|
Section 1 - Chemical Product and Company Identification |
MSDS Name: 1-Tetradecylamine
Catalog Numbers:
AC138100000, AC138100050, AC138100100, AC138101000, AC138102500
Synonyms:
1-Aminotetradecane; Monotetradecylamine; Myristylamine.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
|
Section 2 - Composition, Information on Ingredients
|
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 2016-42-4 |
1-Tetradecylamine |
98 | 217-950-9 |
|
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: pink solid.
Danger! Causes eye and skin burns. Causes
digestive and respiratory tract burns.
Target Organs: Respiratory system, eyes, skin,
mucous membranes.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Amines have been known to cause skin
irritation/corrosion and allergic skin reaction. No skin absorption
data found.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Material has a low
vapor pressure at room temperature, so exposure to vapor is not
likely.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
Octadecylamine, a similar chemical, was tested for chronic toxicity
in rats exposed through the diet to up to 500 ppm for 2 years. No
significant pathological differences between control and test animals
were observed.
|
Section 4 - First Aid Measures
|
Eyes:
In case of contact, immediately flush eyes with plenty of water for a
t least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically.
|
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Contact
with metals may evolve flammable hydrogen gas. Runoff from fire
control or dilution water may cause pollution.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
Flash Point: > 110 deg C (> 230.00 deg F)
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 1; Instability: 0
|
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
|
Section 7 - Handling and Storage
|
Handling:
Remove contaminated clothing and wash before reuse. Minimize dust
generation and accumulation. Do not breathe dust, mist, or vapor. Do
not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale. Use only in a chemical fume hood.
Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
|
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| 1-Tetradecylamine
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
1-Tetradecylamine:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
|
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: white - pink
Odor: fish-like
pH: Not available.
Vapor Pressure: .001 mm Hg @ 25 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 291 deg C @ 760mmHg
Freezing/Melting Point:37 - 42 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:0.993
Molecular Formula:C14H31N
Molecular Weight:213.41
|
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, acid chlorides, aluminum, acid
anhydrides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
|
Section 11 - Toxicological Information
|
RTECS#:
CAS# 2016-42-4:
XB7970000
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 2016-42-4:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
|
Section 12 - Ecological Information
|
Ecotoxicity:
Fish: Pseudomonas putida:
|
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
|
Section 14 - Transport Information
|
| |
US DOT |
Canada TDG |
| Shipping Name: |
AMINES, SOLID, CORROSIVE, N.O.S. |
CORROSIVE SOLID BASIC ORGANIC NOS (1-TETRADECYLAMINE) |
| Hazard Class: |
8 |
8 |
| UN Number: |
UN3259 |
UN3263 |
| Packing Group: |
III |
III |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 2016-42-4 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 2016-42-4 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 2016-42-4: No information available.
Canada - DSL/NDSL
CAS# 2016-42-4 is listed on Canada's NDSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
|
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #8 Date: 11/14/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
|
|