SAFETY DATA SHEET
Australian version - NOHSC:2011 (2003)
OXYPER 庐
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
1.1. Identification of the substance/preparation
Product name : OXYPER 庐
Chemical Name : Sodium carbonate peroxyhydrate
Synonyms : Sodium percarbonate
Commercial Product Name : OXYPER 庐 / Coated OXYPER 庐
Molecular formula : 2Na2CO3.3H2O2
Molecular Weight : 314.06 g/mol
1.2. Use of the Substance/Preparation
Recommended use : - Bleaching agents
- cleaning agent
- Disinfectants and general biocidal products
- oxidizing agents
1.3. Company/Undertaking Identification
Address : SOLVAY INTEROX Pty Ltd
MCPHERSON STREET, 20-22
AUS- 2019 BANKSMEADOW
Telephone : 61293168000
Telefax : 61293166445
1.4. Emergency telephone number
:
Telephone 1 800 023 488 (Emergency 24 Hour)
+44 1865 407333 [CareChem 24] (Australia, New
Zealand)
AU: +61-2-93168000 (Product information)
2. HAZARDS IDENTIFICATION
: crystalline powder
Appearance
: white
Colour
: odourless
Odour
- Classified as hazardous according to criteria of NOHSC.
- Classified as dangerous goods according to the ADG Code
- Oxidising
- Contact with combustible material may cause fire.
- Harmful if swallowed.
- Risk of serious damage to eyes.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Sodium carbonate peroxyhydrate
CAS-No. : 15630-89-4
Symbol(s) : Xn, O
R-phrase(s) : R 8, R22, R41
:
Concentration > 88.00 %
4. FIRST AID MEASURES
4.1. Inhalation
- Remove the subject from dusty environment and let him blow his nose.
- If symptoms persist, call a physician.
4.2. Eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).
- Consult with an ophthalmologist immediately in all cases.
4.3. Skin contact
- Wash off with plenty of water.
- Wash contaminated clothing before re-use.
- If symptoms persist, call a physician.
4.4. Ingestion
The following actions are recommended :
- Consult a physician.
If victim is conscious:
- Clean mouth with water and drink afterwards plenty of water.
- Do NOT induce vomiting.
If victim is unconscious but breathing:
- not applicable
5. FIRE-FIGHTING MEASURES
5.1. Suitable extinguishing media
- Large quantities of water, water spray.
- Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
5.2. Extinguishing media which must not be used for safety reasons
- None.
5.3. Special exposure hazards in a fire
- Oxidizer
- Oxygen released on exothermic decomposition may support combustion in case of surrounding
fire.
- Risk of explosion if heated under confinement.
- Do not spray the dry product with water, except in case of fire.
- Wet product decomposes exothermically and may cause combustion of organic materials.
5.4. Special protective equipment for fire-fighters
- When intervention in close proximity wear acid resistant over suit.
5.5. Other information
- Keep product and empty container away from heat and sources of ignition.
- HAZCHEM Code: 1Y
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6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions
- Refer to protective measures listed in sections 7 and 8.
- Keep away from incompatible products
- Keep away from water.
6.2. Environmental precautions
- Small quantities can be discharged into the sewer with large quantities of water.
- If the product contaminates rivers and lakes or drains inform respective authorities.
6.3. Methods for cleaning up
- Pick up and arrange disposal without creating dust.
- All receiving equipment should be clean, vented, dry, labelled and made of material that is
compatible with the product.
- Because of the contamination risk, the collected material should be isolated in a safe place.
- Flush with plenty of water.
- Treat recovered material as described in the section "Disposal considerations".
7. HANDLING AND STORAGE
7.1. Handling
- Clean and dry piping circuits and equipment before any operations.
- Never return unused material to storage receptacle.
- Keep away from incompatible products
- Containers and equipment used to handle the product should be used exclusively for that
product.
- Avoid any contact with water or humidity.
- For further information, please contact: Supplier
7.2. Storage
- Keep in a dry place.
- Keep away from direct sunlight.
- Keep away from heat.
- Keep away from incompatible products
- Keep in container fitted with safety valve or vent.
- The container must be used exclusively for the product.
- Keep only in the original container at temperature not exceeding 40 掳C.
7.3. Specific use(s)
- For further information, please contact: Supplier
7.4. Packaging material
- stainless steel
- Polyethylene
- Paper + PE coating.
- glass
- Passivated aluminium
7.5. Other information
- Refer to protective measures listed in sections 7 and 8.
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Exposure Limit Values
Sodium carbonate peroxyhydrate
- SAEL (Solvay Acceptable Exposure Limit) 2005
TWA = 5 mg/m3
8.2. Exposure controls
- Ensure adequate ventilation.
- Provide appropriate exhaust ventilation at machinery.
- Refer to protective measures listed in sections 7 and 8.
8.2.1. Occupational exposure controls
8.2.1.1. Respiratory protection
- In case of dust clouds/fog/fumes, dust mask type P2.
8.2.1.2. Hand protection
- protective gloves
- Recommended materials: PVC, neoprene, rubber
8.2.1.3. Eye protection
- Dust proof goggles, if dusty.
8.2.1.4. Skin and body protection
- protective suit
8.2.1.5. Hygiene measures
- Shower and eye wash stations.
- Handle in accordance with good industrial hygiene and safety practice.
8.2.2. Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. General Information (appearance, odour)
: crystalline powder
Appearance
: white
Colour
: odourless
Odour
9.2. Important Health Safety and Environmental Information
: from 10.4 - 10.6
pH
Concentration: 10.101 g/l
: Remarks: Not applicable
Boiling point/range
: Remarks: Not applicable
Flash point
: Lower explosion limit:
Flammability (solid, gas)
Remarks: Not applicable
: Remarks: Non-explosive
Explosive properties
: Remarks: Oxidizer
Oxidizing properties
: Remarks: Not applicable
Vapour pressure
: Remarks: no data available
Relative density / Density
: 0.9 - 1.2 kg/m3
Bulk density
: water
Solubility
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150 g/l
Temperature: 20 掳C
: water
175 g/l
Temperature: 30 掳C
: Remarks: Not applicable
Partition coefficient (n-
octanol/water)
: Remarks: Not applicable
Viscosity
: Remarks: Not applicable
Vapour density
9.3. Other data
: Remarks: Not applicable (before melting)
Melting point/range
: 95 % < 1.4 mm
Granulometry
95 % > 0.15 mm
: Remarks: Self-accelerating decomposition with oxygen release
Decomposition
starting from 50掳C
temperature
10. STABILITY AND REACTIVITY
10.1. Stability
- Potential for exothermic hazard
10.2. Conditions to avoid
- Heat.
- Exposure to moisture.
10.3. Materials to avoid
- water
- acids
- bases
- heavy metal salts
- reducing agents
- organic materials
- flammable materials
10.4. Hazardous decomposition products
- oxygen
11. TOXICOLOGICAL INFORMATION
11.1 Toxicological data
Acute oral toxicity
- LD50, rat, 1,034 mg/kg
Acute inhalation toxicity
- LC0, 1 h, rat, > 4,580 mg/m3
Acute dermal toxicity
- LD lo, rabbit, > 2,000 mg/kg
Skin irritation
- rabbit, slightly irritant (skin)
Eye irritation
- rabbit, Risk of serious damage to eyes.
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Sensitization
- No data
Chronic toxicity
- no data available
Possible hazards (summary)
- Harmful if swallowed.
- Risk of serious damage to eyes.
11.2. Health effects
Main effects
- The product causes irritation of eyes, skin and mucous membranes.
- Risk of serious damage to eyes.
Inhalation
- Irritating to mucous membranes
- At high concentrations, cough.
- In case of repeated or prolonged exposure: risk of sore throat, nose bleeds, chronic bronchitis.
Eye contact
- Severe eye irritation, watering and redness.
- Risk of serious or permanent eye lesions.
Skin contact
- slight irritation
- Chronic exposure may cause dermatitis.
Ingestion
- Severe irritation of the mouth, throat, oesophagus and stomach.
- Bloating of stomach, belching.
- Nausea, vomiting and diarrhea.
12. ECOLOGICAL INFORMATION
12.1. Ecotoxicity effects
Acute toxicity
- Fishes, Pimephales promelas, LC50, 71 mg/l
- Fishes, Pimephales promelas, NOEC, 96 h, 7.4 mg/l
- Crustaceans, Daphnia pulex, EC50, 4.9 mg/l
- Crustaceans, Daphnia pulex, NOEC, 48 h, 2 mg/l
12.2. Mobility
- Air
Remarks: not applicable
- water
Remarks: considerable solubility and mobility
- Soil/sediments, landfill leachate
Remarks: non-significant adsorption
12.3. Persistence and degradability
Abiotic degradation
- Air
Result: not applicable
- Soil, Hydrolysis
- water
Result: significant hydrolysis
Degradation products: Sodium carbonate / carbonic acid/bicarbonate/carbonate / hydrogen
peroxide (bio)degradable
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Biodegradation
- Aerobic/anaerobic
Remarks: no data available
12.4. Bioaccumulative potential
- Result: Does not bioaccumulate.
12.5. Other adverse effects
- Study in progress
12.6. Possible hazards (summary)
- Toxic to aquatic organisms.
- Hazard for the aquatic environment is limited due to product properties:
- Does not bioaccumulate.
- . abiotic degradability.
- . low toxicity of degradation products.
13. DISPOSAL CONSIDERATIONS
13.1. Waste from residues / unused products
- In accordance with local and national regulations.
- Dilute with plenty of water.
- After this treatment, the product can be discharged into the sewer.
- Or
- Dispose of product at a landfill authorised for industrial waste.
13.2. Packaging treatment
- To avoid treatments, as far as possible, use dedicated containers.
- Empty containers are a source of hazard until they have been effectively cleaned. They must be
handled and stored accordingly.
- The empty and clean containers are to be reused in conformity with regulations.
- Containers that cannot be cleaned must be treated as waste.
14. TRANSPORT INFORMATION
UN-No 3378
IATA-DGR
Class 5.1
Packing group III
ICAO-Labels OXIDIZER
Proper shipping name: SODIUM CARBONATE PEROXYHYDRATE
IMDG
Class 5.1
Packing group III
IMO-Labels oxidizing agents
HI/UN No. 3378
EmS: F-A, S-Q
Proper shipping name: SODIUM CARBONATE PEROXYHYDRATE
ADG
Class 5.1
Packing group III
ADG-Labels 5.1
HI/UN No. 50/3378
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Proper shipping name: SODIUM CARBONATE PEROXYHYDRATE
Remarks:
- HAZCHEM Code: 1Y
15. REGULATORY INFORMATION
15.1. Label
- Hazardous components which must be listed on the label: Sodium carbonate peroxyhydrate
- Classified as hazardous according to criteria of NOHSC.
Symbol(s) O Oxidising
Xn Harmful
R-phrase(s) R8 Contact with combustible material may cause fire.
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
S-phrase(s) S3 Keep in a cool place.
S8 Keep container dry.
S17 Keep away from combustible material.
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
16. OTHER INFORMATION
16.1. Administrative information
- Australian version
- General revision
- Distribute new edition to clients
16.2. Text of R phrases mentioned in Section 3
- R 8: Contact with combustible material may cause fire.
- R22: Harmful if swallowed.
- R41: Risk of serious damage to eyes.
The information given corresponds to the current state of our knowledge and experience of the product,
and is not exhaustive. This applies to product which conforms to the specification, unless otherwise
stated. In this case of combinations and mixtures one must make sure that no new dangers can arise. In
any case, the user is not exempt from observing all legal, administrative and regulatory procedures
relating to the product, personal hygiene, and protection of human welfare and the environment.
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