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MSDS  
:
 Saline Sodium Citrate 20X Powder
CAS  
:
 68-04-2
SYNONYMS  
:
 

Section 1 - Chemical Product and Company Identification

MSDS Name: Saline Sodium Citrate 20X Powder
Catalog Numbers: BP1326-1
Synonyms:
Sodium Citrate-Saline Mixture; SSC buffer
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7647-14-5 Sodium chloride 66.5 231-598-3
68-04-2 Trisodium citrate anhydrous 33.5 200-675-3

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless powder.
Caution! May cause respiratory and digestive tract irritation. May cause respiratory and digestive tract irritation. May cause reproductive and fetal effects.
Target Organs: No data found.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. Low hazard for usual industrial handling.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause an increase in blood pressure.
Inhalation: May cause respiratory tract irritation.
Chronic: Prolonged or repeated skin contact may cause defatting and dermatitis. May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Prolonged exposure may cause hypertension.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion.
Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Sodium chloride none listed none listed none listed
Trisodium citrate anhydrous none listed none listed none listed

OSHA Vacated PELs: Sodium chloride: No OSHA Vacated PELs are listed for this chemical. Trisodium citrate anhydrous: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties


Physical State: Powder
Appearance: colorless
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble in water.
Specific Gravity/Density:Not available.
Molecular Formula:Mixture
Molecular Weight:Not available.

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents, reducing agents, bases, dichloromaleic anhydride + urea, nitrogen compounds, lithium, bromine trifluoride.
Hazardous Decomposition Products: Chlorine, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, sodium oxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7647-14-5: VZ4725000      
CAS# 68-04-2: GE8300000
LD50/LC50:
CAS# 7647-14-5:
     Draize test, rabbit, eye: 100 mg Mild;
     Draize test, rabbit, eye: 100 mg/24H Moderate;
     Draize test, rabbit, eye: 10 mg Moderate;
     Draize test, rabbit, skin: 50 mg/24H Mild;
     Draize test, rabbit, skin: 500 mg/24H Mild;
     Inhalation, rat: LC50 = >42 gm/m3/1H;
     Oral, mouse: LD50 = 4 gm/kg;
     Oral, rat: LD50 = 3000 mg/kg;
     Skin, rabbit: LD50 = >10 gm/kg;
.

CAS# 68-04-2:
.

Carcinogenicity:
CAS# 7647-14-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 68-04-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: Teratogenic effects have occurred in experimental animals.
Reproductive Effects: Adverse reproductive effects have occurred in humans.
Mutagenicity: Mutagenic effects have occurred in humans.
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: Not regulated as a hazardous material No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7647-14-5 is listed on the TSCA inventory.
     CAS# 68-04-2 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 7647-14-5: immediate.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7647-14-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 68-04-2 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:


Safety Phrases:


WGK (Water Danger/Protection)

     CAS# 7647-14-5: 0
     CAS# 68-04-2: 0
Canada - DSL/NDSL
     CAS# 7647-14-5 is listed on Canada's DSL List.
     CAS# 68-04-2 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D2A.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 7/16/1999
Revision #4 Date: 6/29/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
PAGE Solution 110-26-9
Saline Sodium Citrate 20X Solution 6132-04-3
Saline-sodium phospate-EDTA 20X solution 60-00-4
Tris Acetate EDTA 1X to 25X Solutions 10378-23-1
Tris Acetate EDTA 25X Powder 10378-23-1
Tris Borate EDTA 10X Solution 60-00-4
Tris Borate EDTA 10X Powder 60-00-4
Tris Borate EDTA Extended Range 10X Solution 60-00-4
Tris EDTA 100X Solution 60-00-4
Tris EDTA 100X Powder 60-00-4
Tris Glycine SDS 1X to 10X Solution 151-21-3
Tris Glycine 1X to 10X Solution 56-40-6
Saline Sodium Citrate 20X Powder 68-04-2
Tris Glycine SDS 10X Powder 151-21-3
2,4,5-Trimethoxybenzoic acid 490-64-2
TCLP Extraction Fluid 2 64-19-7
Ligroine (O3387) 28729-52-4Dimethylcyclopentane<-td>
Ferrous Sulfate 1M Solution 7720-78-7
Potassium Sulfate 1 M Solution 7778-80-5
Magnesium Phosphate Tribasic 1 M Solution 7757-87-1
Ammonium Phosphate Monobasic 1M Solution 7722-76-1
Calcium Phosphate Dibasic 1M Solution 7757-93-9
Cupric nitrate 1M solution 3251-23-8
Soil Nutrient Kit Not available
Potassium Chloride 1 M Solution 7447-40-7
Potassium Phosphate Tribasic 1M Solution 7778-53-2Phosphoric acid, tripotassium salt<-td>
Potassium Phosphate Monobasic Solution 1 M 7778-77-0
Manganese(II) sulfate 1M solution 7785-87-7
Phfft 115-10-6
Artificial Urine 7732-18-5
Saturated Phenol, pH 6.6/7.9 6381-92-6
Saturated Phenol, pH 4.3/4.5 877-24-7
(2S,3S)-(+)-cis-2,3-Dihydroxy-2,3-dihydrochlorobenzene 65986-73-4
Phenol/Chloroform/Isoamyl Alcohol, pH 4.3 123-51-3
Phenol/Chloroform/Isoamyl Alcohol (pH5.2) 123-51-3
Tris 1 Molar Buffer 1185-53-1
Tris 2 Molar Buffer 77-86-1
Crystal Violet Ammonium Oxalate 548-62-9
Ferrous ammonium sulfate 0.5M solution 7783-85-9
Solution #4 7732-18-5
Solution #5 127-09-3
Solution #6 Not available
4-Chloro-alpha-methylstyrene, 96% (GC) 1712-70-5
1,9-Diphenyl-1,3,6,8-nonatetraen-5-one, 98% (uv-vis) 622-21-9
4-Methoxystilbene, 98+% 1142-15-0
Phenoxy resin, average m.w. 85000 26402-79-9
2,3,5-Trimethylanisole, 99% 20469-61-8
4-Methoxybenzylamine, 98% 2393-23-9
4-Nitrophenyl phosphate tris buffer salt, 98% (titr.) 52435-04-8
Picrotoxin, 99% 124-87-8



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