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Section 1 - Chemical Product and Company Identification |
MSDS Name: Potassium Iodide Solution Alkaline
Catalog Numbers:
SA330-1
Synonyms:
None
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 7732-18-5 |
Water |
57 | 231-791-2 |
| 1310-73-2 |
Sodium hydroxide |
33 | 215-185-5 |
| 7681-11-0 |
Potassium iodide |
10 | 231-659-4 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless liquid.
Danger! May be fatal if swallowed. Corrosive.
Causes eye and skin burns. May cause severe respiratory and
digestive tract irritation with possible burns. May cause fetal
effects.
Target Organs: Respiratory system, eyes, skin.
Potential Health Effects
Eye:
Causes severe eye burns.
Skin:
May be fatal if absorbed through the skin. Causes skin burns. May
cause deep, penetrating ulcers of the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. Causes
severe pain, nausea, vomiting, diarrhea, and shock.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes severe irritation of upper respiratory tract with coughing,
burns, breathing difficulty, and possible coma.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
exposure can lead to iodism characterized by headache, excess
salivation, nasal discharge, conjunctivitis, laryngitis, bronchitis,
stomatitis, enlarged submaxillary glands, and skin rashes.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
Wear appropriate protective clothing to prevent contact with skin
and eyes. Wear a self-contained breathing apparatus (SCBA) to
prevent contact with thermal decomposition products. Use water with
caution and in flooding amounts. Contact with moisture or water may
generate sufficient heat to ignite nearby combustible materials.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Neutralize spill with a weak acid
such as vinegar or acetic acid. Clean up spills immediately,
observing precautions in the Protective Equipment section.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Do not ingest or inhale. Discard
contaminated shoes.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep away from strong acids. Keep away from metals. Keep
away from flammable liquids. Keep away from organic halogens.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Water
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none listed
|
none listed
|
none listed
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| Sodium hydroxide
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2 mg/m3 Ceiling
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10 mg/m3 IDLH
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2 mg/m3 TWA
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| Potassium iodide
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Water:
No OSHA Vacated PELs are listed for this chemical.
Sodium hydroxide:
No OSHA Vacated PELs are listed for this chemical.
Potassium iodide:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless
Odor: none reported
pH: Basic.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 140 deg C
Freezing/Melting Point:12 deg C
Decomposition Temperature:Not applicable.
Solubility: Soluble in water.
Specific Gravity/Density:1.5
Molecular Formula:Not applicable.
Molecular Weight:Not available.
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable.
Conditions to Avoid:
Moisture, excess heat, excess light.
Incompatibilities with Other Materials:
Generates large amounts of heat when in contact with water and may
steam and splatter. Reacts with mineral acids to form corresponding
salts; reacts with weak acids gases like hydrogen sulfide, sulfur
dioxide, and carbon dioxide; ignites when in contact with
cinnamaldehyde or zinc; and reacts explosively with a mixture of
chloroform and methane. Corrosive to metals such as aluminum, tin,
and zinc as well as to alloys such as steel, and may cause formation
of flammable hydrogen gas.
Hazardous Decomposition Products:
Toxic fumes of sodium oxide, oxides of potassium, iodine, iodide ions
(I-).
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 1310-73-2:
WB4900000
CAS# 7681-11-0:
TT2975000
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 =
>90 mL/kg;
.
CAS# 1310-73-2:
Draize test,
rabbit, eye: 400 ug Mild;
Draize
test, rabbit, eye: 1% Severe;
Draize test, rabbit, eye: 50 ug/24H
Severe;
Draize test, rabbit, eye:
1 mg/24H Severe;
Draize test,
rabbit, skin: 500 mg/24H Severe;
.
CAS# 7681-11-0:
.
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 1310-73-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7681-11-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information reported.
Teratogenicity:
No information reported. No information reported.
Reproductive Effects:
Iodine salts can cause deformity, illness and death of a
fetus.
Mutagenicity:
Mutation data reported.
Neurotoxicity:
No information reported.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
Sodium hydroxide: TLm, mosquito fish, 125 ppm/96hr. (fresh water);
TLm, bluegill, 99 mg/48hr.(tap water).
Environmental:
Sodium hydroxide is not mobile in solid form, although it absorbs
moisture very easily. Once liquid, sodium hydroxide leaches rapidly
into the soil, possibly contaminating water sources.
Physical:
No information found.
Other:
No information found.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
SODIUM HYDROXIDE SOLUTION |
SODIUM HYDROXIDE SOLUTION |
| Hazard Class: |
8 |
8 |
| UN Number: |
UN1824 |
UN1824 |
| Packing Group: |
II |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 1310-73-2 is listed on the TSCA inventory.
CAS# 7681-11-0 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 1310-73-2: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 1310-73-2: immediate, reactive.
CAS # 7681-11-0: immediate, delayed.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 1310-73-2 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 1310-73-2 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7681-11-0 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 1310-73-2: 1
CAS# 7681-11-0: 1
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 1310-73-2 is listed on Canada's DSL List.
CAS# 7681-11-0 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 1310-73-2 is listed on the Canadian Ingredient Disclosure List.
CAS# 7681-11-0 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 9/30/1997
Revision #4 Date: 9/26/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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