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68130-40-5
68515-48-0
1333-86-4
66402-68-4
77-58-7
98-88-4
2530-83-8
101-68-8

File Name: 68130-40-5.asp

3M MATERIAL SAFETY DATA SHEET 3M(TM) Fast Cure Auto Glass Urethane Windshield Adhesive - High Viscosity, PN 08689,
08690, 08566 06/24/2004




Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Fast Cure Auto Glass Urethane Windshield Adhesive - High Viscosity, PN
08689, 08690, 08566
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket

ADDRESS: 3M Center
St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 06/24/2004
Supercedes Date: 11/30/2003

Document Group: 08-7522-9

Product Use:
Specific Use: Adhesive/Sealant for Windshields


SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
URETHANE POLYMER 68130-40-5 30 - 60
PLASTICIZER 68515-48-0 10 - 30
CARBON BLACK 1333-86-4 10 - 30
ALUMINUM SILICATE 66402-68-4 1 - 20
CATALYST 77-58-7 1- 5
Benzoyl Chloride 98-88-4 1- 5
3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER 2530-83-8 1- 5
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 0.1 - 1



SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
Odor, Color, Grade: Black Paste
General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause allergic


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3M MATERIAL SAFETY DATA SHEET 3M(TM) Fast Cure Auto Glass Urethane Windshield Adhesive - High Viscosity, PN 08689,
08690, 08566 06/24/2004



respiratory reaction. May cause target organ effects.

3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.


Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.

Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.


Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.


Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.


Target Organ Effects:
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.



Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.



Ingredient C.A.S. No. Class Description Regulation
CARBON BLACK 1333-86-4 Group 2B International Agency for Research on Cancer



SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.

Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.



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3M MATERIAL SAFETY DATA SHEET 3M(TM) Fast Cure Auto Glass Urethane Windshield Adhesive - High Viscosity, PN 08689,
08690, 08566 06/24/2004



If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL


5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). DO NOT USE WATER

5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).

Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.


SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Pour isocyanate decontaminant solution
(90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to
react for more than 30 minutes. Cover with absorbent material. Place in a container approved for transportation by appropriate
authorities, but do not seal the container for 48 hours to avoid pressure build-up. Dispose of collected material as soon as possible.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.



SECTION 7: HANDLING AND STORAGE

7.1 HANDLING
Avoid eye contact with vapors, mists, or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly
with soap and water. For industrial or professional use only. Keep away from heat, sparks, open flame, pilot lights and other sources
of ignition. Avoid contact with water to prevent potentially violent reaction or fire. Avoid eye contact with dust or airborne particles.

7.2 STORAGE
Store in a cool place. Keep container tightly closed.

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Fast Cure Auto Glass Urethane Windshield Adhesive - High Viscosity, PN 08689,
08690, 08566 06/24/2004




SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Do not use in a confined area or areas with little or no air movement.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Indirect Vented Goggles.

8.2.2 Skin Protection
Avoid skin contact.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Neoprene, Nitrile Rubber.

8.2.3 Respiratory Protection
Do not breathe vapors.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Fullface air-purifying respirator with organic vapor cartridges and P100 particulate prefilters. Consult the
current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.

8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
3-(TRIMETHOXYSILYL)PROPYL CMRG TWA 5 ppm
GLYCIDYL ETHER
Benzoyl Chloride ACGIH CEIL 0.5 ppm Table A4
Benzoyl Chloride AIHA TWA 1 ppm
Benzoyl Chloride CMRG TWA 1 ppm
CARBON BLACK ACGIH TWA 3.5 mg/m3 Table A4
CARBON BLACK CMRG TWA 0.5 mg/m3
CARBON BLACK OSHA TWA 3.5 mg/m3 Table Z-1
PLASTICIZER CMRG TWA 5 mg/m3
FREE ISOCYANATES 3M TWA 0.005 ppm
FREE ISOCYANATES 3M STEL 0.02 ppm
P,P'-METHYLENEBIS(PHENYL ACGIH TWA 0.005 ppm
ISOCYANATE)
P,P'-METHYLENEBIS(PHENYL OSHA CEIL 0.02 ppm Table Z-1
ISOCYANATE)


SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)



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3M MATERIAL SAFETY DATA SHEET 3M(TM) Fast Cure Auto Glass Urethane Windshield Adhesive - High Viscosity, PN 08689,
08690, 08566 06/24/2004




SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Paste
Specific Physical Form:
Black Paste
Odor, Color, Grade:
Solid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
No Data Available
Boiling point

No Data Available
Vapor Density

No Data Available
Vapor Pressure

1.24 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
No Data Available
Melting point

Nil
Solubility in Water
No Data Available
Evaporation rate
80 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds
< 10 %
Percent volatile
80 g/l [Test Method: calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents
No Data Available
Viscosity


SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.

Materials and Conditions to Avoid: Amines; Alcohols; Water; Reaction with water, alcohols, and amines is not hazardous if
container can vent to the atmosphere to prevent pressure buildup.


Hazardous Polymerization: Hazardous polymerization will not occur.


Hazardous Decomposition or By-Products
Substance Condition
Isocyanates During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion



SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.




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3M MATERIAL SAFETY DATA SHEET 3M(TM) Fast Cure Auto Glass Urethane Windshield Adhesive - High Viscosity, PN 08689,
08690, 08566 06/24/2004



SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION
Not determined.

CHEMICAL FATE INFORMATION
Not determined.


SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal
alternative, dispose of waste product in a facility permitted to accept chemical waste.

EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable regulations or authorities before disposal.


SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-9800-3228-2, 60-9800-3558-2, 60-9800-3918-8




Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.


SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.


311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes



Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Benzoyl Chloride 98-88-4 1- 5

This material contains a chemical which requires export notification under TSCA Section 12[b]:

Ingredient (Category if applicable) C.A.S. No Regulation Status
PLASTICIZER (ALKYL PHTHALATES) 68515-48-0 Toxic Substances Control Act (TSCA) 4 Test Applicable


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3M MATERIAL SAFETY DATA SHEET 3M(TM) Fast Cure Auto Glass Urethane Windshield Adhesive - High Viscosity, PN 08689,
08690, 08566 06/24/2004



Rule Chemicals



STATE REGULATIONS
Contact 3M for more information.




CHEMICAL INVENTORIES
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.

The components of this product are in compliance with the chemical notification requirements of TSCA.

The components of this product are listed on the Australian Inventory of Chemical Substances.

Contact 3M for more information.




INTERNATIONAL REGULATIONS
Contact 3M for more information.



WHMIS: Hazardous



This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.


SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 2 Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.

Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards
of the product have not changed. We encourage you to reread the MSDS and review the information.

Revision Changes:
Section 16: NFPA hazard classification heading was modified.
Section 3: Carcinogenicity heading was modified.
Section 3: Other potential health effects heading was modified.
Copyright was modified.


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3M MATERIAL SAFETY DATA SHEET 3M(TM) Fast Cure Auto Glass Urethane Windshield Adhesive - High Viscosity, PN 08689,
08690, 08566 06/24/2004



Section 8: Exposure guidelines data source legend was modified.
Section 3: Potential effects from skin contact information was modified.
Section 3: Potential effects from ingestion information was modified.
Section 15: 311/312 hazard categories heading was modified.
Section 15: International regulations information was modified.
Section 15: State regulations information was modified.
Section 15: US federal regulations information was modified.
Section 15: WHMIS regulations information was modified.
Section 10: Hazardous polymerization heading was modified.
Section 3: Carcinogenicity phrase was modified.
Section 3: Immediate other hazard(s) was modified.
Section 2: Ingredient table was modified.
Section 15: TSCA section 12[b] text was modified.
Section 3: Other health effects information was modified.
Section 16: NFPA explanation was modified.
Section 15: Inventories information was modified.
Section 15: EPCRA 313 information was modified.
Section 3: Carcinogenicity table was modified.
Section 15: EPCRA 313 text was modified.
Section 12: Ecotoxicological information heading was modified.
Section 12: Chemical fate information heading was modified.
Section 8: Exposure guidelines ingredient information was modified.
Section 16: NFPA hazard classification for special hazards was modified.
Section 16: Reason for reissue heading was modified.
Section 12: Ecotoxicological phrase was modified.
Section 12: Chemical Fate phrase was modified.
Section 2: Ingredient phrase was added.
Section 3: Immediate other hazard(s) comment was deleted.
Section 8: Exposure guideline note was deleted.
Section 3: Other health effects information (reproductive hazards) was deleted.


DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.


3M MSDSs are available at www.3M.com




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