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Section 1 - Chemical Product and Company Identification |
MSDS Name: m-Phenylenediamine
Catalog Numbers:
AC130560000, AC130560010, AC130560250, AC130562500, AC130565000
Synonyms:
1,3-Diaminobenzene.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 108-45-2 |
m-Phenylenediamine |
99+ | 203-584-7 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: brown-gray solid.
Danger! Toxic if swallowed, inhaled or absorbed
through the skin. Causes eye irritation. Possible risks of
irreversible effects. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment. May cause sensitization
by skin contact.
Target Organs: Kidneys, central nervous system.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation. Toxic in contact with skin. May cause
sensitization by skin contact.
Ingestion:
May cause irritation of the digestive tract. Toxic if swallowed.
Inhalation:
May cause respiratory tract irritation. Toxic if inhaled.
Chronic:
Adverse reproductive effects have been reported in animals.
Laboratory experiments have resulted in mutagenic effects. Repeated
or prolonged exposure may cause allergic reactions in sensitive
individuals. May cause kidney damage. Exposure to high
concentrations may cause central nervous system depression. Animal
studies have reported the development of tumors. Possible risk of
irreversible effects.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
POISON material. If swallowed, get medical aid immediately. Only
induce vomiting if directed to do so by medical personnel. Never give
anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors or dust may form explosive mixture with air.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: 175 deg C ( 347.00 deg F)
Autoignition Temperature: 530 deg C ( 986.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 1; Instability: 1
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Wear a self contained breathing apparatus and appropriate
personal protection. (See Exposure Controls, Personal Protection
section). Avoid generating dusty conditions. Provide ventilation.
Evacuate unnecessary personnel. Do not let this chemical enter the
environment.
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Section 7 - Handling and Storage
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Handling:
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Do not ingest or inhale. Use only in a
chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store protected from light. Store under nitrogen.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| m-Phenylenediamine
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0.1 mg/m3 TWA
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none listed
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none listed
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OSHA Vacated PELs:
m-Phenylenediamine:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Solid
Appearance: yellow - light tan - brown-gray
Odor: amine-like
pH: 8 (100g/L aq.sol.)
Vapor Pressure: 1.3 hPa @ 100 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 282 - 284 deg C @ 760 mmHg
Freezing/Melting Point:63 - 65 deg C
Decomposition Temperature:Not available.
Solubility: 350 g/L (25癈)
Specific Gravity/Density:Not available.
Molecular Formula:C6H8N2
Molecular Weight:108.14
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Section 10 - Stability and Reactivity
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Chemical Stability:
Darkens on exposure to light and air. Air sensitive. Light
sensitive.
Conditions to Avoid:
Incompatible materials, light, dust generation, exposure to air,
excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid chlorides, acid anhydrides,
chloroformates.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 108-45-2:
SS7700000
LD50/LC50:
CAS# 108-45-2:
Draize test,
rabbit, eye: 100 uL Severe;
Oral,
mouse: LD50 = 67700 ug/kg;
Oral,
rabbit: LD50 = 437 mg/kg;
Oral,
rat: LD50 = 280 mg/kg;
.
Carcinogenicity:
CAS# 108-45-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Tumorigenic effects have been reported in experimental
animals.
Teratogenicity:
Teratogenic effects have occurred in experimental animals.
Reproductive Effects:
Adverse reproductive effects have occurred in experimental
animals.
Mutagenicity:
Mutagenic effects have occurred in experimental animals.
Neurotoxicity:
No information found
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
Fish: Fathead Minnow: LC50 = 0.028 mg/L; 96 Hr.; UnspecifiedFish:
Rainbow trout: LC50 =3.9 mg/L; 96 Hr.; UnspecifiedFish: Goldfish:
LC50 =5.74 mg/L; 48 Hr.; UnspecifiedWater flea Daphnia: EC50 =
3.9 mg/L; 48 Hr.; Unspecified
The product is chemically identically to the natural amino acid
L-Serine and can therefore be degraded microbiologically.
Environmental:
An estimated BCF value of 0.33 was calculated for 1,3-benzenediamine,
using an estimated log Kow of -0.33 and a recommended
regression-derived equation. BCF values of 1.3 to 4.6 and <1.6 to 24
were measured for 1,3-benzenediamine in carp at 2 and 0.2 mg/l,
respectively. According to a classification scheme, these BCF values
suggest that bioconcentration in acquatic organisms is low.
Physical:
No information found.
Other:
The Koc of 1,3-benzenediamine is estimated as approximately 16, using
a measured log Kow of -0.33 and a regression-derived equation.
According to a recommended classification scheme, this estimated Koc
value suggests that 1,3-benzenediamine is expected to have very high
mobility in soil. However, anilines are expected to bind strongly to
humus or organic matter in soils due to the high reactivity of the
aromatic amino group; therefore, mobility may be much lower in some
soils.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
PHENYLENEDIAMINES |
PHENYLENEDIAMINES |
| Hazard Class: |
6.1 |
6.1 |
| UN Number: |
UN1673 |
UN1673 |
| Packing Group: |
III |
III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 108-45-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
CAS# 108-45-2: 40 CFR 799.3300
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
This material contains
m-Phenylenediamine (CAS# 108-45-2, 99+%),which is subject to the
reporting requirements of Section 313 of SARA Title III and 40 CFR
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 108-45-2 can be found on the
following state right to know lists: New Jersey, Minnesota,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin and if
swallowed.
R 36 Irritating to eyes.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R 68 Possible risk of irreversible effects.
Safety Phrases:
S 36/37 Wear suitable protective clothing and gloves.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 60 This material and its container must be disposed of as hazardou
s waste.
S 28A After contact with skin, wash immediately with plenty of water
.
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 108-45-2: 2
Canada - DSL/NDSL
CAS# 108-45-2 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1B, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 108-45-2 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 5/19/1999
Revision #7 Date: 2/19/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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