Section 1 - Chemical Product and Company Identification |
MSDS Name: 1-Bromobutane
Catalog Numbers:
AC106770000, AC106770010, AC106770050, AC106770500, AC106772500,
AC219710000, AC219710050, AC219710500, B400-500
Synonyms:
n-Butyl bromide.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
109-65-9 |
1-Bromobutane |
98+ | 203-691-9 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear colorless to light yellow liquid. Flash Point: 10 deg C.
Danger! Flammable liquid and
vapor. Causes eye, skin, and respiratory tract
irritation.
Target Organs: Kidneys, central nervous system,
liver, respiratory system, eyes, skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause nausea and
vomiting. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May cause pulmonary edema and
severe respiratory disturbances. May be harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause liver and kidney damage. Prolonged or repeated
exposure may cause nausea, dizziness, and headache.
Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Containers may explode in the heat of a fire.
Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: 10 deg C ( 50.00 deg F)
Autoignition Temperature: 265 deg C ( 509.00 deg F)
Explosion Limits, Lower:2.6 vol %
Upper: 7 vol %
NFPA Rating:
(estimated) Health: 2; Flammability: 3; Instability: 0
Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wear a self contained breathing
apparatus and appropriate personal protection. (See Exposure
Controls, Personal Protection section). Remove all sources of
ignition. Use a spark-proof tool. Do not let this chemical enter the
environment.
Section 7 - Handling and Storage
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Handling:
Use spark-proof tools and explosion proof equipment. Do not get in
eyes, on skin, or on clothing. Take precautionary measures against
static discharges. Keep away from heat, sparks and flame. Do not
ingest or inhale. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use only under a chemical fume hood.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
1-Bromobutane
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
1-Bromobutane:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear colorless to light yellow
Odor: characteristic odor
pH: Not available.
Vapor Pressure: 34 mm Hg @ 20 deg C
Vapor Density: 4.72
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 100 - 104 deg C @ 760 mmHg
Freezing/Melting Point:-112 deg C
Decomposition Temperature:Not available.
Solubility: 0.608 g/L (30°C)
Specific Gravity/Density:1.270
Molecular Formula:C4H9Br
Molecular Weight:137.02
Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, active metals, alkali metals,
magnesium, potassium, sodium.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
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RTECS#:
CAS# 109-65-9:
EJ6225000
LD50/LC50:
CAS# 109-65-9: Inhalation, mouse:
LC50 = 25000 mg/m3/2H; Inhalation,
rat: LC50 = 47000 mg/m3/2H; Oral,
rat: LD50 = 2761 mg/kg; .
Carcinogenicity:
CAS# 109-65-9:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
No data available.
Physical:
No data available.
Other:
Do not empty into drains.
Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
1-BROMOBUTANE |
1-BROMOBUTATE |
Hazard Class: |
3 |
3 |
UN Number: |
UN1126 |
UN1126 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 109-65-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 109-65-9: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 109-65-9 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection)
CAS# 109-65-9: 2
Canada - DSL/NDSL
CAS# 109-65-9 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 109-65-9 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 12/12/1997 Revision #9 Date: 4/02/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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