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Section 1 - Chemical Product and Company Identification |
MSDS Name: Tin(IV) Chloride Pentahydrate
Catalog Numbers:
T137-100, T137-500
Synonyms:
Stannic chloride pentahydrate; Tetrachlorostannane pentahydrate .
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 10026-06-9 |
Stannic chloride pentahydrate |
>98 | unlisted |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: white to yellow solid.
Danger! Causes eye and skin burns. Causes
digestive and respiratory tract burns.
Target Organs: Eyes, skin, mucous membranes.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause severe skin irritation with possible burns, especially if
skin is wet or moist.
Ingestion:
May cause severe digestive tract irritation with abdominal pain,
nausea, vomiting and diarrhea. May cause corrosion and permanent
tissue destruction of the esophagus and digestive tract.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema. May
cause severe irritation of the upper respiratory tract with pain,
burns, and inflammation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
exposure to tin oxide dusts and fumes may result in stannosis (benign
pneumoconiosis).
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Section 4 - First Aid Measures
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Eyes:
In case of contact, immediately flush eyes with plenty of water for a
t least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
No specific antidote exists. Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Not combustible, but if involved in a fire, decomposes to
produce hydrogen chloride.
Extinguishing Media:
Do NOT use water directly on fire. Use extinguishing media most
appropriate for the surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 1
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Provide ventilation. Use water spray
to cool and disperse vapors and protect personnel.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Do not
get in eyes, on skin, or on clothing. Do not ingest or inhale. Use
only with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep away from metals. Corrosives area. Do not get water
inside containers.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Stannic chloride pentahydrate
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2 mg/m3 TWA (as Sn, except Tin hydride) (listed under Tin inorganic compounds).
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2 mg/m3 TWA (as Sn, except Tin oxide) (listed under Tin inorganic compounds).100 mg/m3 IDLH (as Sn, except Tin oxides) (listed under Tin inorganic compounds).
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2 mg/m3 TWA (as Sn, except oxides) (listed under Tin inorganic compounds).
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| Stannic chloride, anhydrous
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2 mg/m3 TWA (as Sn, except Tin hydride) (listed under Tin inorganic compounds).
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2 mg/m3 TWA (as Sn, except Tin oxide) (listed under Tin inorganic compounds).100 mg/m3 IDLH (as Sn, except Tin oxides) (listed under Tin inorganic compounds).
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2 mg/m3 TWA (as Sn, except oxides) (listed under Tin inorganic compounds).
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OSHA Vacated PELs:
Stannic chloride pentahydrate:
No OSHA Vacated PELs are listed for this chemical.
Stannic chloride, anhydrous:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Solid
Appearance: white to yellow
Odor: hydrochloric odor - slight odor
pH: Acidic in solution.
Vapor Pressure: 10 mm Hg @ 10 deg C
Vapor Density: Not available.
Evaporation Rate:Not applicable.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:56 deg C
Decomposition Temperature:Not available.
Solubility: Freely Soluble.
Specific Gravity/Density:2.2 (water=1)
Molecular Formula:SnCl4.5H2O
Molecular Weight:350.57
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
High temperatures, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases, alcohols, amines, ethylene oxide, potassium, sodium,
alkyl nitrates, turpentine.
Hazardous Decomposition Products:
Hydrogen chloride, tin/tin oxides.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 10026-06-9:
XP8870000
CAS# 7646-78-8:
XP8750000
LD50/LC50:
Not available.
CAS# 7646-78-8:
Inhalation,
rat: LC50 = 2300 mg/m3/10M;
.
Carcinogenicity:
CAS# 10026-06-9:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7646-78-8:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
See actual entry in RTECS for complete information.
Neurotoxicity:
No information available.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
STANNIC CHLORIDE, PENTAHYDRATE |
STANNIC CHLORIDE PENTAHYDRATE |
| Hazard Class: |
8 |
8 |
| UN Number: |
UN2440 |
UN2440 |
| Packing Group: |
III |
III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 10026-06-9 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 7646-78-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10026-06-9: immediate, delayed.
CAS # 7646-78-8: immediate, delayed, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 10026-06-9 can be found on the
following state right to know lists: New Jersey.
CAS# 7646-78-8 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 34 Causes burns.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 7/8 Keep container tightly closed and dry.
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 10026-06-9: No information available.
CAS# 7646-78-8: 1
Canada - DSL/NDSL
CAS# 7646-78-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 10026-06-9 is not listed on the Canadian Ingredient Disclosure List.
CAS# 7646-78-8 is not listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 6/21/1999
Revision #6 Date: 2/15/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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