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Section 1 - Chemical Product and Company Identification |
MSDS Name: 2-Ethylhexylamine 99%
Catalog Numbers:
AC271660000, AC271660010, AC271660050, AC271662500
Synonyms:
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 104-75-6 |
2-Ethylhexylamine |
99 | 203-233-8 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear liquid. Flash Point: 50 deg C.
Warning! Corrosive. Flammable liquid and
vapor. Causes digestive and respiratory tract
irritation with possible burns. Harmful if swallowed or absorbed
through the skin. Causes eye and skin irritation and possible burns.
Target Organs: Kidneys, liver.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
Harmful if absorbed through the skin. Causes severe skin irritation
and possible burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause burns to the
gastrointestinal tract.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Vapors may cause dizziness
or suffocation.
Chronic:
May cause liver and kidney damage. Prolonged exposure may cause
systemic effects.
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Section 4 - First Aid Measures
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Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Flammable liquid and vapor. Vapors may
be heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
Use dry chemical, carbon dioxide, or alcohol-resistant foam. Contact
professional fire-fighters immediately.
Flash Point: 50 deg C ( 122.00 deg F)
Autoignition Temperature: 295 deg C ( 563.00 deg F)
Explosion Limits, Lower:.80 vol %
Upper: 6.00 vol %
NFPA Rating:
2 - health, 2 - flammability, 0 - instability
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation. Cover with a 90:10
mixture of sand/soda ash. Place in a container. Flush area with
water.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Do not ingest
or inhale. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a cool,
dry, well-ventilated area away from incompatible substances. Keep
away from strong acids. Flammables-area.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| 2-Ethylhexylamine
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
2-Ethylhexylamine:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear
Odor: musky, ammonia odor
pH: Not available.
Vapor Pressure: 1.6 hPa @ 20 C
Vapor Density: 4.45
Evaporation Rate:Not available.
Viscosity: 1.1 MPA 20.00 deg C
Boiling Point: 169 deg C @ 760.00mm Hg
Freezing/Melting Point:-76 deg C
Decomposition Temperature:Not available.
Solubility: 2.5 g/l (20 c)
Specific Gravity/Density:.7890g/cm3
Molecular Formula:C8H19N
Molecular Weight:129.25
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, metals, excess heat, electrical sparks, exposure to
flame.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, alcohols, aluminum, copper,
vinyl acetate, zinc, tin, aldehydes (e.g. acetaldehyde, acrolein,
chloral hydrate, formaldehyde), isocyanates (e.g. methyl
isocyanate), ketones (e.g. acetone, acetophenone, MEK, MIBK), lead,
organic anhydrides.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 104-75-6:
MQ5250000
LD50/LC50:
CAS# 104-75-6:
Draize test,
rabbit, eye: 50 ug/24H Severe;
Draize test, rabbit, skin: 750 ug/24H
Severe;
Oral, rat: LD50 = 450
mg/kg;
Skin, rabbit: LD50 = 600
uL/kg;
.
Carcinogenicity:
CAS# 104-75-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
2-ETHYLHEXYLAMINE |
2-ETHYLHEXYLAMINE |
| Hazard Class: |
3 |
8 |
| UN Number: |
UN2276 |
UN2276 |
| Packing Group: |
III |
III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 104-75-6 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 104-75-6 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with skin and if
swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36 Wear suitable protective clothing.
WGK (Water Danger/Protection)
CAS# 104-75-6: 2
Canada - DSL/NDSL
CAS# 104-75-6 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 104-75-6 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 5/05/1998
Revision #4 Date: 3/15/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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