MATERIAL SAFETY DATA SHEET
ULTRADOSE TARTAR AND LIGHT STAIN REMOVER
PCN(s): 028 Publication Date: 2/27/09 REV: G
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1. SUPPLIER AND EMERGENCY INFORMATION Emergency Phone Numbers:
L&R Manufacturing Company Product Information For emergencies involving a spill, leak,
577 Elm Street, P.O. Box 607 Call: 201-991-5330 fire or accident contact:
CHEMTREC - 800-424-9300
Kearny, NJ 07032 - 0607 USA www.lrultrasonics.com
[USA] for
within the United States or (01)703-527-3887
International collect calls
2. HAZARDS IDENTIFICATION
Physical appearance and odor: White free flowing powder, odorless.
A: Warning Statement:
Good industrial hygiene practices should be used when handling this material.
Acute Eyes: Direct contact causes irritation, redness and possible tearing.
Acute Skin: Prolonged or repeated contact causes redness, and drying of the skin.
Acute Inhalation: Breathing high concentrations of vapors or mists may cause irritation to the nose and throat.
Acute Ingestion: Not known, but expected to cause nausea and diarrhea.
B: POTENTIAL HEALTH EFFECTS:
Chronic Effects: This product does not contain any ingredient designated by IARC, NTP, ACGIH or OSHA as probable or
suspected human carcinogens.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS Number Percentage
Citric Acid 77 -92 -9 80 - 85
Fumaric Acid 110 -17 -8 10 -15
Dodecybenzene Sulfonate, Sodium Salt 25155-30-0 1 ?10
4. FIRST AID MEASURES
Eye Exposure: Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek medical attention.
Skin Exposure: Wash thoroughly with water. If irritation or redness develops, seek medical attention.
Inhalation: If respiratory irritation or distress occurs, move victim to fresh air. Seek medical attention if respiratory irritation or distress
continues.
Ingestion: Seek immediate medical attention. DO NOT INDUCE VOMITING.
MEDICAL CONDITIONS POSSIBLY AGGRAVATED BY EXPOSURE: Skin contact may aggravate existing skin disease.
5. FIRE FIGHTING MEASURES
FIRE HAZARD DATA: Non-Combustible
Suitable Extinguishing Media: Extinguish surrounding area with dry chemical, CO2 or a BC/ABC extinguisher.
Special Fire Fighting Procedures: None known
Unusual Fire and Explosion Hazards: Closed containers may burst due to build up of pressure when exposed to extreme heat.
Hazardous Decomposition Materials: (under fire conditions) May release sulfur dioxide and trioxide or ammonia gas.
6. ACCIDENTAL RELEASE MEASURES:
Cleanup and Disposal of Spill: Sweep up powder, avoid breathing dust. Residual powder may be washed with water. Dispose of in accord with
Federal, State and Local regulations.
Environmental and Regulatory Reporting: Not required
7. HANDLING AND STORAGE
Minimum/Maximum Storage Temperatures: 32 to 100O F Protect from moisture and sunlight..
HANDLING: AVOID CONTACT WITH SKIN, EYES OR CLOTHING
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8. EXPOSURE CONTROL/PERSONAL PROTECTION
General: These recommendations provide general guidance for handling of this product. Because specific work environments and material
handling practices vary, safety procedures should be developed for each intended application. When developing safe handling procedures, do
not overlook the need to clean and dispose of the material. Waste resulting from the use of this product should be handled in accordance with
Section 13: Disposal Considerations.
Exposure Guidelines: Exposure limits are recommended worker breathing limits. The following limits apply to this material:
INGREDIENTS LIMITS INGREDIENTS LIMITS
Citric Acid Generally recognized as safe Fumaric Acid Generally recognized as safe
Sodium dodecylbenzene sulfonate None established
Engineering Controls: Normal room ventilation.
Respiratory Controls: For reasonable uses of this material, respiratory protection should not be necessary.
Eye/Face Protection: Safety glasses to protect from splashing.
Skin Protection: Rubber or plastic gloves to avoid drying and irritation to the skin.
Work Practice Control: Normal hygiene in the work area should be taken when working with or handling this product.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Free Flowing Powder Color: White Odor: odorless
pH: 2.0 as diluted Specific Gravity: Not available Odor Threshold: Not available
Water Solubility: Soluble Melting Point Range: Not available Evaporation Rate: Not available
Freezing Point Range: Not applicable Boiling Point: Not Established. Partition Coefficient; n-octanol / water: Not available
Vapor Pressure: Not established Vapor Density: Not established Decomposition Temperature: Not available
Flash Point: None Method: Tag Closed Cup Auto Ignition Temperature: Not available
Flammability limits (vol/vol %): Lower: No Data Upper: No Data
Percent volatile by volume: Less than 1% by volume V.O.C. (calculated): Less than 5 grams / l.
10. STABILITY AND REACTIVITY
Chemical Stability: Stable
Conditions to be avoided: Moisture and sunlight
Materials/Chemicals to be avoided: Strong bases , nitrites , nitrates , chlorates, chlorine, hypochlorite, cyanides and sukfides
Decomposition Type: Thermal May release sulfur dioxide, sulfur trioxide or ammonia gases.
Possibility of Hazardous Reactions: WILL NOT OCCUR
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11. TOXICOLOGICAL INFORMATION
Acute Eye Irritation: Irritating to eyes.
Acute Skin Irritation: May cause irritation to Skin.
Acute Dermal Toxicity: No test data found for product.
Acute Respiratory Irritation: May cause nose and throat irritation..
Acute Oral Toxicity:
LD50 (rat) = Citric Acid = 3 gm / kg.
Fumaric Acid = 10,700 mg / kg
Sodium dodecylbenzene sulfonate = 438 mg / kg
Chronic Toxicity: This product does not contain any substances that are considered by OSHA, NTP, IARC OR
ACGIH to be a probable or suspected human carcinogen. No additional test data was found for this product.
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12. ECOLOGICAL INFORMATION
Ecotoxicological Information: No data found.
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13. DISPOSAL CONSIDERATIONS
This product is biodegradable and can be disposed in sanitary sewer system, with dilution, where permitted by local, federal and state
regulations.
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14. TRANSPORTATION INFORMATION
This product is not regulated for transportation. Do not stack cartons more than five high..
15. REGULATORY INFORMATION
Inventory Issues: All components of this product are listed on the U.S. TSCA, Canadian DSL, European EINECS/ELINS chemical
listings
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16. OTHER INFORMATION
National Fire Protection Association
Hazard Rating, NFPA Health Flammability Reactivity Special
2 0 0 --
MSDS CHANGES
REV DATE DESCRIPTION OF CHANGE
G 1/30/08 Corrected / Reviewed NFPA rating
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Disclaimer: The information herein is given in good faith but no warranty expressed or implied is made.
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Prepared By: L&R Manufacturing Company Date: 2/27/09
Product Name: ULTRADOSE TARTAR AND LIGHT STAIN REMOVER
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