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Section 1 - Chemical Product and Company Identification |
MSDS Name: Nitric acid-d, 68 wt. % solution in d2o, 99+ atom % d
Catalog Numbers:
AC175430000, AC175430250, AC175430500
Synonyms:
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 13587-52-5 |
Nitric acid-d, 68 wt. % solution in D2O |
| 237-024-8 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless liquid.
Oxidizer. Hygroscopic (absorbs moisture from the air).
Target Organs: Respiratory system, teeth, eyes,
skin.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract.
Inhalation:
May be fatal if inhaled. Effects may be delayed. May cause
irritation of the respiratory tract with burning pain in the nose and
throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure
may cause erosion of teeth.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
No specific antidote exists.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. Substance is noncombustible.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Substance is noncombustible; use agent most
appropriate to extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: ; Flammability: ; Instability:
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wear a self contained breathing
apparatus and appropriate personal protection. (See Exposure
Controls, Personal Protection section). Neutralize spill with sodium
bicarbonate. Use water spray to disperse the gas/vapor.
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Section 7 - Handling and Storage
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Handling:
Do not breathe dust, mist, or vapor. Do not get in eyes, on skin, or
on clothing. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area. Store under an
inert atmosphere.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Nitric acid-d, 68 wt. % solution in D2O
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Nitric acid-d, 68 wt. % solution in D2O:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:DNO3
Molecular Weight:64.02
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Section 10 - Stability and Reactivity
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Chemical Stability:
Decomposes when in contact with air, light, or organic matter.
Conditions to Avoid:
High temperatures, incompatible materials, light, combustible
materials, organic materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, bases, metals.
Hazardous Decomposition Products:
Nitrogen oxides.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 13587-52-5
unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 13587-52-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
Data for nitric acid; CAS# 7697-37-2; Rtecs#
QU5775000:Effects on newborn: biochemical and metabolic,
Oral-rat TDLo=2345 mg/kg (female 18D post). Fetotoxicity:
Stunted fetus, Oral-rat TDLo=21150 mg/kg (female 1-21D
post).
Reproductive Effects:
For nitric acid: orl-rat TDLo:21150 mg/kg (female 1-21D
preg)orl-rat TDLo:2345 mg/kg (female 18D preg)
Mutagenicity:
No information available.
Neurotoxicity:
For nitric acid: EPA Genetox Program 1988, Negative: Cell
transform.-SA7/SHE
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
For nitric acid:Mosquito fish: TLm=72 ppm/96H (fresh water) Cockle:
LC50=330-1000 ppm/48H (salt water)
Environmental:
No information available.
Physical:
No information available.
Other:
None.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
NITRIC ACID |
No information available. |
| Hazard Class: |
8 |
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| UN Number: |
UN2031 |
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| Packing Group: |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 13587-52-5 is not listed on the TSCA inventory.
It is for research and development use only.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 13587-52-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 35 Causes severe burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 13587-52-5: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
WHMIS: Not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 1/18/2000
Revision #4 Date: 3/26/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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