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Section 1 - Chemical Product and Company Identification |
MSDS Name: 2,6-Dimethylphenol
Catalog Numbers:
AC116560000, AC116560050, AC116561000, AC116565000, AC116570000, AC116570010
AC116570010, AC116570025, AC116570050, AC116572500
Synonyms:
2,6-Xylenol.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 576-26-1 |
2,6-Dimethylphenol |
99 | 209-400-1 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless to yellow brown low melting solid. Flash Point: 73 deg C.
Danger! Toxic if absorbed through the skin. Toxic
if swallowed. Causes burns by all exposure routes. Toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment. Material is a solid at room temperature that melts upon
moderate heating into a combustible liquid with a flash point below
200癋(93.3癈).
Target Organs: Blood, kidneys, central nervous
system, liver, spleen, respiratory system, gastrointestinal system,
eyes, skin.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Substance is rapidly absorbed through the skin.
Toxic in contact with skin. If absorbed, may cause central nervous
system effects. May cause erythema (redness) and blistering.
Ingestion:
Causes gastrointestinal tract burns. May cause central nervous
system effects. May cause convulsions, seizures and death. Toxic if
swallowed. May cause tremors, weakness, muscular spasms and ataxia
(failure of muscular coordination).
A case of fatal xylenol ingestion by a long stay mental hospital
patient is described. Clinical course was similar to that observed
in other phenolic poisonings with active bowel sounds, nausea, and
vomiting. Severe metabolic acidosis, hypotension, and cardiac and
renal failure.
Inhalation:
Causes chemical burns to the respiratory tract. May cause adverse
central nervous system effects including headache, convulsions, and
possible death. Inhalation may be fatal as a result of spasm,
inflammation, edema of the larynx and bronchi, chemical pneumonitis
and pulmonary edema. May be harmful if inhaled.
Chronic:
May cause liver and kidney damage. Repeated exposure may cause
damage to the spleen. Chronic exposure may cause blood effects.
Exposure to high concentrations may cause central nervous system
depression. Animal studies have reported the development of tumors.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
POISON material. If swallowed, get medical aid immediately. Only
induce vomiting if directed to do so by medical personnel. Never give
anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Containers may
explode in the heat of a fire. Material is a solid at room
temperature that melts upon moderate heating into a combustible
liquid with a flash point below 200癋(93.3癈).
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
Flash Point: 73 deg C ( 163.40 deg F)
Autoignition Temperature: 555 deg C ( 1,031.00 deg F)
Explosion Limits, Lower:1.4 vol %
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 2; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wear a self contained breathing apparatus and appropriate personal
protection. (See Exposure Controls, Personal Protection section).
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Avoid generating dusty conditions.
Remove all sources of ignition. Use a spark-proof tool. Do not let
this chemical enter the environment.
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Section 7 - Handling and Storage
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Handling:
Use spark-proof tools and explosion proof equipment. Do not get in
eyes, on skin, or on clothing. Keep away from heat, sparks and flame.
Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use only under a chemical fume hood.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| 2,6-Dimethylphenol
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
2,6-Dimethylphenol:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Low melting solid
Appearance: colorless to yellow brown
Odor: sweetish odor
pH: 6-7 (5 g/L aq.sol.)
Vapor Pressure: 0.1 mbar @ 20 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 203 deg C @ 760 mm Hg
Freezing/Melting Point:45 - 48 deg C
Decomposition Temperature:Not available.
Solubility: 10 g/L (20癈)
Specific Gravity/Density:1.150
Molecular Formula:C8H10O
Molecular Weight:122.17
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, bases, acid chlorides, acid anhydrides,
brass, copper, copper alloys, steel.
Hazardous Decomposition Products:
Carbon monoxide, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 576-26-1:
ZE6125000
LD50/LC50:
CAS# 576-26-1:
Draize test,
rabbit, eye: 100 mg;
Oral, mouse:
LD50 = 450 mg/kg;
Oral, mouse:
LD50 = 450000 mg/m3;
Oral, rabbit:
LD50 = 700 mg/kg;
Oral, rabbit:
LD50 = 700000 mg/m3;
Oral, rat:
LD50 = 296 mg/kg;
Oral, rat: LD50
= 296000 mg/m3;
Skin, rabbit: LD50
= 1 gm/kg;
Skin, rabbit: LD50 =
1000000 mg/m3;
Skin, rat: LD50 =
2325 mg/kg;
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Carcinogenicity:
CAS# 576-26-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Tumorigenic effects have been reported in experimental
animals.
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
Fish: Fathead Minnow: >27mg/L; 96H; Freshwater
No data available.
Environmental:
Terrestrial: Should display high mobility. Other dimethylphenols have
been reported to degrade from soil. Aquatic: Expected to undergo
rapid biodegradation. Loss due to volatilization should be
insignificant and adsorption onto sediment should not be expected.
Atmospheric: Would be expected to rapidly degrade by reaction with
photochemically produced hydroxyl radicals; the half-life can be
estimated at 7.1 hr. Expected slight bioconcentration.
Physical:
No information available.
Other:
Do not empty into drains.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
TOXIC SOLIDS, CORROSIVE, ORGANIC, N.O.S. |
TOXIC SOLIDS, CORROSIVE, ORGANIC, |
| Hazard Class: |
6.1 |
6.1 |
| UN Number: |
UN2928 |
UN2928 |
| Packing Group: |
II |
II |
| Additional Info: | | N.O.S. |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 576-26-1 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 576-26-1: immediate.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 576-26-1 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T N
Risk Phrases:
R 34 Causes burns.
R 24/25 Toxic in contact with skin and if swallowed.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 576-26-1: 2
Canada - DSL/NDSL
CAS# 576-26-1 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B4, D1B, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 4/16/1999
Revision #5 Date: 3/24/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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