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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 07/12/2005 Reviewed on 04/24/2005
1 Identification of substance:
Product details:
Product name: Lead titanium oxide
Stock number: 35671
Manufacturer/Supplier:
Alfa Aesar, A Johnson Matthey Company
Johnson Matthey Catalog Company, Inc.
30 Bond Street
Ward Hill, MA 01835-8099
Emergency Phone: (978) 521-6300
CHEMTREC: (800) 424-9300
Web Site: www.alfa.com
Information Department: Health, Safety and Environmental Department
Emergency information:
During normal hours the Health, Safety and Environmental Department.
After normal hours call Chemtrec at (800) 424-9300.
2 Composition/Data on components:
Chemical characterization:
Description: (CAS#)
Lead titanium oxide (CAS# 12060-00-3); 100%
Identification number(s):
EINECS Number: 235-038-9
EU Number: 082-001-00-6
3 Hazards identification
Hazard description:
T Toxic
N Dangerous for the environment
Information pertaining to particular dangers for man and environment
R 61 May cause harm to the unborn child
R 62 Possible risk of impaired fertility
R 20/22 Harmful by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH 2 Health (acute effects) = 2
Flammability = 0
FIRE 0
Reactivity = 0
REACTIVITY 0
4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep
patient warm.
Seek immediate medical advice.
(Contd. on page 2)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 07/12/2005 Reviewed on 04/24/2005
Product name: Lead titanium oxide
(Contd. of page 1)
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a
doctor.
After swallowing Seek immediate medical advice.
5 Fire fighting measures
Suitable extinguishing agents
Product is not flammable. Use fire fighting measures that suit the
surrounding fire.
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
6 Accidental release measures
Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Measures for environmental protection:
Do not allow material to be released to the environment without proper
governmental permits.
Measures for cleaning/collecting:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Additional information:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
Handling
Information for safe handling:
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
The product is not flammable
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
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(Contd. on page 3)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 07/12/2005 Reviewed on 04/24/2005
Product name: Lead titanium oxide
(Contd. of page 2)
8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals
and having an average face velocity of at least 100 feet per minute.
Components with limit values that require monitoring at the workplace:
Lead, elemental, and inorganic compounds (as Pb)
mg(Pb)/m3
ACGIH TLV 0.05; Confirmed animal carcinogen
Austria MAK 0.1
Belgium TWA 0.15
Denmark TWA 0.1
Germany MAK 0.1
Japan OEL 0.1
Korea TLV 0.05; Confirmed animal carcinogen
Netherlands TWA 0.15
Norway TWA 0.05
Poland TWA 0.05
Sweden TWA 0.05 (resp. dust)
0.1 (total dust)
Switzerland MAK-W 0.1
United Kingdom TWA 0.1
USA PEL 0.05
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be
followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Refer to 29CFR1910.1025 for regulations on respiratory protection
required during exposure to lead and lead compounds.
Protection of hands: Impervious gloves
Eye protection: Safety glasses
Body protection: Protective work clothing.
9 Physical and chemical properties:
General Information
Form: Powder
Color: Yellow
Odor: Odorless
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: Not applicable
Ignition temperature: Not determined
(Contd. on page 4)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 07/12/2005 Reviewed on 04/24/2005
Product name: Lead titanium oxide
(Contd. of page 3)
Decomposition temperature: Not determined
Danger of explosion: Product does not present an
explosion hazard.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not determined
Density at 20掳C (68掳F): 7.52 g/cm鲁
Solubility in / Miscibility with
Water: Insoluble
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to
specifications.
Materials to be avoided: None known.
Dangerous reactions No dangerous reactions known
Dangerous products of decomposition: Toxic metal compounds
11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral LD50 >12000 mg/kg (rat)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Other information (about experimental toxicology):
Reproductive effects have been observed on tests with laboratory animals.
Subacute to chronic toxicity:
Lead and lead compounds may cause abdominal pain, diarrhea, loss of
appetite, metallic taste, nausea, vomiting, lassitude, insomnia, muscle
weakness, joint and muscle pain, irritability, headache and dizziness.
Red blood cells may be damaged resulting in anemia. Gastritis and injury
to the kidneys, liver, male gonads, and central nervous system may also
occur.
Additional toxicological information:
May cause harm to the unborn child.
Possible risk of impaired fertility.
To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
EPA-B2: Probable human carcinogen, sufficient evidence from animal
studies; inadequate evidence or no data from epidemiologic studies.
IARC-2B: Possibly carcinogenic to humans: limited evidence in humans in
the absence of sufficient evidence in experimental animals.
NTP-2: Reasonably anticipated to be a carcinogen: limited evidence from
studies in humans or sufficient evidence from studies in experimental
animals.
ACGIH A3: Animal carcinogen: Agent is carcinogenic in experimental
animals at a relatively high dose, by route(s) of administration, at
site(s), of histologic type(s), or by mechanism(s) not considered
(Contd. on page 5)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 07/12/2005 Reviewed on 04/24/2005
Product name: Lead titanium oxide
(Contd. of page 4)
relevant to worker exposure. Available epidemologic studies do not
confirm an increased risk of cancer in exposed humans. Available
evidence suggests that the agent is not likely to cause cancer in humans
except under uncommon or unlikely routes or levels of exposure.
12 Ecological information:
Ecotoxical effects:
Remark: Very toxic for fish
General notes:
Also poisonous for fish and plankton in water bodies.
Do not allow material to be released to the environment without proper
governmental permits.
Very toxic for aquatic organisms
13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
14 Transport information
Not a hazardous material for transportation.
DOT regulations:
Hazard class: None
Land transport ADR/RID (cross-border)
ADR/RID class: None
Maritime transport IMDG:
IMDG Class: None
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: None
Transport/Additional information:
Not dangerous according to the above specifications.
15 Regulations
Product related hazard informations:
Hazard symbols:
T Toxic
N Dangerous for the environment
Risk phrases:
61 May cause harm to the unborn child
62 Possible risk of impaired fertility
20/22 Harmful by inhalation and if swallowed.
33 Danger of cumulative effects.
(Contd. on page 6)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 07/12/2005 Reviewed on 04/24/2005
Product name: Lead titanium oxide
(Contd. of page 5)
50/53 Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
Safety phrases:
53 Avoid exposure - obtain special instructions before use.
45 In case of accident or if you feel unwell, seek medical advice
immediately.
60 This material and its container must be disposed of as hazardous
waste.
61 Avoid release to the environment. Refer to special instructions/Safety
data sheets
National regulations
All components of this product are listed in the U.S. Environmental
Protection Agency Toxic Substances Control Act Chemical substance
Inventory.
All components of this product are listed on the Canadian Domestic
Substances List (DSL).
Information about limitation of use:
For use only by technically qualified individuals.
This product contains lead and is subject to the reporting requirements
of section 313 of the Emergency Planning and Community Right to Know Act
of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Refer to 29CFR1910.1025 for regulations concerning lead and lead
compounds.
16 Other information:
Employers should use this information only as a supplement to other
information gathered by them, and should make independent judgement of
suitability of this information to ensure proper use and protect the
health and safety of employees. This information is furnished without
warranty, and any use of the product not in conformance with this
Material Safety Data Sheet, or in combination with any other product or
process, is the responsibility of the user.
Department issuing MSDS: Health, Safety and Environmental Department.
Contact: Darrell R. Sanders
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