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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 10/03/2005 Reviewed on 10/03/2005
1 Identification of substance:
Product details:
Product name: 3-Methyl-2-butanone
Stock number:
B24527
L13327
Manufacturer/Supplier:
Alfa Aesar, A Johnson Matthey Company
Johnson Matthey Catalog Company, Inc.
30 Bond Street
Ward Hill, MA 01835-8099
Emergency Phone: (978) 521-6300
CHEMTREC: (800) 424-9300
Web Site: www.alfa.com
Information Department: Health, Safety and Environmental Department
Emergency information:
During normal hours the Health, Safety and Environmental Department.
After normal hours call Chemtrec at (800) 424-9300.
2 Composition/Data on components:
Chemical characterization:
Description: (CAS#)
3-Methyl-2-butanone (CAS# 563-80-4): 100%
Identification number(s):
EINECS Number: 209-264-3
EU Number: 606-007-00-0
3 Hazards identification
Hazard description:
F Highly flammable
Information pertaining to particular dangers for man and environment
R 11 Highly flammable.
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH 1 Health (acute effects) = 1
Flammability = 3
FIRE 3
Reactivity = 1
REACTIVITY 1
4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep
patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
(Contd. on page 2)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 10/03/2005 Reviewed on 10/03/2005
Product name: 3-Methyl-2-butanone
(Contd. of page 1)
After eye contact
Rinse opened eye for several minutes under running water. Then consult a
doctor.
After swallowing Seek immediate medical advice.
5 Fire fighting measures
Suitable extinguishing agents
Carbon dioxide, extinguishing powder or water spray. Fight larger fires
with water spray or alcohol resistant foam.
Special hazards caused by the material, its products of combustion or
resulting gases:
In case of fire, the following can be released:
Carbon monoxide and carbon dioxide
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
6 Accidental release measures
Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Measures for environmental protection:
Do not allow material to be released to the environment without proper
governmental permits.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders,
universal binders, sawdust).
Ensure adequate ventilation.
Keep away from ignition sources.
Additional information:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
Handling
Information for safe handling:
Keep container tightly sealed.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Keep ignition sources away.
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Protect from heat.
Further information about storage conditions:
Keep container tightly sealed.
(Contd. on page 3)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 10/03/2005 Reviewed on 10/03/2005
Product name: 3-Methyl-2-butanone
(Contd. of page 2)
Store in cool, dry conditions in well sealed containers.
8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals
and having an average face velocity of at least 100 feet per minute.
Components with limit values that require monitoring at the workplace:
3-Methyl-2-butanone
ppm
ACGIH TLV 200
Belgium TWA 200
Denmark TWA 200
Finland TWA 200; 250-STEL
France VME 200
Korea TLV 200
Netherlands MAC-TGG 200
Switzerland MAK-W 200
Components with limit values that require monitoring at the workplace:
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be
followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Check protective gloves prior to each use for their proper condition.
Impervious gloves
Material of gloves
The selection of suitable gloves not only depends on the material, but
also on quality. Quality will vary from manufacturer to manufacturer.
Eye protection: Safety glasses
Body protection: Protective work clothing.
9 Physical and chemical properties:
General Information
Form: Liquid
Odor: Not determined
Change in condition
Melting point/Melting range: -92掳C (-134掳F)
Boiling point/Boiling range: 94-95掳C (201-203掳F)
Sublimation temperature / start: Not determined
Flash point: 6掳C (43掳F)
Ignition temperature: Not determined
(Contd. on page 4)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 10/03/2005 Reviewed on 10/03/2005
Product name: 3-Methyl-2-butanone
(Contd. of page 3)
Decomposition temperature: Not determined
Danger of explosion: Product is not explosive. However,
formation of explosive air/vapor
mixtures is possible.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not determined
Density at 20掳C (68掳F): 0.805 g/cm鲁
Solubility in / Miscibility with
Water: Not determined
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to
specifications.
Materials to be avoided:
Oxidizing agents
Heat
Dangerous reactions No dangerous reactions known
Dangerous products of decomposition: Carbon monoxide and carbon dioxide
11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral LD50 2572 mg/kg (mus)
3078 mg/kg (rat)
Dermal LD50 6350 mg/kg (rbt)
Inhalative LC50 30000 mg/m3 (mus)
LCLo/4H 5700 ppm/4H (rat)
Irritation of skin mild 500 mg (rbt)
moderate 500 mg/24H (rbt)
Irritation of eyes mild 100 mg/24H (rbt)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Other information (about experimental toxicology):
Mutagenic effects have been observed on tests with bacteria.
Subacute to chronic toxicity:
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) reports the
following effects in laboratory animals:
Lungs, Thorax, or Respiration - other changes.
Liver - other changes.
Kidney, Ureter, Bladder - other changes.
(Contd. on page 5)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 10/03/2005 Reviewed on 10/03/2005
Product name: 3-Methyl-2-butanone
(Contd. of page 4)
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
No classification data on carcinogenic properties of this material is
available from the EPA, IARC, NTP, OSHA or ACGIH.
12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper
governmental permits.
13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
14 Transport information
DOT regulations:
Hazard class: 3
Identification number: UN1224
Packing group: II
Proper shipping name (technical
name): KETONES, LIQUID, N.O.S. (3-Methyl-2-
butanone)
Label 3
Land transport ADR/RID (cross-border)
ADR/RID class: 3 Flammable liquids
Danger code (Kemler): 33
UN-Number: 1224
Packaging group: II
Description of goods: 1224 KETONES, LIQUID, N.O.S. (vapor
pressure at 50掳C at most 110 kPa) (3-
Methyl-2-butanone)
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Material Safety Data Sheet
acc. to OSHA and ANSI
Printing date 10/03/2005 Reviewed on 10/03/2005
Product name: 3-Methyl-2-butanone
(Contd. of page 5)
Maritime transport IMDG:
IMDG Class: 3
UN Number: 1224
Label 3
Packaging group: II
Proper shipping name: KETONES, LIQUID, N.O.S. (3-Methyl-2-
butanone)
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 3
UN/ID Number: 1224
Label 3
Packaging group: II
Proper shipping name: KETONES, LIQUID, N.O.S. (3-Methyl-2-
butanone)
15 Regulations
Product related hazard informations:
Hazard symbols:
F Highly flammable
Risk phrases:
11 Highly flammable.
Safety phrases:
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
33 Take precautionary measures against static discharges.
National regulations
All components of this product are listed in the U.S. Environmental
Protection Agency Toxic Substances Control Act Chemical substance
Inventory.
All components of this product are listed on the Canadian Domestic
Substances List (DSL).
Information about limitation of use:
For use only by technically qualified individuals.
16 Other information:
Employers should use this information only as a supplement to other
information gathered by them, and should make independent judgement of
suitability of this information to ensure proper use and protect the
health and safety of employees. This information is furnished without
warranty, and any use of the product not in conformance with this
Material Safety Data Sheet, or in combination with any other product or
process, is the responsibility of the user.
Department issuing MSDS: Health, Safety and Environmental Department.
Contact: Darrell R. Sanders
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