyl)thien-2-yl]methyl}-N-methylamine 869901-16-6
1-Methyl-1H-pyrazole-3-sulfonyl chloride 89501-90-6
2-Methyl-4-phenyl-1,3-thiazole-5-carboxylic acid 32002-72-5
5-Methyl-2-phenyl-3-furaldehyde 157836-53-8
5-Amino-1-methyl-1H-pyrazole-4-carbaldehyde 62564-90-3
3-Piperidin-1-ylpyridine-2-carbonitrile 780802-33-7
2-(2-(2-CHLOROETHOXY)-ETHOXY)-ETHANOL, 98% (GC) 5197-62-6
(3-Thien-3-ylphenyl)methylamine 138139-99-8
4-Allyl 1-(9-H-fluoren-9-ylmethyl)hydrogen piperazine-1,2,4- tricarboxylate 898289-65-1
Isopropyltriphenylphosphoniumiodide, 98% 24470-78-8
Methyl 2-chloropyrimidine-5-carboxylate 287714-35-6
5-(Chloromethyl)-3-[4-(1,3-dithiolan-2-yl)phenyl]-1,2,4-oxadiazole 287197-10-8
Resorcinol sulfide, 98% 97-29-0
Ethyl 4-[5-chloro-4-(diethylamino)-6-oxopyridazin-1(6H)-yl]benzoate Not available
Phenylmagnesium bromide, 2.8M solution in 2-Methyltetrahydrofuran 100-58-3
4,4-Dimethyl-1,3-oxazolane-2-thione 54013-55-7
Methyl Isobutyl Ketone 108-10-1
Methylmagnesium bromide, 3.2M solution in 2-Methyltetrahydrofuran 75-16-1
5-Bromo-2-hydroxybenzaldehyde 1761-61-1
Methyl 2-(aminosulfonyl)benzoate 57683-71-3
Zinc sulfate monohydrate 7446-19-7
Sodium phosphate, tribasic 7601-54-9
Calcium phosphate, dibasic dihydrate 7789-77-7
Pyrophosphoric acid 2466-09-3
(4(S)-TRANS)-4,5-DIHYDROXY-3-OXO- CYCLOHEXENE-1-CARBOXYLIC ACID, 98+% (HPLC) 2922-42-1
Phenoxytrimethylsilane 1529-17-5
Allyltrimethoxysilane 2551-83-9
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole 269410-08-4
1-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole 761446-44-0
Graphite, fluorinated 51311-17-2
Hafnium(IV) fluoride 13709-52-9
Neodymium(III) fluoride 13709-42-7
6-(2-Morpholinoethylamino)pyridine-3-boronic acid pinacol ester Not available
Bromine-1,4-dioxane complex 15481-39-7
Iodoacetyl chloride 38020-81-4
Ruthenium tetroxide, 0.5% solution in water 20427-56-9
Sodium tert-pentoxide, 30% solution in THF 14593-46-5
8-Bromo-7-(2,3-dihydroxypropyl)-1,3-dimethyl-2,3,6,7-tetrahydro-1H-2,6-purinedione 111038-24-5
2-Amino-8-bromo-9-[3,4-dihydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl]-6,9-dihydro-1H-purin-6-one Not available
4-(Trifluoromethyl)-1,4,5,6-tetrahydropyridine-3-carboxamide 175204-83-8
(2R)-1-(tert-Butoxycarbonyl)hexahydropyridine-2-carboxylic acid 26250-84-0
2-(4-Pentylbenzoyl)-1-benzofuran-5-carbaldehyde 300665-10-5
N-Methyl-N-[4-(pyridin-2-yloxy)benzyl]amine 892501-90-5
{2-[2-(Dimethylamino)ethoxy]phenyl}methanol 59115-26-3
N-Methyl-4-(1H-pyrazol-1-ylmethyl)benzylamine 892502-08-8
N-Methyl-3-(1H-pyrazol-1-ylmethyl)benzylamine 892502-10-2



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