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MSDS  
:
 5-Hydroxypentanal, Tech.
CAS  
:
 4221-03-8
SYNONYMS  
:
 5-Hydroxyvaleraldehyde

Section 1 - Chemical Product and Company Identification
MSDS Name: 5-Hydroxypentanal, Tech.
Catalog Numbers: AC156410000, AC156410250
Synonyms:
5-Hydroxyvaleraldehyde
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
4221-03-8 5-Hydroxypentanal 100 224-165-5

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear, colorless liquid.
Caution! May cause eye and skin irritation. May cause respiratory and digestive tract irritation. The toxicological properties of this material have not been fully investigated.
Target Organs: No data found.


Potential Health Effects
Eye: May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin: May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic: No information found.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode in the heat of a fire. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out.
Flash Point: > 112 deg C (> 233.60 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:N/A
Upper: N/A
NFPA Rating: (estimated) Health: ; Flammability: 1; Instability:

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
5-Hydroxypentanal none listed none listed none listed

OSHA Vacated PELs: 5-Hydroxypentanal: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: 3.5
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 115 deg C @ 15.00mmHg
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:1.0550g/cm3
Molecular Formula:C5H10O2
Molecular Weight:102.13

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials: Oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 4221-03-8 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 4221-03-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: Not regulated as a hazardous material No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 4221-03-8 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 4221-03-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:


Safety Phrases:

     S 24/25 Avoid contact with skin and eyes.
     S 37 Wear suitable gloves.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 28A After contact with skin, wash immediately with plenty of water
     .

WGK (Water Danger/Protection)

     CAS# 4221-03-8: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     WHMIS: Not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 5/12/1998
Revision #4 Date: 10/03/2005

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
6-(Bromomethyl)bicyclo[2.2.1]hept-2-yl 4-methylbenzene-1-sulfonate Not available
Methyl 2-(2-acetyl-4,5-dimethoxyphenyl)acetate 17173-27-2
di(2,4,6-Trichlorophenyl) 2-benzylmalonate 15781-74-5
4-Ethylbenzene-1-carbohydrazide 64328-55-8
5-Hydroxypentanal, Tech. 4221-03-8
(3-Pyrimidin-5-ylphenyl)methanol 852180-75-7
4-Pyrimidin-5-ylbenzaldehyde 198084-12-7
Platinum(iv) oxide hydrate, typical pt-content 79-84% 52785-06-5
4-(Piperidin-1-ylmethyl)benzaldehyde 471929-86-9
2-[4-(Trifluoromethyl)phenyl]-1,3-thiazole-4-carbaldehyde 174006-70-3
N-Methyl-N-({2-[4-(trifluoromethyl)phenyl]-1,3-thiazol-4-yl}methyl)amine 857284-26-5
Ethyl 6-(2-Oxocyclopentyl)-Hexanoate 96% 63135-03-5
4-Phenyl-5-(trifluoromethyl)-2-thiophenecarbonyl chloride 208108-75-2
Ethyl 5-(2-thienyl)isoxazole-3-carboxylate 90924-54-2
3-(Bromomethyl)-5-phenylisoxazole 154016-50-9
2-Methyl-2-(2-naphthyloxy) propanoic acid 7756-78-7
1-[(Methylthio)methyl]piperidine 17859-41-5
Propylbenzene, 98% (GC) 103-65-1
(4-Pyrimidin-5-ylphenyl)methanol 198084-13-8
5-(Pyrid-3-yloxy)-2-furaldehyde 857284-14-1
(5-Phenylisoxazol-3-yl)methanol 1619-37-0
3-Pyrimidin-5-ylbenzaldehyde 640769-70-6
3-(1-Pyrrolidinyl)benzonitrile 175696-73-8
1-Phenyl-3-(2-thienyl)prop-2-en-1-one 2910-81-8
1-Phenyl-3-(3-thienyl)prop-2-en-1-one 106522-00-3
2-Chloro-3-phenylacrylaldehyde oxime 35088-92-7
2,4-Dichloro-1,3-thiazole-5-carbaldehyde oxime Not available
2,3,5,6-Tetrachlorobenzene-1-thiol 4707-16-8
5-Chloro-2-fluoroaniline 2106-05-0
3-Chloro-4,4,4-trifluoro-2-phenylbut-2-enal oxime Not available
N-(4-Bromophenyl)-N'-[6-chloro-4-(trifluoromethyl)-2-pyridyl]urea Not available
N-(4-Methoxybenzyl)-N-(4-methoxy-3-methylbenzyl)amine Not available
6-(Chloromethyl)-2-[5-(trifluoromethyl)-2-pyridyl]pyrimidin-4-ol Not available
2,6-Dichloro-4-(trifluoromethyl)pyridin-3-amine 175277-67-5
1-(4-Nitrophenyl)-3,5-di(trifluoromethyl)-1H-pyrazole 123066-63-7
2-Bromo-5-chloro-1-benzothiophene-3-carbaldehyde 680212-97-9
1-Chloro-1-methylcyclohexane 931-78-2
2,3-Dihydrobenzo[b]furan-3-one 7169-34-8
(5-Chloro-1,3-dimethyl-1H-pyrazol-4-yl)(1,3-dimethyl-1H-pyrazol-5-yl)methanone Not available
1,3-Benzodioxole-5-sulfonyl chloride 115010-10-1
Thieno[2,3-b]pyridine-2-carbaldehyde 53174-98-4
Thieno[2,3-b]pyridin-2-ylmethanol 131337-81-0
N-[4-(1H-Imidazol-1-yl)benzyl]-N-methylamine 179873-45-1
(2,5-Dimethyl-1,3-oxazol-4-yl)methanol 92901-94-5
[4-(Piperidin-1-ylmethyl)phenyl]methanol 91271-62-4
4'-Aminoacetanilide, >95% 122-80-5
Methyltriphenylphosphonium bromide 1779-49-3
4,4'-Bis(Dimethylamino)benzophenone, 98% 90-94-8
2-Bromomesitylene, 99% 576-83-0
1-Bromo-2-nitrobenzene 577-19-5



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