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CAS

693-98-1 288-32-4 7446-09-5 7553-56-2

File Name: 693-98-1_288-32-4_7446-09-5_7553-56-2.asp

EC safety data sheet
Status: 7/6/2001 10:17:25
Trade name: HYDRANAL-Composite 1, one-component reagent
Version : 1 / EU
Product no.: SEC34827 Date of printing : 09.01.2003



1.) Identification of the substance/preparation and company
Product details
Trade name
HYDRANAL-Composite 1, one-component reagent

Identification of the manufacturer / supplier
Address
Honeywell Specialty Chemicals Seelze GmbH
Wunstorfer Str. 40
D-30926 Seelze
Telephone no. +49 (0) 5137-999-0
Information provided by / telephone
Health, Safety & Environment - Product Defintion
Emergency telephone number
+49 (0) 5137-999-0

2.) Composition / information on ingredients
Chemical characterization
HYDRANAL-Composite 1, one-component reagent
for volumetric Karl Fischer titration
Hazardous ingredients
2-Methylimidazole
CAS no. 693-98-1
Concentration > 5 < 15 %-b.w.
Imidazol
CAS no. 288-32-4
Concentration > 5 < 15 %-b.w.
Schwefeldioxid
CAS no. 7446-09-5
EINECS no. 231-195-2
Concentration > 5 < 15 %-b.w.
Classification T;R23
C;R34

Iod
CAS no. 7553-56-2
EINECS no. 231-442-4
Concentration > 1 < 10 %-b.w.
Classification Xn;R20/21
N;R50



3.) Hazards possibilities
Particular information pertaining specific risk for human / environment
Does not require a hazard labelling warning label, but the normal safety precautions for handling of chemicals must
be observed.

4.) First aid measures
After inhalation
Ensure supply of fresh air.
After skin contact
In case of contact with skin wash off immediately with plenty of water.
After eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
After ingestion
When swallowed, allow water to be drunk. Induce the patient to vomit of his own accord only if fully conscious.

2 page: 1(2)
EC safety data sheet
Status: 7/6/2001 10:17:25
Trade name: HYDRANAL-Composite 1, one-component reagent
Version : 1 / EU
Product no.: SEC34827 Date of printing : 09.01.2003


Summon a doctor immediately.


5.) Fire-fighting measures
Suitable extinguishing media
Water mist; Foam; Carbon dioxide; Dry powder
Special exposure hazards arising from the substance or preparation itself, its combustion products or from
resulting gases
In the event of fire the following can be released: Sulphur dioxide (SO2); Sulphur trioxide (SO3)
Special protective equipment for firefighting
Use self-contained breathing apparatus.


6.) Accidental release measures
Personal precautions
Ensure adequate ventilation.
Methods for cleaning up/taking up
Take up with absorbent material (eg sand, kieselguhr, universal binder). Pick for disposal in tightly closed
containers


7.) Handling and storage
Handling
Advice on safe handling
Exhaust ventilation at the object is necessary.
Advice on protection against fire and explosion
Keep away from sources of ignition.

Storage
Further information on storage conditions
Keep container tightly closed.
VCI storage category
10 Flammable liquids except for LGK 3A and 3B


8.) Exposure controls / personal protection
Ingredients with occupational exposure limits to be monitored
None

Personal protective equipment
Hand protection
Gloves (solvent-proof)
Eye protection
Safety glasses
Skin protection
light protective clothing, anti-static
General protective and hygiene measures
Wash hands before breaks and after work. Do not eat or drink during work time. Do not smoke during work time.


9.) Physical and chemical properties
Appearance
Form liquid
Colour brown
Odour characteristic




2 page: 2(2)
EC safety data sheet
Status: 7/6/2001 10:17:25
Trade name: HYDRANAL-Composite 1, one-component reagent
Version : 1 / EU
Product no.: SEC34827 Date of printing : 09.01.2003


Safety data
Changes in physical state
Value 194
type Boiling point
Value 癈
Pressure 1013 hPa
Flash point
Value 90 癈
Density
Value appr. 1.110 g/cm?br> Reference temperature 20 癈
Solubility in water
Remarks miscible
pH value
Value 3.0 - 4.0
Reference temperature 20 癈
Other information (chapter 9.)
The information regarding the flash point is that of the solvent.


10.) Stability and reactivity
Hazardous decomposition products
Nitrous gases; Possible in traces; Sulphur dioxide
Thermal decomposition
Remarks No decomposition if used as prescribed.

11.) Toxicological information
Acute toxicity
Acute oral toxicity
LD50 5500 mg/kg
Species rat
Source RTECS
Acute dermal toxicity
LD50 8500 mg/kg
Species rabbit
Source RTECS

Irritant/corrosive effects
Irritant effect on skin
Species rabbit
evaluation non-irritant
Source Riedel-de Haen
Irritant effect on eyes
Species rabbit eye
evaluation slightly irritant
Source Riedel-de Haen

Other information (chapter 11.)
The substance has no mutagenic activity (Ames Test)
Analogous to product with a similar composition.




2 page: 3(2)
EC safety data sheet
Status: 7/6/2001 10:17:25
Trade name: HYDRANAL-Composite 1, one-component reagent
Version : 1 / EU
Product no.: SEC34827 Date of printing : 09.01.2003



12.) Ecological information
Data on elimination ( persistence and degradability)
Biodegradability
Value 78
Duration of exposure 14 day(s)
Method OECD 302 B
Source Riedel-de Haen
evaluation readily degradable

13.) Disposal considerations
Product
May be released into drains. Observe local authority regulations


14.) Transport information
Land transport ADR/RID
Remarks non-dangerous goods
Marine transport IMDG/GGVSee
Remarks The product does not constitute a hazardous substance in sea transport.
Air transport ICAO/IATA
Remarks The product does not constitute a hazardous substance in air transport.

15.) Regulatory information
Labelling in accordance with EC directives
The product does not require a hazard warning label in accordance with EC Directives.
Hazardous component(s) to be indicated on label
2-Methylimidazole
Imidazol
Schwefeldioxid
Iod


16.) Other information
Other information
2-Methylimidazole
22 Harmful if swallowed.
34 Causes burns.
Imidazol
22 Harmful if swallowed.
34 Causes burns.
Schwefeldioxid
23 Toxic by inhalation.
34 Causes burns.
Iod
20/21 Harmful by inhalation and in contact with skin.
50 Very toxic to aquatic organisms.
Department issuing safety data sheet
This information is based on our present state of knowledge. However, it should not constitute a guarantee for any
specific product properties and shall not establish a legally valid relationship.




2 page: 4(2)

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