|
Section 1 - Chemical Product and Company Identification |
MSDS Name: Borane-trimethylamine complex
Catalog Numbers:
AC402740000, AC402740250, AC402741000
Synonyms:
Trimethylamine borane.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
|
Section 2 - Composition, Information on Ingredients
|
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 75-22-9 |
Borane-trimethylamine complex |
98 | 200-850-4 |
|
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white crystalline powder.
Danger! Flammable solid. Water-reactive. Causes
eye irritation. May cause skin and respiratory tract irritation.
Target Organs: Eyes.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
No information found.
|
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
|
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Water reactive.
Material will react with water and may release a flammable and/or
toxic gas. Flammable solid.
Extinguishing Media:
Use dry chemical, carbon dioxide, or alcohol-resistant foam. DO NOT
USE WATER!
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 3; Instability: 2; Special Hazard: -W-
|
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Remove all sources of
ignition. Use a spark-proof tool. Do not expose spill to water. Do
not get water inside containers. Do not let this chemical enter the
environment.
|
Section 7 - Handling and Storage
|
Handling:
Use with adequate ventilation. Minimize dust generation and
accumulation. Use spark-proof tools and explosion proof equipment.
Do not get in eyes, on skin, or on clothing. Keep away from heat,
sparks and flame. Do not ingest or inhale. Do not allow contact with
water.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Flammables-area.
|
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Borane-trimethylamine complex
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Borane-trimethylamine complex:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
|
Section 9 - Physical and Chemical Properties
|
Physical State: Crystalline powder
Appearance: white
Odor: Not available.
pH: Not available.
Vapor Pressure: 0.8 mm Hg @ 23 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 172 deg C @ 760 mmHg
Freezing/Melting Point:92 - 96 deg C
Decomposition Temperature:Not available.
Solubility: decomposes
Specific Gravity/Density:Not available.
Molecular Formula:C3H12BN
Molecular Weight:72.95
|
Section 10 - Stability and Reactivity
|
Chemical Stability:
Reacts with water.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid chlorides, alcohols, acid
anhydrides.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide, oxides of boron,
hydrogen gas.
Hazardous Polymerization: Has not been reported
|
Section 11 - Toxicological Information
|
RTECS#:
CAS# 75-22-9:
PA0525000
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 75-22-9:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
|
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
Do not empty into drains.
|
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
|
Section 14 - Transport Information
|
| |
US DOT |
Canada TDG |
| Shipping Name: |
FLAMMABLE SOLIDS, ORGANIC, N.O.S. |
FLAMMABLE SOLIDS, ORGANIC, N.O.S. |
| Hazard Class: |
4.1 |
4.1 |
| UN Number: |
UN1325 |
UN1325 |
| Packing Group: |
II |
II |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 75-22-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 75-22-9 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI F
Risk Phrases:
R 11 Highly flammable.
R 36 Irritating to eyes.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 39 Wear eye/face protection.
WGK (Water Danger/Protection)
CAS# 75-22-9: No information available.
Canada - DSL/NDSL
CAS# 75-22-9 is listed on Canada's NDSL List.
Canada - WHMIS
This product has a WHMIS classification of B4, B6, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
|
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #5 Date: 1/28/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
|
|