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Section 1 - Chemical Product and Company Identification |
MSDS Name: N,N,N',N'-Tetramethyl-1,3-propanediamine, 99+%
Catalog Numbers:
AC155510000, AC155510100, AC155510500
Synonyms:
1,3-Propanediamine, N,N,N',N'-tetramethyl-;
N,N,N',N'-Tetramethyl-1,3-diaminopropane;
N,N,N',N'-Tetramethyltrimethylenediamine; Propane-1,3-diamine,
N,N,N',N'-tetramethyl-; Tetramethyltrimethylenediamine
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 110-95-2 |
N,N,N',N'-Tetramethyl-1,3-propanediamine |
99+ | 203-818-8 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: clear, colorless clear liquid. Flash Point: 31 deg C.
Warning! Toxic. May be readily absorbed through
the skin. Forms explosive mixture with air. Causes eye and skin
irritation and burns. Flammable liquid and vapor.
Harmful if swallowed, inhaled, or absorbed through the skin. May
cause severe respiratory and digestive tract irritation with possible
burns. May cause central nervous system depression.
Target Organs: Central nervous system.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Harmful if absorbed through the skin. May cause severe irritation
and possible burns. Substance is readily absorbed through the skin.
May cause cyanosis of the extremities.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. Ingestion of large amounts may cause
CNS depression.
Inhalation:
Exposure produces central nervous system depression. Inhalation may
be fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea, and vomiting. Harmful if inhaled.
Chronic:
Effects may be delayed.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. In case of fire,
use carbon dioxide, dry chemical powder or appropriate foam.
Flash Point: 31 deg C ( 87.80 deg F)
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 3; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Remove all sources of ignition. Use
a spark-proof tool. A vapor suppressing foam may be used to reduce
vapors.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Ground and
bond containers when transferring material. Use spark-proof tools and
explosion proof equipment. Do not get in eyes, on skin, or on
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep away from heat, sparks and flame.
Do not ingest or inhale. Use and store under nitrogen. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Do not breathe vapor.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Keep containers tightly
closed.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| N,N,N',N'-Tetramethyl-1,3-propanediamine
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
N,N,N',N'-Tetramethyl-1,3-propanediamine:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Clear liquid
Appearance: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 760 mm Hg @ 145 deg C
Vapor Density: 4.49
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 145.0 - 146.0 deg C @ 760.00m
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Miscible.
Specific Gravity/Density:0.779
Molecular Formula:C7H18N2
Molecular Weight:130.23
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Acid chlorides, acids, acid anhydrides, strong oxidizing agents,
carbon dioxide.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 110-95-2:
TX8400000
LD50/LC50:
CAS# 110-95-2:
Oral, rat: LD50 =
410 uL/kg;
Skin, rabbit: LD50 = 300
uL/kg;
.
Inhalation, rat: LD50 = 375
Carcinogenicity:
CAS# 110-95-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
No data available.
Physical:
No data available.
Other:
None.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. |
FLAMMABLE LIQUID CORROSIVE NOS (NNNN-TETRAMETHYL-1) |
| Hazard Class: |
8 |
3(8) |
| UN Number: |
UN2734 |
UN2924 |
| Packing Group: |
II |
III |
| Additional Info: | | FP=31C |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 110-95-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 110-95-2 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 24 Toxic in contact with skin.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static discharges.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 110-95-2: 2
Canada - DSL/NDSL
CAS# 110-95-2 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D1B, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997
Revision #5 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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