MATERIAL SAFETY DATA SHEET
INTERNATIONAL BONDING ADHESIVE
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Material Identity
Product Name: INTERNATIONAL BONDING ADHESIVE
General or Generic ID: SYNTHETIC RUBBER/RESIN IN SOLVENT (S)
Company Emergency Telephone Number:
Ashland Chemical Co. 1-800-ASHLAND (1-800-274-5263)
P.O. Box 2219 24 hours everyday
Columbus, OH 43216
614-790-3333 Regulatory Information Number:
1-800-325-3751
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients (s) CAS Number % (by weight)
------------------------------------------- ------------------------ --------------------
TOLUENE 108-88-3 37.0
ACETONE 67-64-1 20.0- 24.0
ALIPHATIC PETROLEUM DISTILLATES 64742-89-8 13.0- 17.0
SYNTHETIC RUBBER Trade Secret 13.0- 17.0
TRET-BUTYLPHENOL, POLYMER W/FORMALDEHYDE 2.5- 6.0
HYDROCARBON RESIN Trade Secret 1.0- 4.2
AROMATIC HYDROCARBON RESIN 68410-16-2 1.0- 3.7
HEXANE 110-54-3 3.7- 5.0
3. HAZARDS IDENTIFICATION
Potential Health Effects
Eye
Exposure may cause mild eye irritation. Symptoms may include stinging, tearing, and redness.
Skin
Exposure may cause mild skin irritation. Prolonged or repeated exposure may dry the skin.
Symptoms may include redness, burning, drying and cracking, and skin burns.
Swallowing
Single dose oral toxicity is low. Swallowing small amounts during normal handling is not likely
To cause harmful effects; swallowing large amounts may be harmful. This material can enter the
Lungs during swallowing or vomiting and cause lung inflammation and/or damage.
Inhalation
Exposure to vapor or mist is possible. Short-term inhalation toxicity is low. Breathing small
Amounts during normal handling is not likely to cause harmful effects; breathing large amounts
May be harmful.
Symptoms of Exposure
Gastrointestinal irritation (nausea, vomiting, diarrhea), irritation (nose, throat, respiratory
Tract), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea,
Headache, unconsciousness), and death.
Target Organ Effects
Prolonged and repeated exposure to n-hexane may cause peripheral neuropathy by damaging
Peripheral nerve tissue (that of the arms and legs) and result in muscular weakness and loss of
Sensation. Prolonged and repeated inhalation of high levels of mixed isomers of hexane resulted
In kidney damage in male rats. The effects observed are the same as those seen in male rats
Exposed to other hydrocarbons. The mechanism by which these chemicals cause the
Characteristic kidney toxicity is unique to the male rat and the kidney effects are not expected
To occur in man. Overexposure to this material (or its components) has been suggested as a
Cause of the following effects in laboratory animals, and may aggravate pre-existing disorders
Of these organs in humans: liver abnormalities, spleen damage, eye damage, kidney damage,
Lung damage. Overexposure to his material (or its components) has been suggested as a cause
Of the following effectes in humans, and may aggravate pre-existing disorders of these organs:
Central nervous system effects, liver abnormalities.
Developmental information
No data
Cancer Information
No data
Other Health Effects
No data
Primary Route (s) of Entry
Inhalation, Skin absorption, Skin contact.
4. FIRST AID MEASURES
Eyes
If symptoms develop, immediately move individual away from exposure and into fresh air. Flush
Eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate
Medical attention.
Skin
Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist,
Seek medical attention. Launder clothing before reuse.
Inhalation
If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist
Seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet;
Seek immediate medical attention.
Note to Physicians
No data
5. FIRE FIGHTING MEASURES
Flash Point
-2.0 F (-18.8 C) SETA
Explosive Limit
(for component) Lower 1.0 Upper 7.0 %
INTERNATIONAL BONDING ADHESIVE
Autoignition Temperature
No data
Hazardous Products of Combustion
May form: carbon dioxide and carbon monoxide, phenols, various hydrocarbons.
Fire and Explosion Hazards
Material is highly volatile and readily gives off vapors which may travel along the ground or be moved
By ventilation and ignited by pilot lights, other flames, sparks, heaters, smoking, electric motors, static
Discharge,or other ignition sources at locations distant from material handling point. Never use
Welding or cutting torch on or near drum (even empty) because products ( even just residue) can ignite
Explosively.
Extinguishing Media
Regular foam, water fog, carbon dioxide, dry chemical.
Fire Fighting Instructions
Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure
Demand mode with appropriate turn-out gear and chemical resistant personal protective equipment.
Refer to the personal protective equipment section of this MSDS.
NFPA Rating
Not determined
6. ACCIDENTAL RELEASE MEASURES
Small Spill
Absorb liquid on vermiculite, floor absorbent, or other absorbent material and transfer to hood.
Eliminate all sources of ignition such as flares, flames (including pilot lights), and electrical sparks.
Large Spill
Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not
Wearing protective equipment should be excluded from area of spill until clean 璾p has been
Completed. Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of
Water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum
Transfer spilled products to clean containers for recovery. Absorb unrecoverable product. Transfer
Contaminated absorbent, soil and other materials to containers for disposal. Notify the proper
Authorities as required that a spill has occurred.
7. HANDLING AND STORAGE
Handling
Containers of this material may be hazardous when emptied, since emptied containers retain product
Residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
All five gallon pails and larger metal containers including tank cars and tank trucks should be grounded
And/or bonded when material is transferred. When used as part of an EPDM roofing system involving
Roller application, pails should be electrically and mechanically connected to the application
Equipment and the system should be grounded. When used as part of a roofing system involving spray
Application, the roof surface, applicator nozzle and human operator should be electrically and
Mechanically connected and the system should be grounded.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA
Regulations also permit other type safety glasses. Consult your safety representative.
Skin Protection
Wear resistant gloves (consult your safety equipment supplier)., To prevent repeated or prolonged
Skin contact, wear impervious clothing and boots..
Respiratory Protections
If workplace exposure limit (s) of product or any component is exceeded (see exposure guidelines)
A NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental
Control. OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type)
Under specified conditions (see your industrial hygienist). Engineering or administrative controls
Should be implemented to reduce exposure.
Engineering Controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure
Below TLV (s).
Exposure Guidelines
Component
-----------------
TOLUENE (108-88-3)
OSHA VPEL 100.000 ppm ?TWA
OSHA VPEL 150.000 ppm ?STEL
ACGIH TLV 50.000 ppm ?TWA (Skin)
ACGIH TLV 150.000 ppm ?STEL (Skin)
ACETONE (67-64-1)
OSHA VPEL 750.000 ppm ?TWA
OSHA VPEL 1000.000 ppm ?STEL
ACGIH TLV 750.000 ppm ?TWA
ACGIH TLV 1000.000 ppm ?STEL
ALIPHATIC PETROLEUM DISTILLATES 964742-89-8)
No Exposure limits established
SYNTHETIC RUBBER
No exposure limits established
TERT-BUTYLPHENOL, POLYMER W/FORMALDEHYDE
No exposure limits established
HYDROCARBON RESIN
No exposure limits established
AROMATIC HYDROCARBON RESIN (68410-16-2)
No exposure limits established
HEXANE (110-54-3)
OSHA VPEL 50.000 ppm ?TWA
ACGIH TLV 50.000 ppm ?TWA
INTERNATIONAL BONDING ADHESIVE
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point
(for component) 133.0 F (56.1 C) @ 760 mmHg
Vapor Pressure
(for component) 181.700 mmHg @ 68.00 F
Specific Vapor Density
1.000 @ AIR=1
Specific Gravity
.872 @ 77.00 F
Liquid Density
7.260 lbs/gal @ 77.00 F
.871 kg/a @ 25.00 C
Percent Volatiles
73.0 - 77.0 %
Evaporation Rate
SLOWER THAN ETHYL ETHER
Appearance
No data
State
SEMISOLID
Physical Form
PASTE
Color
YELLOW
Odor
No data
PH
No data
10. STABILITY AND REACTIVITY
Hazardous Polymerization
Product will not undergo hazardous polymerization.
Hazardous Decomposition
May form: carbon dioxide and carbon monoxide, phenols, various hydrocarbons.
Chemical Stability
Stable.
Incompatibility
Avoid contact with: strong alkalies, strong mineral acids strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
No data
12. ECOLOGICAL INFORMATION
No data
13. DISPOSAL CONSIDERATION
Waste Management Information
Destroy by liquid incineration in accordance with applicable regulations.
14. TRANSPORT INFORMATION
DOT information ?49 CFR 172.101
DOT Description:
ADHESIVES,3,UN1133,III
Container/Mode:
55 GAL DRUM/TRUCK PACKAGE
NOS Component:
NONE
RQ (Reportable Quantity) ?49 CFR 172.101
Product Quantity (lbs) Component
---------------------------- -------------------------------------------
2727 TOLUENE
22272 ACETONE
15. REGULATORY INFORMATION
US Federal Regulations
TSCA (Toxic Substances Control Act) Status
TSCA (UNITED STATES) The intentional ingredients of this product are listed.
CERCLA RQ ?40 CFR 302.4
Component RQ (lbs)
-------------------------------- ---------------
TOLUENE 1000
ACETONE 5000
HEXANE 1
INTERNATIONAL BONDING ADHESIVE
SARA 302 Components ?40 CFR 355 Appendix A
None
Section 311/312 Hazard Class ?40 CFR 370.2
Immediate (X) Delayed(X) Fire(X) Reactive( ) Sudden Release of Pressure( )
Sara 313 Components ?40 CFR 372.65
Section 313 Component (s) CAS Number Max %
--------------------------------- ---------------------- ---------------
TOLUENE 108-88-3 36.67
N-HEXANE 110-54-3 5.21
International Regulations
Inventory Status
DSL (CANADA) The intentional ingredients of this product are listed.
State and Local Regulations
California Proposition 65
The following statement is made in order to comply with the California Safe Drinking
Water and Toxic Enforcement Act of 1986: This product contains the following
Substance (s) known to the state of California to cause cancer. BENZENE
The following statement is made in order to comply with the California Safe Drinking
Water and Toxic Enforcement Act of 1986: This product contains the following
Substance (s) known to the state of California to cause reproductive harm.
TOLUENE
New Jersey RTK Label Information
TOLUENE 108-88-3
ACETONE 67-64-1
NAPHTHA, SOLVENT 64742-89-8
N-HEXANE 110-54-3
Pennsylvania RTK Label Information
BENZENE, METHYL- 108-88-3
2-PROPANONE 67-64-1
HEXANE 110-54-3
16. OTHER INFORMATION
The information accumulated herein is believed to be accurate but is not warranted to be
Whether originating with the company or not. Recipients are advised to confirm in advance
Of need that the information is current, applicable, and suitable to their circumstances.
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