MATERIAL SAFETY DATA SHEET
SikaFix HH+
HMIS
HEALTH *2
FLAMMABILITY 1
REACTIVITY 1
C
PERSONAL PROTECTION
1. Product And Company Identification
Supplier Manufacturer
Sika Corporation de neef Construction Chemicals Inc.
201 Polito Ave 5610 Brystone Drive
Lyndhurst, NJ 07071 Houston, TX 77095 USA
Company Contact: EHS Department
Telephone Number: 201-933-8800 Telephone Number: 800-732-0166
FAX Number: 201-933-9379 FAX Number: 713-849-3340
Web Site: www.sikausa.com Web Site: www.deneef.com
Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC: 800-424-9300 CHEMTREC: 800-424-9300
INTERNATIONAL: 703-527-3887 INTERNATIONAL: 703-527-3887
Issue Date: 09/18/2007
Product Name: SikaFix HH+
CAS Number: Not Established
MSDS Number: 4176
Product Code: 043L05G
2. Composition/Information On Ingredients
Ingredient CAS Percent Of
Name Number Total Weight
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI) 101-68-8 10 - 30
DIBUTYL MALEATE 105-76-0 10 - 30
DIBUTYL PHTHALATE 84-74-2 15 - 40
POLYETHER POLYOL 9082-00-2 5 - 10
POLYETHER POLYOL 9003-11-6 5 - 10
POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9 5 - 10
3. Hazards Identification
Eye Hazards
Causes eye irritation. Contact with eyes may cause product to polymerize.
Skin Hazards
Causes mild to moderate skin irritation. Contact with skin may cause product to polymerize. Prolonged and/or
repeated skin contact may cause an allergic reaction/sensitization.
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MATERIAL SAFETY DATA SHEET
SikaFix HH+
3. Hazards Identification - Continued
Ingestion Hazards
Harmful if swallowed. Polymerization of this product in airway could cause soffocation. Ingestion of this product
is harmful and maybe fatal.
Inhalation Hazards
Causes respiratory tract irritation. May cause an allergic respiratory reaction / sensitization after prolonged or
repeated contact.
4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of tepid water for at least 15 minutes.
Get medical attention immediately if irritation develops and persists. Remove contact lenses, if worn.
Skin
In case of contact, remove contaminated clothing and blot or brush the product away, prior to washing the
exposed area with water. Flush skin with soap and plenty of tepid water for at least 15 minutes. Get medical
attention immediately if irritation (redness, rash, blistering) develops and persists. The process of trying to
remove the cured product may cause irriation. Wash clothing before reuse.
Ingestion
SEEK IMMEDIATE MEDICAL ATTENTION! DELAYED TREATMENT MAY RESULT IN FATALITY. Do not
induce vomiting. Rinse mouth out with water. Aspiration of material into the lungs due to vomiting can cause
chemical pneumonitis which can be fatal.
Inhalation
Remove to fresh air. If not breathing, give artificial respiration, seek medical attention. Seek medical attention
immediately.
5. Fire Fighting Measures
Flash Point: > 266 癋 > 130 癈
Flash Point Method: COC (ASTM D 93)
Autoignition Point: 537 癋 281 癈
Lower Explosive Limit: NA
Upper Explosive Limit: NA
Extinguishing Media
Dry Chemical, CO2, Foam or Water Fog
Fire Fighting Instructions
In the event of a fire, firefighters should wear full protective clothing and NIOSH-approved self-contained
breathing apparatus with a full facepiece operated in the pressure demand or other positive pressure mode.
Do not scatter material with high pressure water streams.
Fire or intense heat will decompose the product into CO2, CO, Hydrogen Cyanide, Oxides of Nitrogen, Isocyanates,
Isocyanic, and dense black smoke.
6. Accidental Release Measures
Where exposure level is known, wear approved respirator suitable for the level of exposure. If exposure is unknown,
wear approved, positive pressure, self-contained respirator. In addition to the protective clothing in Section 8, wear
impermeable boots.
Remove sources of ignition. Stop and contain / dam the spill. Absorb the inert materials (vermiculite / diatomaceous
earth). Shovel material into appropriate container for disposal.
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MATERIAL SAFETY DATA SHEET
SikaFix HH+
7. Handling And Storage
Handling Precautions
Avoid skin and eye contact. Wash thoroughly after handling. Keep product away from heat and open flame.
Storage Precautions
Keep in manufacturer's sealed nitrogen packed pail. Maintain storage temperatures between 65F to 86F (18C to
30C).
8. Exposure Controls/Personal Protection
Engineering Controls
Normal room ventilation is usually adequate under normal use.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves. Lab coat or other work clothing to prevent skin exposure (Long sleeve shirt and long
pants). Launder before reuse. In cured form, the product is difficult to remove from skin and hair.
Respiratory Protection
None normally required. In areas where the Permissible Exposure Limits are exceeded, use a properly fitted
NIOSH-approved respirator.
Other/General Protection
Use good hygiene practices when handling this material including changing and laundering work clothes after
use.
Ingredient(s) - Exposure Limits
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI)
ACGIH TLV-TWA 0.005 ppm
ACGIH TLV-TWA 0.051 mg/m3
OSHA PEL-CEILING 0.020 ppm
OSHA PEL-CEILING 0.2 mg/m3
DIBUTYL PHTHALATE
ACGIH TLV-TWA 5 mg/m3
OSHA PEL-TWA 5 mg/m3
9. Physical And Chemical Properties
Appearance
Dark brown liquid
Odor
Slightly musty odor
Chemical Type: Mixture
Physical State: Liquid
Melting Point: NA 癋
Boiling Point: NA 癋
Specific Gravity: NA
Percent Volatiles: NA
Percent VOCs: NA
Packing Density: 8.75 - 9.17 lbs/gal (ASTM 3574)
Vapor Pressure: NA
Vapor Density: NA
Solubility: None
Viscosity: 500-700 cps (ASTM D 2196 Method A)
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MATERIAL SAFETY DATA SHEET
SikaFix HH+
9. Physical And Chemical Properties - Continued
Odor - Continued
Evaporation Rate: NA
Solids Content: 100% (ASTM D 2369 B)
10. Stability And Reactivity
Conditions To Avoid (Stability)
Contact with moisture or temperatures above 350F (177C) will cause polymerization.
Incompatible Materials
Water, Amines, Strong Bases, Alcohols, Copper Alloys, Liquid Chlorine
Hazardous Decomposition Products
Fire or intense heat will decompose the product into CO2, CO, Hydrogen Cyanide, Oxides of Nitrogen,
Isocyanates, Isocyanic, and dense black smoke.
Conditions To Avoid (Polymerization)
Product will polymerize when exposed to water. During normal polymerization CO2 is produced
11. Toxicological Information
Chronic/Carcinogenicity
IARC: Group 3 (not classifiable as to its carcinogenicty in humans)
EPA: Group D
Ingredient(s) - Carginogenicity
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI)
Listed In The IARC Monographs
POLYMERIC DIPHENYLMETHANE DIISOCYANATE
Listed In The IARC Monographs
LD50: >3,700 mg/kg Oral (rat) Dibutyl Maleate
LC 50: 490 mg/m3 vapor 4 h (rat) Polymeric Diphenylmethane Diisocyanate
12. Ecological Information
Ecotoxicological Information
Does not Bioaccumulate (All Ingredients)
Biodegrade to 0% in 28 days (4,4 Diphenylmethane Dissocyante)
Biodegrade to 40% - 0% in 28 days (Dibutyl Phthalate)
Biodegrade to 70% compressive strength in 80 years (cured foam state)
13. Disposal Considerations
Refer to applicable federal, state, and local regulations prior to disposition of container and residual contents. This
product in its cured foam state is inert and non-toxic.
14. Transport Information
Proper Shipping Name
Not regulated by the USDOT.
15. Regulatory Information
U.S. Regulatory Information
All ingredients of this product are listed or are excluded from listing under the U.S. Toxic Substances Control Act
(TSCA) Chemical Substance Inventory.
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MATERIAL SAFETY DATA SHEET
SikaFix HH+
15. Regulatory Information - Continued
U.S. Regulatory Information - Continued
SARA Hazard Classes
Acute Health Hazard
Chronic Health Hazard
SARA Title III - Section 313 Supplier Notification
This product contains the following toxic chemicals that are subject to the reporting requirements of section 313 of
the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI) (101-68-8) 10 - 30 %
DIBUTYL PHTHALATE (84-74-2) 15 - 40 %
POLYMERIC DIPHENYLMETHANE DIISOCYANATE (9016-87-9) 5 - 10 %
This information must be included on all MSDSs that are copied and distributed for this material.
Ingredient(s) - U.S. Regulatory Information
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI)
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
DIBUTYL PHTHALATE
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
POLYMERIC DIPHENYLMETHANE DIISOCYANATE
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
Ingredient(s) - State Regulations
4,4' -DIPHENYLMETHANE DIISOCYANATE (MDI)
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
DIBUTYL PHTHALATE
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
Pennsylvania - Workplace Hazard
Pennsylvania - Environmental Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
POLYMERIC DIPHENYLMETHANE DIISOCYANATE
New Jersey - Environmental Hazard
16. Other Information
HMIS Rating
Health: *2
F i re : 1
Reactivity: 1
Personal Protection: C
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MATERIAL SAFETY DATA SHEET
SikaFix HH+
16. Other Information - Continued
Revision/Preparer Information
MSDS Preparer: EHS Department
MSDS Preparer Phone Number: 201-933-8800
Disclaimer
The information contained in this Material Safety Data Sheet applies only to the actual Sika Corporation ("Sika")
product identified and described herein. This information is not intended to address, nor does it address the use
or application of the identified Sika product in combination with any other material, product or process. All of the
information set forth herein is based on technical data regarding the identified product that Sika believes to be
reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the
warnings and instructions on the product's current Technical Data Sheet, product label and Material Safety Data
Sheet for each Sika product, which are available at web site and/or telephone number listed in Section 1 of this
MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS
INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR
CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A
MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY
OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sikacorp.com or
201-933-8800.
Sika Corporation
Printed Using MSDS GeneratorTM 2000
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