Material Safety Data Sheet 3/16/2006
Issue Date:
MSDS Number: TN310 Product Name: H24SP1 Toner Revision: [00]03/16/2006
Section 1 - Chemical Product and Company Identification
Product Name: H24SP1 Toner Chemical Formula NA
NA (mixture) General Use: Toner
CAS Number:
Future Graphics LLC Part Number: HP1160MKI10KG
Same as Manufacturer
Mitsubishi Kagaku Imaging Corporation
Company Name: Distributor:
Health 1
401 Volvo Parkway Same as Manufacturer
Street Address: Street Address:
Fire 1
Chesapeake Same as Manufacturer
Town: Town:
Virginia Same as Manufacturer
State: State: Reactivity 0
23320 Same as Manufacturer
Zip Code: Zip Code:
PPE (See Sec. 8)
Chemtrec 1-800-424-9300 757-382-5750
Emergency Contacts: Other Contacts:
<<<>>> EMERGENCY OVERVIEW <<<>>>
This product may cause irritation of the respiratory system, eyes, and skin. This product
is stable under normal conditions of use.
Section 2 - Composition and Information on Ingredients
Ingredient Iron Oxide - Black Pigment CAS No. Proprietary % in Mixture 35-55
OSHA ACGIH NIOSH UNIT OF MEASURE
TWA 10 5 5 mg/cu.meter
STEL NE NE NE mg/cu.meter
IDLH NA NA 2500 mg/cu.meter
Ingredient Styrene Acrylate Copolymer CAS No. Proprietary % in Mixture 40-60
OSHA ACGIH NIOSH UNIT OF MEASURE
NE NE NE mg/cu.meter
TWA
NE NE NE mg/cu.meter
STEL
NA NA NE mg/cu.meter
IDLH
Ingredient Wax CAS No. Proprietary % in Mixture 1-10
OSHA ACGIH NIOSH UNIT OF MEASURE
TWA NE 2 2 mg/cu.meter
STEL NE NE NE mg/cu.meter
IDLH NA NA NE mg/cu.meter
* TOTAL DUST / INHALABLE DUST
** RESPIRABLE DUST
*** Refer to Section 11 - Toxicological Information
OVERALL MIXTURE:
This product is a mixture of dry chemical components. OSHA regulatory limits set for PARTICULATES NOT
MSDS Printed On: Monday, August 21, 2006 MSDS Number: TN310 Page 1 of 8
OTHERWISE CLASSIFIED are: 15 mg/cu.meter for TOTAL DUST / INHALABLE DUST and 5 mg/cu.meter for
RESPIRABLE DUST.
Section 3 - Hazards Identification
Primary Entry Routes:
Absorption, Inhalation
Target Organs:
NA
Inhalation Effects:
Slight irritation of respiratory tract.
Eye Effects:
Dust may cause irritation by mechanical abrasion.
Skin Effects:
May cause skin irritation.
Ingestion Effects:
NA
Carcinogenicity:
NA
Medical Conditions Aggravated by Long-term Exposure:
Accumulation of dust in the respiratory system may cause moderate congestion.
Chronic Effects and/or Recommendations:
If use generates airborne particles, treat as a NUISANCE PARTICULATE (ACGIH TLV = 10 mg/cu. meter).
Section 4 - First Aid Measures
Inhalation:
Protect yourself with appropriate PPE, remove the person to fresh air. Decontaminate and begin rescue
breathing if breathing has stopped and CPR if heart action has stopped. Seek prompt medical attention.
Eye:
DO NOT allow victim to rub or keep eyes tightly shut. Gently lift eyelids and immediately flush eyes with large
amounts of water. Remove any contact lenses. Continue to flush for at least 30 minutes, occasionally lifting the
upper and lower lids. Seek prompt medical attention.
Skin:
Quickly remove contaminated clothing. Immediately wash area with large amounts of water. Seek prompt
medical attention for any reddened skin other than from washing.
Ingestion:
Never give anything by mouth to an unconscious or convulsing person. Contact a Poison Control Center (PCC).
Unless the PCC advises otherwise, have the conscious and alert person drink 1 to 2 glasses of water to dilute.
Induce vomiting only after recent ingestions due to the possibility of seizures. Seek prompt medical attention.
Additional First Aid Information:
NA
Section 5 - Fire Fighting Measures
Flash Point: Flash Point Method:
NA NA
Flammability Classification: Auto Ignition Temperature:
1 Slight (HMIS, NFPA) ND
LEL: UEL: Burning Rate:
NA NA NA
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Extinguishing Media:
Water spray, dry chemical, foam, carbon dioxide, or halon-type extinguishers.
Unusual Fire / Explosion Hazards:
May form flammable dust-air mixture.
Hazardous Combustion Products:
Carbon monoxide, carbon dioxide, nitrogen oxide, and smoke. Under certain conditions some aliphatic
aldehydes and carboxylic acids may form.
Fire-Fighting Instructions:
Do not release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment:
Because fire may produce toxic thermal decomposition products, wear a self-contained breathing apparatus
(SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode.
Section 6 - Accidental Release Measures
Containment Method:
When cleaning up spilled material, keep unnecessary people away, isolate area, and deny entry until the spilled
material has been removed. Scoop up material and place in a chemical waste container. Suction up remaining
material using a high efficiency vacuum cleaner. Avoid suspending particles in the air. Extreme caution should
be used as material presents a slip hazard.
Reporting Requirements:
Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions:
Keep containers closed at all times. Avoid creating dust. Keep away from ignition sources.
Storage Requirements:
Product is prone to gradual oxidation which may reduce quality over time.
Regulatory Requirements:
Follow all applicable local, state, and Federal regulations.
Section 8 - Exposure Controls and Personal Protection
Ventilation
The best protection is to enclose operations and/or provide local exhaust ventilation at the site of chemical
release in order to maintain airborne concentrations of the product below OSHA PELs (See Section 2). Local
exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at
its source.
Respiratory Protection
IMPROPER USE OF RESPIRATORS IS DANGEROUS. Seek professional advice prior to respirator selection
and use. Follow OSHA respirator regulations (29 CFR 1910.134 and 1910.137) and, if necessary, wear a
NIOSH approved respirator. Select respirator based on its suitability to provide adequate worker protection for
given work conditions, level of airborne contamination, and presence of sufficient oxygen. For emergency or
non-routine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. WARNING! Air
purifying respirators do not protect worker in oxygen-deficient atmospheres. If respirators are used, OSHA
requires a written respiratory protection program that includes at least: medical certification, training, fit
testing, peroidic environmental monitoring, maintenance, inspection, cleaning and convenient, sanitary storage
areas.
Protective Clothing and Equipment
Wear chemically protective gloves, boots, aprons, and gauntlets to prevent prolonged or repeated skin contact.
Wear splash-proof chemical goggles and face shield when working with liquid, unless full facepiece respiratory
protection is worn. Contact lenses are not eye protective devices. Appropriate eye protection must be worn
MSDS Printed On: Monday, August 21, 2006 MSDS Number: TN310 Page 3 of 8
instead of, or in conjunction with contact lenses.
Safety Stations
Make emergency eyewash stations, safety/quick-drench showers, and washing facilities avalable in work area.
Contaminated Equipment
Separate contaminated work clothes from street clothes. Launder before reuse. Remove material from your shoes
and clean personal protective equipment. Never take home contaminated clothing.
Comments
Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially
before eating, drinking, smoking, using the restroom, or apply cosmetics.
Additional Information
NA
Section 9 - Physical and Chemical Properties
Freezing or Odor Physical
Melting Point: Threshold: State:
Boiling Point:
NA NA ND Solid
Refractive Vapor Density Appearance
Index: (Air = 1) and Odor:
Viscosity:
NA NA Heavier than Black, free-flowing powder, odorless.
air.
Surface Vapor Water
Tension: Pressures: Solubility:
% Volatiles:
NA NA NA Negligible
Evaporation Formula Other
Rate: Weight: Solubilities:
Density:
1.5-2.5 NA NA NA
Specifice Gravity where Additional
pH: Water = 1 at 4 deg C Comments:
NA NA NA
Section 10 - Stability and Reactivity
Stability: Polymerization: Hazardous Decomposition Products:
Stable under Hazardous NA
conditions of normal polymerization cannot
use. occur.
Chemical Incompatibilities:
NA
Conditions to Avoid:
NA
Other Comments:
NA
Section 11 - Toxicological Information
Checked box indicates that related health effects criteria applies to the overall mixture.
MSDS Printed On: Monday, August 21, 2006 MSDS Number: TN310 Page 4 of 8
Eye Effects Acute Oral Effects Acute Inhalation Effects Mutagenicity
Skin Effects Chronic Effects Carcinogenicity Teratogenicity
EXPLANATION of HEALTH EFFECTS:
Ames Test Negative
EXPLANATION of TOXICOLOGICAL CRITERIA:
Iron Oxide - Black Pigment
Chemical Component:
MAGNETITE: Toxicity Data: 400 mg/kg intrapleural-mouse TDLO
MEDCIAL CONDITIONS AGGRAVATED BY EXPOSURE: respiratory disorders
HEALTH EFFECTS:
INHALATION: MAGNETITE: See information on metal fume fever. Repeated or prolonged exposure,
greater than 10 years, may cause siderosis, a benign pneumoconiosis. Chronic bronchitis has been associated
with siderosis. Dyspnea may be pronounced and increases on exposure to irritants.
ACUTE EXPOSURE:
METAL FUME FEVER: Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly
formed metal oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns. Symptoms may
be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth.
Other symptoms may include upper respiratory tract irritation accompanied by coughing and dryness of the
mucous membranes, lassitude and a generalized feeling of malaise. Fever, chills, muscular pain, mild to severe
headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination,
diarrhea and prostration may also occur. Tolerance to fumes develops rapidly, but is quickly lost. All symptoms
usually subside within 24-36 hours.
CHRONIC EXPOSURE:
METAL FUME FEVER: There is no form of chronic metal fume fever; however, repeated bouts with symptoms
as described above are quite common. Resistance to the condition develops after a few days of exposure, but is
quickly lost in 1 or 2 days.
SKIN CONTACT:
ACUTE EXPOSURE: MAGNETITE: May cause irritation.
CHRONIC EXPOSURE: MAGNETITE: No data available.
EYE CONTACT:
ACTUTE EXPOSURE: MAGNETITE: May cause conjunctivitis, choroiditis, and retinitis. Iron particles
embedded in eye tissue may cause ocular siderosis. Discoloration of the iris is one of the earliest symptoms.
Siderosis may spread depending on the location of the particle. Rarely, ocular siderosis may cause glaucoma.
CHRONIC EXPOSURE: MAGNETITE: No data available.
INGESTION:
ACUTE EXPOSURE: MAGNETITE: No data available.
CHRONIC EXPOSURE: MAGNETITE: No data available.
Styrene Acrylate Copolymer
Chemical Component:
Data Not Available
MSDS Printed On: Monday, August 21, 2006 MSDS Number: TN310 Page 5 of 8
Wax
Chemical Component:
PARAFFIN WAX:
IRRITATION DATA:
500 mg/24(s) skin-rabbit mild; 100 mg/24 hour(s) eyes-rabbit mild
TUMORGENIC DATA:
120 mg/kg implant-rat TDLo; 640 mg/kg implant-mouse TD; 660 mg/kg implant-mouse TD; 560 mg/kg TD
HEALTH EFFECTS:
ACUTE EXPOSURE:
Fumes from heated paraffin wax may cause mild nose and throat irritation with nausea. Animals exposed to
paraffin vapors in a concentration sufficient to cause death within 2 hours became hyperactive and developed
clonic spasms and limb flexor muscle tetanic contractions which persisted until death.
CHRONIC EXPOSURE:
A 5 year occupational exposure to high concentrations of aerosolized paraffin wax caused dyspnea and
hypoxemia, progressing to lipoid pneumonia characterized pathologically by alveolitis involving large lipid-
laden macrophages and interstitial fibrosis.
SKIN CONTACT:
ACUTE EXPOSURE:
May cause mild irritation. Heated liquid may burn skin. Sensitization reactions have been reported.
CHRONIC EXPOSURE:
Development of foreign body skin granulomas has been reported following occupational exposure. Paraffin
wax, possibly impure, in the oil refining industry has been reported to act as a skin cancer promoter with a
latent period of 20 years.
EYE CONTACT:
ACUTE EXPOSURE:
Fumes may cause mild irritation. Heated wax may burn eyes.
CHRONIC EXPOSURE:
No data available
INGESTION:
ACUTE EXPOSURE:
Paraffin wax is not digested or absorbed.
CHRONIC EXPOSURE: No data available.
Section 12 - Ecological Information
Checked box indicates that information regarding the criteria applies to the overall mixture.
Ecotoxicity Environmental Fate Environmental Degradation Soil Absorption and Mobility
EXPLANATION of APPLICABLE ECOLOGICAL CRITERIA:
NA
Section 13 - Disposal Considerations
Disposal:
Waste material may be disposed of, incinerated, or recycled for its iron oxide under conditions that meet all
Federal, State and Local regulations. Contact your supplier or a licensed contractor for detailed recommendations.
Disposal Regulatory Requirements:
NA
Container Cleaning and Disposal:
NA
Section 14 - Transport Information
MSDS Printed On: Monday, August 21, 2006 MSDS Number: TN310 Page 6 of 8
DOT Transportation Data (49CFR 172.101)
Shipping Name: Label: Passenger Air and Railcar:
NA NA NA
Shipping Symbols: Special Provisions: Cargo Aircraft:
NA NA NA
Hazard Class: Exceptions: Oceangoing Vessel Stowage:
NA NA NA
ID Number: Non-bulk Packaging: Other:
NA NA NA
Packing Group: Bulk Packaging:
NA NA
EXPLANATION of APPLICATION TRANSPORTATION CRITERIA:
NA
Section 15 - Regulatory Information
Checked box(es) indicate that the chemical is subject to the associated regulatory requirements and/or appears
on the associated chemical inventory list
Chemical Component: Iron Oxide - Black Pigment Proprietary
CAS #
40 CFR 261.33 CAA 40 CFR 112 TSCA inventory (US)
40 CFR 261 classified AICS inventory (Australia)
SARA 40 CFR 311 and 312
RCRA Section 3001 EINECS inventory (Europe)
SARA 40 CFR 372.65
DSL inventory (Canada)
SARA 40 CFR 355
CERCLA RQ established
ECL inventory (Korea)
40 CFR 302.4
OSHA 1910 1000 Z-1 tables ENCS inventory (Japan)
CWA 40 CFR 311( b)(4) OSHA 1910 subpart Z PICCS inventory (Phillipines)
CWA 40 CFR 307(a) CHINA inventory
Chemical Component: Styrene Acrylate Copolymer Proprietary
CAS #
40 CFR 261.33 CAA 40 CFR 112 TSCA inventory (US)
40 CFR 261 classified AICS inventory (Australia)
SARA 40 CFR 311 and 312
RCRA Section 3001 EINECS inventory (Europe)
SARA 40 CFR 372.65
DSL inventory (Canada)
SARA 40 CFR 355
CERCLA RQ established
ECL inventory (Korea)
40 CFR 302.4
OSHA 1910 1000 Z-1 tables ENCS inventory (Japan)
CWA 40 CFR 311( b)(4) OSHA 1910 subpart Z PICCS inventory (Phillipines)
CWA 40 CFR 307(a) CHINA inventory
Chemical Component: Wax Proprietary
CAS #
40 CFR 261.33 CAA 40 CFR 112 TSCA inventory (US)
40 CFR 261 classified AICS inventory (Australia)
SARA 40 CFR 311 and 312
RCRA Section 3001 EINECS inventory (Europe)
SARA 40 CFR 372.65
DSL inventory (Canada)
SARA 40 CFR 355
CERCLA RQ established
ECL inventory (Korea)
40 CFR 302.4
OSHA 1910 1000 Z-1 tables ENCS inventory (Japan)
CWA 40 CFR 311( b)(4) OSHA 1910 subpart Z PICCS inventory (Phillipines)
CWA 40 CFR 307(a) CHINA inventory
Section 16 - Other Information
Abbreviations: ACGIH - American Conference of Governmental Industrial Hygienists
MSDS Printed On: Monday, August 21, 2006 MSDS Number: TN310 Page 7 of 8
IDLH - Immediatly Dangerous to Life and Health
NA - Not Applicable to the criteria OR Not Available
ND- Not Determined OR Not Known
NE - None established
OSHA - Occupational Safety and Health Administration
PEL - Permissible Exposure Limit
RCRA - Resource Conservation Recovery Act
STEL - Short Term Exposure Limit
TLV - Threshold Limit Value
TSCA - Toxic Substances Control Act
TWA - Time Weighted Average
Disclaimer: The information presented in this Material Safety Data Sheet is based on data believed to be
accurate as of the date this Material Safety Data Sheet was prepared. The information above is
provided on the condition that parties receiving the product make their own determination as to
the suitability of the product for their particular purpose and assume the risk of use of the
product. NO WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR
PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED
REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED
ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR
THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS
USE. Mitsubishi Kagaku Imaging Corporation has no responsibility or liability for any damage or
injury resulting from abnormal use or from any failure to adhere to recommended procedures.
Mitsubishi Kagaku Imaging Corporation neither grants, nor shall the party receiving the product
imply any authorization to practice any patented invention without a license.
Additional Comments NA
Revision Notes: ACB
<<<<< END OF MSDS>>>>>
MSDS Printed On: Monday, August 21, 2006 MSDS Number: TN310 Page 8 of 8
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