Material Safety Data Sheet
Technical Bulletin B-6
24-HOUR EMERGENCY PHONE NUMBER: (800) 535-5053
I. Product Name: Extreme Slow Cure PVC Resin
II. Composition/Information on Ingredients
OSHA HAZARDOUS COMPONENTS
(29 CFR 1910.1200)
Exposure limits ? hrs. TWA (ppm)
CHEMICAL NAME WT CAS # ACGIH TLV OSHA PEL OTHER
Methyl Methacrylate(MMA) 40-75 80-62-6 100 ppm 100 ppm 100ppm(Canada)
Cumene Hydroperoxide 1-10 80-15-9 1ppm -- Skin
p-toulenesulfonyl 1-10 98-59-9 -- -- --
Methacrylic Acid 1-10 79-41-4 20ppm(skin) 20ppm(skin) --
III. Hazardous Information
Emergency Overview:
Physical State: Liquid. Color: Milky white. Odor: Pungent. Acrylic.
WARNING! FLAMMABLE LIQUID AND VAPOR. MAY CAUSE ALLERGIC SKIN REACTION
MAY CAUSE EYE, SKIN, AND RESPIRATORY IRRITATION
Potential Health Effects:
Eye: Moderate eye irritation. Redness. Excess tearing.
Skin: Allergic skin reaction. Itching Moderate skin irritation. Redness.
Ingestion: Toxicity by ingestion is not likely to occur.
Inhalation: Moderate respiratory tract irritation. Shortness of breath. Coughing.
Chronic: Detailed information provided in section XI.
Conditions Aggravated by Exposure: Respiratory disorders. Skin disorders. Eye disorders.
IV. First Measures
Eye: Immediately flush eyes with water for at least 20 minutes. Get immediate medical attention.
Skin: Wash thoroughly with soap and water. Discard contaminated clothing. Do not use organic solvents.
If irritation occurs, get medical attention.
Material Safety Data Sheet
Technical Bulletin B-6
24-HOUR EMERGENCY PHONE NUMBER: (800) 535-5053
Inhalation: Remove person to fresh air or apply artificial respiration if not breathing. Get medical attention if short of breath
or if respiratory symptoms develop.
Ingestion: Give 1-2 glasses of milk or water to conscious person. Get medical attention.
DO NOT INDUCE VOMITING
V. Fire Fighting Measures
Flashpoint and Method: 51F (TCC)
Autoignition Temperature: NA
Flammable Limits: 2.1 MMA, Upper 12.5 fpr MMA
Extinguishing Media: Flammable liquid, insoluble in water. Use DRY chemical powder.
Special Fire Fighting Instructions: Fire fighters should wear positive pressure self-contained
breathing apparatus (SCBA) and full turnout gear.
Hazardous Combustion Products: Oxides of carbon and nitrogen. Hydrogen cyanide.
Methylene biphenyl isocyanate. Hydrocarbons. Smoke. Cyclopentanone. Butanediol. Tetrahydrofuran.
VI. Accidental Release Measures
Remove sources of ignition. Use with ventilation. Dike area to prevent spreading. Absorb on vermiculite, sand or other inert
absorbing material. Dispose of as a chemical waste in accordance with current local state, and Federal Regulations. Do
not discharge into water. Incineration recommended. Wash spill area with strong detergent. After proper mixing of resin and
activator sides, the material will polymerize into a cured solid state, which can be treated as a nonhazardous solid. Applicable
CERCLA/RCRS waste code: 0001 (ignitability) U162 (MMA)
VII. Storage and Handling
Storage: Avoid storage over 100癋, contamination with incompatible materials. Store in cool place. Do not store in direct
sunlight. Recommended storage in flammable containment area. Shelf Life is at least 6 months when properly stored in an
unopened original container in a cool, dark area at least 55癋 to 75癋.
Handling: Avoid prolonged or repeated breathing of vapor. Avoid contact with skin and eyes. Wash hands before smoking or
eating.
VIII. Exposures Controls/Personal Protection
Engineering Controls: Use local exhaust ventilation of the potential for airborne exposure exists.
Material Safety Data Sheet
Technical Bulletin B-6
24-HOUR EMERGENCY PHONE NUMBER: (800) 535-5053
Personal Protection:
Respiratory Protection: Use NIOSH approved respirator if there is potential to exceed any exposure limit(s).
Skin Protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to
prevent skin contact.
Eye Protection: Chemical splash goggles or safety glasses with side shields.
Other Protective Equipment: NA
IX. Physical and Chemical Properties
Vapor Pressure: 29mm at 20C Vapor Density: >1 Heavier then air, 3.5 for MMA
Solubility in Water: Slight Specific Gravity: 09.94-1.0
Boiling Point: 214F for MMA Freezing Point: NA
Physical State: Liquid pH: NA
Odor: Pungent. Acrylic Appearance: Light gel, milky white in color
VOC: 1.98; 1.92g/l (adhesive & activator mixed)
X. Stability and Reactivity
Stability: Stable
Incompatible Materials and Conditions to Avoid: No known conditions to avoid. Oxidizing agents, Alkalis, Moisture.
Strong acids. Strong bases. Reducing agent. Ultraviolet radiation. Amines.
Hazardous Polymerization: Non known
XI: Toxicological Information
Product Toxicology Data: None available
Ingredients Carcinogen Target organ
NTP IARC OSHA
Methyl methacrylate No N/A No Allergen. Irritant. Nervous
System. Respiratory. Kidney. Liver
Cumene hydroperoxide No No No Allergen. Central Nervous
System. Corrosive. Irritant. Mutagen
Methacrylic acid No No No Allergen. Corrosive. Irritant
XII. Ecological Information
Not available
Material Safety Data Sheet
Technical Bulletin B-6
24-HOUR EMERGENCY PHONE NUMBER: (800) 535-5053
XIII: Disposal Consideration
Disposal Method: Dispose according to EPA and local government regulations. EPE Hazardous waste #0001;U162; D003.
XIV: Transport Information
DOT(49 CFR 172)
Proper Shipping Name: Adhesives / Consumer Commodity
Identification Number: Un1133
Hazard Class: 3 PACKING GROUP: III
Exceptions: Single unit less than or equal to 1 liter
Class/Division: ORM-D - 3 INTERNATIONAL AIR TRANSPORTATION (IATA)
Exceptions: Consumer Commodity, class 9, ID 8000, less than 500ml
XV: Regulatory Information
TCA (Toxic Substance Control Act): All components are listed on or exempt from listing on the Toxic Substances Control Act
Inventory.
CERLA (Comprehensive emergency Response, Compensation, and Liability Act): NA
SARA TITLE III (Superfund amendments and Reauthorization Act): 313 Reportable Ingredients: Methyl Methacrylate,
Cumene Hydroperoxide.
Canadian Inventory Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
California Proposition 65: This product contains chemicals known to the state of California to cause cancer, birth
defects, or other reproductive harm.
XVI: Other Information
NFPA: Health 2 Fire 3 Reactivity 2 Special None
Hazardous Materials Information System (HMIS) Ratings:
Health 2 Flammability 3 Reactivity 2 Protective Equipment: see Section VIII
The information in this MSDS was obtained from current and reliable sources. However, the data is provided without warranty, expressed or implied,
regarding its correctness or accuracy. Since the conditions for use, handling, storage and disposal of the product are beyond Extreme Adhesives, Inc.
Control: it is the user's responsibility both to determine safe conditions for use of this product and to assume liability for loss, damage or expense aris-
ing our of the product's improper use. No warranty, expressed or implied regarding the product described herein shall be created by or inferred from any
statement or omissions in this MSDS. Various government agencies (e DOT, EPA, FDA) may have specific regulations concerning the transportation,
handling, storage use or disposal of the product, which may not be reflected in this MSDS.
The user should review those regulations to ensure full compliance.
Material Safety Data Sheet
Technical Bulletin B-6
24-HOUR EMERGENCY PHONE NUMBER: (800) 535-5053
I. Product Name: Extreme Slow Cure PVC Activator
II. Composition/Information on Ingredients
OSHA HAZARDOUS COMPONENTS
(29 CFR 1910.1200)
Exposure limits ? hrs. TWA (ppm)
CHEMICAL NAME WT CAS # ACGIH TLV OSHA PEL OTHER
Methyl Methacrylate(MMA) 40-75 80-62-6 100 ppm 100 ppm 100ppm(Canada)
Amine 1-10 Trade Secret -- -- --
III. Hazardous Information
Emergency Overview:
Physical State: Liquid. Color: Milky white. Odor: Pungent. Acrylic.
WARNING! FLAMMABLE LIQUID AND VAPOR. MAY CAUSE ALLERGIC SKIN REACTION
MAY CAUSE EYE, SKIN, AND RESPIRATORY IRRITATION
Potential Health Effects:
Eye: Moderate eye irritation. Redness. Excess tearing.
Skin: Allergic skin reaction. Itching Moderate skin irritation. Redness.
Ingestion: Toxicity by ingestion is not likely to occur.
Inhalation: Moderate respiratory tract irritation. Shortness of breath. Coughing.
Chronic: Detailed information provided in section XI.
Conditions Aggravated by Exposure: Respiratory disorders. Skin disorders. Eye disorders.
IV. First Aid Measures
Eye: Immediately flush eyes with water for at least 20 minutes. Get immediate medical attention.
Skin: Wash thoroughly with soap and water. Discard contaminated clothing. Do not use organic solvents.
If irritation occurs, get medical attention.
Material Safety Data Sheet
Technical Bulletin B-6
24-HOUR EMERGENCY PHONE NUMBER: (800) 535-5053
Inhalation: Remove person to fresh air or apply artificial respiration if not breathing. Get medical attention if short of
breath or if respiratory symptoms develop.
Ingestion: Give 1-2 glasses of milk or water to conscious person. Get medical attention.
DO NOT INDUCE VOMITING
V. Fire Fighting Measures
Flashpoint and Method: 51F (TCC)
Autoignition Temperature: NA
Flammable Limits: 2.1 MMA, Upper 12.5 fpr MMA
Extinguishing Media: Flammable liquid, insoluble in water. Use DRY chemical powder.
Special Fire Fighting Instructions: Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA)
and full turnout gear.
Hazardous Combustion Products: Oxides of carbon and nitrogen. Hydrogen cyanide.
Methylene bisphenyl isocyanate. Hydrocarbons. Smoke. Cyclopentanone. Butanediol. Tetrahydrofuran.
VI. Accidental Release Measures
Remove sources of ignition. Use with ventilation. Dike area to prevent spreading. Absorb on vermiculite, sand or other inert
absorbing material. Dispose of as a chemical waste in accordance with current local state, and Federal Regulations. Do not
discharge into water. Incineration recommended. Wash spill area with strong detergent. After proper mixing of activator and
activator sides, the material will polymerize into a cured solid state, which can be treated as a nonhazardous solid. Applicable
CERCLA/RCRS waste code: 0001 (ignitability) U162 (MMA)
VII. Storage and Handling
Storage: Avoid storage over 100癋, contamination with incompatible materials. Store in cool place. Do not store in direct
sunlight. Recommended storage in flammable containment area. Shelf life is at least 6 months when properly stored in an
unopened original container in a cool, dark area at least 55癋 to 75癋.
Handling: Avoid prolonged or repeated breathing of vapor. Avoid contact with skin and eyes. Wash hands before smoking or
eating.
VIII. Exposure Controls/Personal Protection
Engineering Controls: Use local exhaust ventilation of the potential for airborne exposure exists.
Material Safety Data Sheet
Technical Bulletin B-6
24-HOUR EMERGENCY PHONE NUMBER: (800) 535-5053
Personal Protection:
Respiratory Protection: Use NIOSH approved respirator if there is potential to exceed any exposure limit(s).
Skin Protection: Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent
skin contact.
Eye Protection: Chemical splash goggles or safety glasses with side shields.
Other Protective Equipment: NA
IX. Physical and Chemical Properties
Vapor Pressure: 29mm at 20C Vapor Density: >1 Heavier then air, 3.5 for MMA
Solubility in Water: Slight Specific Gravity: 09.94-1.0
Boiling Point: 214F for MMA Freezing Point: NA
Physical State: Liquid pH: NA
Odor: Pungent. Acrylic Appearance: Light gel, milky white in color (black or gray if dyed)
VOC: 1.98; 1.92g/l (adhesive & activator mixed)
X. Stability and Reactivity
Stability: Stable
Incompatible Materials and Conditions to Avoid: No known conditions to avoid. Oxidizing agents, Alkalis, Moisture. Strong
acids. Strong bases. Reducing agent. Ultraviolet radiation. Amines.
Hazardous Polymerization: Non known
XI: Toxicological Information
Product Toxicology Data: None available
Ingredients Carcinogen Target organ
NTP IARC OSHA
Methyl methacrylate No N/A No Allergen. Irritant. Nervous
System. Respiratory. Kidney. Liver
Amine condensate No No No Not Available
XII. Ecological Information
Not available
Material Safety Data Sheet
Technical Bulletin B-6
24-HOUR EMERGENCY PHONE NUMBER: (800) 535-5053
XIII: Disposal Consideration
Disposal Method: Dispose according to EPA and local government regulations. EPE Hazardous waste #0001;U162;D003.
May be mixed with EXT-Resin and disposed of as non-hazardous solid waste.
XIV: Transport Information
DOT(49 CFR 172)
Proper Shipping Name: Adhesives / Consumer Commodity
Identification Number: Un1133
Hazard Class: 3 PACKING GROUP: III
Exception: Single unit less than or equal to 1 liter
Class/Division: ORM-D - 3 INTERNATIONAL AIR TRANSPORTATION (IATA)
Exceptions: Consumer Commodity, class 9, ID 8000, less than 500ml
XV: Regulatory Information
TCA (Toxic Substance Control Act): All components are listed on or exempt from listing on the Toxic Substances Control
Act Inventory.
CERLA (Comprehensive emergency Response, Compensation, and Liability Act): NA
SARA TITLE III (Superfund amendments and Reauthorization Act): 313 Reportable Ingredients: Methyl Methacrylate,
Cumene Hydroperoxide.
Canadian Inventory Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances
List.
California Proposition 65: This product contains chemicals known to the state of California to cause cancer, birth defects,
or other reproductive harm.
XVI: Other Information
NFPA: Health 2 Fire 3 Reactivity 2 Special None
Hazardous Materials Information System (HMIS) Ratings:
Health 2 Flammability 3 Reactivity 2 Protective Equipment: see Section VIII
The information in this MSDS was obtained from current and reliable sources. However, the data is provided without warranty, expressed or implied,
regarding its correctness or accuracy. Since the conditions for use, handling, storage and disposal of the product are beyond Extreme Adhesives, Inc.
Control: it is the user's responsibility both to determine safe conditions for use of this product and to assume liability for loss, damage or expense arising
our of the product's improper use. No warranty, expressed or implied regarding the product described herein shall be created by or inferred from any
statement or omissions in this MSDS. Various government agencies (e DOT, EPA, FDA) may have specific regulations concerning the transportation,
handling, storage use or disposal of the product, which may not be reflected in this MSDS.
The user should review those regulations to ensure full compliance.
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