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Section 1 - Chemical Product and Company Identification |
MSDS Name: 1-Chlorobutane
Catalog Numbers:
AC154630000, AC154630010, AC154630025, AC154630200, AC154635000,
AC404550000, AC404550010, B416-1, B416-4, B416J-1, B429-4, B429-4LC,
B429J-4, B429SK-4
Synonyms:
n-Butyl chloride.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 109-69-3 |
1-Chlorobutane |
99+ | 203-696-6 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: -12 deg C.
Danger! Flammable liquid and vapor. May cause eye,
skin, and respiratory tract irritation. May cause central nervous
system depression.
Target Organs: Blood, central nervous system.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed. May cause central nervous system depression.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause respiratory tract irritation. May be harmful if
inhaled.
Chronic:
Adverse reproductive effects have been reported in animals.
Laboratory experiments have resulted in mutagenic effects. Chronic
exposure may cause blood effects. Animal studies have reported the
development of tumors.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation develo
ps, get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Extremely flammable. Material will readily
ignite at room temperature. Containers may explode in the heat of a
fire. Flammable liquid and vapor.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog or
alcohol-resistant foam.
Flash Point: -12 deg C ( 10.40 deg F)
Autoignition Temperature: 460 deg C ( 860.00 deg F)
Explosion Limits, Lower:1.0 vol %
Upper: 10.1 vol %
NFPA Rating:
(estimated) Health: 1; Flammability: 3; Instability: 1
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wear a self contained breathing
apparatus and appropriate personal protection. (See Exposure
Controls, Personal Protection section). Remove all sources of
ignition. Use a spark-proof tool. Do not let this chemical enter the
environment.
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Section 7 - Handling and Storage
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Handling:
Use spark-proof tools and explosion proof equipment. Do not get in
eyes, on skin, or on clothing. Keep away from heat, sparks and flame.
Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use only under a chemical fume hood.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| 1-Chlorobutane
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
1-Chlorobutane:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear, colorless
Odor: none reported
pH: Not available.
Vapor Pressure: 108 mbar @ 20 deg C
Vapor Density: 3.19 (air=1)
Evaporation Rate:Not available.
Viscosity: 0.45 mPa @ 20 deg C
Boiling Point: 77 - 78 deg C @ 760 mmHg
Freezing/Melting Point:-123 deg C
Decomposition Temperature:Not available.
Solubility: 0.5 g/L (20癈)
Specific Gravity/Density:0.880
Molecular Formula:C4H9Cl
Molecular Weight:92.57
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
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Section 11 - Toxicological Information
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RTECS#:
CAS# 109-69-3:
EJ6300000
LD50/LC50:
CAS# 109-69-3:
Oral, mouse: LD50 =
5600 mg/kg;
Oral, rat: LD50 = 2200
mg/kg;
.
Carcinogenicity:
CAS# 109-69-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Tumorigenic effects have been reported in experimental
animals.
Teratogenicity:
Teratogenic effects have occurred in experimental animals.
Reproductive Effects:
Adverse reproductive effects have occurred in experimental
animals.
Mutagenicity:
Mutagenic effects have occurred in experimental animals.
Neurotoxicity:
No information available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
Daphnia: Daphnia: 452 mg/L; 48 Hrs.; Directive 84/449/EEC,
C.2Bacteria: Pseudomonas putida: 375 mg/L; 18 Hrs.;
Bringmann-Kuhn test
No data available.
Environmental:
No information available.
Physical:
No information available.
Other:
Do not empty into drains.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
CHLOROBUTANES |
CHLOROBUTANES |
| Hazard Class: |
3 |
3 |
| UN Number: |
UN1127 |
UN1127 |
| Packing Group: |
II |
II |
| Additional Info: | | FLASHPOINT -12C |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 109-69-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 109-69-3: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 109-69-3 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 29 Do not empty into drains.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 109-69-3: 2
Canada - DSL/NDSL
CAS# 109-69-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 11/03/1998
Revision #6 Date: 1/29/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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