Section 1 - Chemical Product and Company Identification |
MSDS Name: Vanadyl(IV)-sulfate hydrate, 17-23% Vanadium
Catalog Numbers:
AC214840000, AC214841000
Synonyms:
Oxysulfato vanadium (IV) hydrate; Vanadium oxysulfate;
Oxo[sulfato(2-)-O]-Vanadium; Vanadyl (IV) sulfate; Oxysulfato
vanadium (IV); Vanadium (IV) sulfate oxide; Vanadyl(IV)-sulfate
hydrate
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
12439-96-2 |
Vanadyl(IV)-sulfate hydrate |
100 | unlisted |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: blue crystals.
Warning! Causes eye, skin, and respiratory tract
irritation.
Target Organs: Respiratory system, eyes, skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Vanadium compounds can cause polycythemia (an increase in
the total red cell mass of the blood), followed by red blood cell
destruction, anemia, loss of appetite, pallor, and emaciation. May
cause greenish-black tongue discoloration due to deposition of
vanadium salts.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed. May produce scattered allergy-like
eczematous skin lesions symptomatic of vanadium toxicity.
Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Use with adequate ventilation. Wash
clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Vanadyl(IV)-sulfate hydrate
|
none listed
|
none listed
|
none listed
|
Vanadyl sulfate
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Vanadyl(IV)-sulfate hydrate:
No OSHA Vacated PELs are listed for this chemical.
Vanadyl sulfate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
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Physical State: Crystals
Appearance: blue
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:Not available.
Molecular Formula:O5SV.xH2O
Molecular Weight:163.00
Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Chlorine, lithium, strong acids, strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
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RTECS#:
CAS# 12439-96-2:
YW1840000
CAS# 27774-13-6:
YW1925000
LD50/LC50:
CAS# 12439-96-2: Oral, mouse: LD50
= 467 mg/kg; Oral, mouse: LD50 =
467 mg/kg; Oral, rat: LD50 = 448
mg/kg; Oral, rat: LD50 = 448
mg/kg; .
CAS# 27774-13-6: Skin, rabbit:
LD50 = 4450 mg/kg; .
Carcinogenicity:
CAS# 12439-96-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 27774-13-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
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No information available.
Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
VANADYL SULFATE |
VANADYL SULPHATE |
Hazard Class: |
6.1 |
6.1 |
UN Number: |
UN2931 |
UN2931 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 12439-96-2 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 27774-13-6 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 27774-13-6: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 27774-13-6: immediate.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 27774-13-6 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 12439-96-2 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 27774-13-6 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 12439-96-2: No information available.
CAS# 27774-13-6: No information available.
Canada - DSL/NDSL
CAS# 27774-13-6 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 27774-13-6 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997 Revision #7 Date: 9/26/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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