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Section 1 - Chemical Product and Company Identification |
MSDS Name: N,N-Diethylethanolamine, P.A.
Catalog Numbers:
AC219850000, AC219851000
Synonyms:
2-Diethylaminoethanol; Beta-Diethylaminoethanol
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 100-37-8 | N,N-Diethylethanolamine |
99.0 | 202-845-2 |
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear yellow brown liquid. Flash Point: 60 deg C.
Flammable liquid and vapor.
May cause eye and skin irritation. May cause respiratory and
digestive tract irritation. Hygroscopic (absorbs moisture from the
air). Warning! May be harmful if swallowed or
absorbed through the skin.
Target Organs: None.
Potential Health Effects
Eye:
May cause eye irritation. May cause eye injury.
Skin:
May cause severe skin irritation. May be harmful if absorbed through
the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Vapors may cause dizziness or suffocation. May cause nausea and
possible vomiting.
Chronic:
None
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Section 4 - First Aid Measures
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Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Containers may explode
in the heat of a fire. Flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Do NOT get water inside containers. For
large fires, use water spray, fog or alcohol-resistant foam. Cool
containers with flooding quantities of water until well after fire
is out.
Flash Point: 60 deg C ( 140.00 deg F)
Autoignition Temperature: 260 deg C ( 500.00 deg F)
Explosion Limits, Lower:6.70 vol %
Upper: 11.7 vol %
NFPA Rating:
(estimated) Health: 1; Flammability: 2; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Use water spray to disperse the
gas/vapor. Remove all sources of ignition. Use a spark-proof tool.
Provide ventilation.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Store protected from
moisture.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| N,N-Diethylethanolamine | 2 ppm TWA; skin - potential for cutaneous absorption |
10 ppm TWA; 50 mg/m3 TWA 100 ppm IDLH | 10 ppm TWA; 50 mg/m3 TWA |
OSHA Vacated PELs:
N,N-Diethylethanolamine:
10 ppm TWA; 50 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: clear yellow brown
Odor: unpleasant odor
pH: Not available.
Vapor Pressure: 1.9 mbar @ 20 C
Vapor Density: 4.04
Evaporation Rate:Not available.
Viscosity: 5mPa @ 20C
Boiling Point: 161 deg C @ 760.00mm Hg
Freezing/Melting Point:-70 deg C
Decomposition Temperature:Not available.
Solubility: soluble
Specific Gravity/Density:.8840g/cm3
Molecular Formula:C6H15NO
Molecular Weight:117.19
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 100-37-8: KK5075000
LD50/LC50:
CAS# 100-37-8:
Dermal, guinea pig: LD50 = 1 mL/kg;
Draize
test, rabbit, eye: 5 mg Severe;
Inhalation, mouse: LC50 = 5000
mg/m3;
Oral, rat: LD50 = 1300 mg/kg;
Skin, rabbit: LD50 =
1260 uL/kg;
Carcinogenicity:
CAS# 100-37-8:
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Neurotoxicity:
No information available.
Mutagenicity:
No information available.
Other Studies:
Standard Draize Test: Administration into the eye (rabbit)
= 5 mg/24H (Severe).
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Section 12 - Ecological Information
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Ecotoxicity:
Fish: Fathead Minnow: 1780 mg/L; 96 Hr.; Flow-through
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
IATA |
RID/ADR |
IMO |
Canada TDG |
| Shipping Name: |
2-DIETHYLAMINOETHANOL |
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No information available. |
| Hazard Class: |
8 |
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| UN Number: |
UN2686 |
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| Packing Group: |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 100-37-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 100-37-8: acute, chronic, flammable.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA.
None of the chemicals in this product are listed as Priority
Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous
by OSHA.
STATE
CAS# 100-37-8 can be found on the following state right to know
lists: California, New Jersey, Pennsylvania, Minnesota,
Massachusetts.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 100-37-8: 1
Canada - DSL/NDSL
CAS# 100-37-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2.
Canadian Ingredient Disclosure List
CAS# 100-37-8 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
CAS# 100-37-8: OEL-AUSTRALIA:TWA 10 ppm (50 mg/m3);Skin OEL-AUSTRIA
:TWA 10 ppm (50 mg/m3);Skin OEL-BELGIUM:TWA 10 ppm (48 mg/m3);Skin O
EL-DENMARK:TWA 10 ppm (50 mg/m3);Skin OEL-FINLAND:STEL 10 ppm (50 mg/
m3);Skin OEL-FRANCE:TWA 10 ppm (50 mg/m3);Skin OEL-GERMANY:TWA 10 pp
m (50 mg/m3);Skin OEL-THE NETHERLANDS:TWA 10 ppm (50 mg/m3);Skin OEL
-THE PHILIPPINES:TWA 10 ppm (50 mg/m3);Skin OEL-RUSSIA:STEL 5 mg/m3;S
kin OEL-SWITZERLAND:TWA 10 ppm (50 mg/m3);Skin OEL-UNITED KINGDOM:TW
A 10 ppm (50 mg/m3);Skin OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA che
ck ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
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Section 16 - Additional Information
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MSDS Creation Date: 5/03/1999
Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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