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Section 1 - Chemical Product and Company Identification |
MSDS Name: Allyl bromide, stabilized
Catalog Numbers:
AC102900000, AC102900025, AC102900050, AC102900500, AC102902500, AC102905000
AC102905000
Synonyms:
3-Bromopropene.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 106-95-6 |
Allyl bromide |
99 | 203-446-6 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: -1 deg C.
Danger! Flammable liquid and vapor. Toxic if
inhaled. Toxic if swallowed. Causes burns by all exposure routes.
Stench. Very toxic to aquatic organisms.
Target Organs: Respiratory system,
gastrointestinal system, eyes, skin.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns. May be harmful if absorbed through the skin.
Ingestion:
Causes gastrointestinal tract burns. Toxic if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract. Toxic if inhaled.
Chronic:
Laboratory experiments have resulted in mutagenic effects.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Call a poison
control center.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Containers may explode in the heat of a fire.
Flammable liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. Water may be ineffective.
Flash Point: -1 deg C ( 30.20 deg F)
Autoignition Temperature: 295 deg C ( 563.00 deg F)
Explosion Limits, Lower:4.4
Upper: 7.3
NFPA Rating:
(estimated) Health: 3; Flammability: 3; Instability: 1
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wear a self contained breathing
apparatus and appropriate personal protection. (See Exposure
Controls, Personal Protection section). Remove all sources of
ignition. Do not let this chemical enter the environment.
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Section 7 - Handling and Storage
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Handling:
Use spark-proof tools and explosion proof equipment. Do not get in
eyes, on skin, or on clothing. Keep away from heat, sparks and flame.
Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use only under a chemical fume hood.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Allyl bromide
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none listed
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none listed
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none listed
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| Propylene oxide
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2 ppm TWA
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400 ppm IDLH
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100 ppm TWA; 240 mg/m3 TWA
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OSHA Vacated PELs:
Allyl bromide:
No OSHA Vacated PELs are listed for this chemical.
Propylene oxide:
20 ppm TWA; 50 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear, colorless
Odor: stench
pH: Not available.
Vapor Pressure: 147 mbar @ 20 deg C
Vapor Density: 4.2
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 70 - 71 deg C @ 760 mmHg
Freezing/Melting Point:-119 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:1.390
Molecular Formula:C3H5Br
Molecular Weight:120.98
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Section 10 - Stability and Reactivity
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Chemical Stability:
Light sensitive.
Conditions to Avoid:
Incompatible materials, light, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: May occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 106-95-6:
UC7090000
CAS# 75-56-9:
TZ2975000
LD50/LC50:
CAS# 106-95-6:
Inhalation, mouse:
LC50 = 4110 mg/m3/2H;
Inhalation,
rat: LC50 = 10 gm/m3/30M;
Inhalation, rat: LC50 = 10000
mg/m3/2H;
Oral, rat: LD50 = 120
mg/kg;
.
CAS# 75-56-9:
Draize test,
rabbit, eye: 20 mg Severe;
Draize
test, rabbit, eye: 20 mg/24H Moderate;
Draize test, rabbit, skin: 50 mg/6M
Severe;
Inhalation, mouse: LC50 =
1740 ppm/4H;
Inhalation, rat: LC50
= 4000 ppm/4H;
Oral, mouse: LD50 =
440 mg/kg;
Oral, rat: LD50 = 380
mg/kg;
Skin, rabbit: LD50 = 1500
uL/kg;
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Carcinogenicity:
CAS# 106-95-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 75-56-9:
- ACGIH:
A3 - Confirmed animal carcinogen with unknown relevance to humans
- California:
carcinogen, initial date 10/1/88
- NTP:
Suspect carcinogen
- IARC:
Group 2B carcinogen
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
Mutagenic effects have occurred in humans.
Neurotoxicity:
No information available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
Rapidly volatilizes into atmosphere.
Physical:
No information available.
Other:
Do not empty into drains.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
ALLYL BROMIDE |
ALLYL BROMIDE |
| Hazard Class: |
3 |
3(6.1) |
| UN Number: |
UN1099 |
UN1099 |
| Packing Group: |
I |
I |
| Additional Info: | | FLASHPOINT 1癈 |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 106-95-6 is listed on the TSCA inventory.
CAS# 75-56-9 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 75-56-9: Effective 10/4/82, Sunset 10/4/92
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 75-56-9: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
CAS# 75-56-9: 10000 lb TPQ
SARA Codes
CAS # 106-95-6: immediate, fire, reactive.
CAS # 75-56-9: immediate, delayed, fire, reactive.
Section 313
This material contains Propylene
oxide (CAS# 75-56-9, -%),which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 75-56-9 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 75-56-9 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 106-95-6 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
CAS# 75-56-9 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
WARNING: This product contains Propylene oxide, a chemical known to
the state of California to cause cancer.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T F N
Risk Phrases:
R 11 Highly flammable.
R 23/25 Toxic by inhalation and if swallowed.
R 34 Causes burns.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 106-95-6: No information available.
CAS# 75-56-9: 2
Canada - DSL/NDSL
CAS# 106-95-6 is listed on Canada's DSL List.
CAS# 75-56-9 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D1A, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 106-95-6 is listed on the Canadian Ingredient Disclosure List.
CAS# 75-56-9 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 4/17/1998
Revision #4 Date: 1/25/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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