W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Zonolite庐 Masonry Insulation
MSDS ID Number: Z-01630 MSDS Date: 05/17/2004
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Zonolite 庐 Masonry Insulation
Product Name:
Z-01630
MSDS Number:
Z-01537
Cancelled MSDS Number:
5/17/2004
MSDS Date:
Expanded Vermiculite (Enoree, South Carolina Source):
Chemical Family Name:
Magnesium-Aluminosilicate Mineral.
Aggregate Insulating Material for Masonry Applications
Product Use:
(Mg, Ca, K, Fe11)3 (Si, A1, Fe111)4O310 (OH)2 .H2O
Chemical Formula:
Mixture NA
CAS # (Chemical Abstracts Service
Number):
Manufactured by:
W.R.Grace & Co.-Conn. Grace Canada, Inc.
62 Whittemore Avenue 294 Clements Road West
Cambridge, MA 02140 Ajax, Ontario L1S 3C6
In Case of Emergency Call:
In USA: (617) 876-1400 In Canada: (905) 683-8561
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS# Percent (max)
Quartz 014808-60-7 1-10
Vermiculite 001318-00-9 50-100
This product has been treated with a water based emulsion. AVOID WATER REACTIVE CHEMICALS.
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview:
Caution!
Causes eye irritation.
Causes respiratory tract irritation.
Avoid contact with eyes.
HMIS Rating:
Health: 1
Flammability: 0
Reactivity: 0
Personal Protective Equipment: E
Potential Health Effects:
Inhalation:
Causes respiratory tract irritation.
Effects include: Coughing, shortness of breath, wheezing and reduced pulmonary function from
pneumoconiosis (dusty lungs).
Eye Contact:
Eye contact causes physical irritation.
Prolonged eye contact can result in redness and itching.
Skin Contact:
Skin contact is not expected to cause any harmful effects.
Skin Absorption:
Not expected to be harmful if absorbed through the skin.
Ingestion:
Ingestion not expected to be harmful.
Effects include: No other effects expected unless listed below.
www.graceconstruction.com Page 1 of 5 06/29/04
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Zonolite庐 Masonry Insulation
MSDS ID Number: Z-01630 MSDS Date: 05/17/2004
SECTION 4 - FIRST AID MEASURES:
Skin Contact:
Wash with soap and water.
If discomfort or irritation persists, consult a physician.
Remove contaminated clothing and wash before reuse.
Eye Contact:
Flush eyes with water for at least 15 minutes while holding eyelids open.
If discomfort or irritation persists, consult a physician.
Ingestion:
Adverse health effects are not expected if swallowed.
Inhalation:
If symptoms develop, get fresh air. If symptoms persist, consult a physician.
If breathing has stopped, give artificial respiration then oxygen if needed.
SECTION 5 - FIRE AND EXPLOSION HAZARD DATA
Flash Point: Not Applicable
Flash Point Method: Not Applicable
Lower Explosion Limit: Not Available
Upper Explosion Limit: Not Available
Auto-Ignition Temperature: Not Available
NFPA Rating:
Health: 1
Flammability: 0
Reactivity: 0
Extinguishing Media: Not Applicable. Product will not burn.
Special Fire Fighting Procedures:
None
Unusual Fire and Explosion Hazards:
None.
SECTION 6 - ACCIDENTAL RELEASE MEASURES:
Spills/Leaks:
Carefully shovel or sweep up spilled material and place in suitable container for recycle or disposal.
Dampen with water spray or use other methods to clean spill which avoid creating dust. Discard empty
packaging promptly. Avoid excessive handling of empty packaging, which may result in unnecessary
release of airborne particulates.
Use proper personal protective equipment.
SECTION 7 - HANDLING AND STORAGE
Precautionary Measures:
Avoid contact with eyes, skin and clothing.
Avoid creating and inhaling airborne dust or particulates.
Use only with adequate ventilation.
Wash clothing before reuse.
Provide respiratory protection if needed.
FOR PROFESSIONAL USE ONLY. KEEP OUT OF CHILDREN'S REACH.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
EXPOSURE GUIDELINES (US)
Ingredient ACGIH TLV OSHA PEL Other
TWA STEL Ceiling TWA STEL Ceiling
Quartz 0.05 mg/m3 TWA - - respirable dust: - - -
(respirable 0.1 mg/m3
fraction) TWA
Vermiculite - - - - - - -
www.graceconstruction.com Page 2 of 5 06/29/04
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Zonolite庐 Masonry Insulation
MSDS ID Number: Z-01630 MSDS Date: 05/17/2004
In addition to the exposure limits referenced above, the following non-specific limits for dust apply to this
product; OSHA, 15 mg/m3-TWA or Total Dust and 5 mg/m3-TWA as Respirable Dust, ACGIH, 10 mg/m3-TWA
as Total Dust and 3 mg/m3-TWA as Respirable Dust.
EXPOSURE GUIDELINES (CANADA)
Employers should consult local Provincial regulatory limits for exposure guidelines which may vary locally.
Engineering Controls: General ventilation may be desirable and should be used where appropriate.
Personal Protective Equipment:
Respiratory Protection: Respiratory protection may be desirable if dust is created in handling and is
required at or above the Permissible Exposure Limits (PELs) specified.
Skin Protection: Gloves are recommended.
Eye Protection: Safety glasses or goggles should be worn.
Work/Hygienic Practices: Use good personal hygiene practices.
Quartz (Crystalline silica) is a naturally-occurring mineral that is commonly contained in materials that
are mined from the earth's surface such as sand, limestone, clay and gypsum (Calcium sulfate). Total
quartz is a value usually representing the combined fractions of large, nonrespirable sized particles
and of respirable sized particles (less than ten microns in aerodynamic diameter). It is only the
respirable fraction of total quartz that is recognized as hazardous by professionals in the field of
Occupational Health and by most regulatory agencies. This product contains compounds subject to
exposure guidelines and/or identified as carcinogens. (See Sections 8 and 11
Grace has not been able to detect respirable sized quartz in vermiculite above the current Permissible
Exposure Limit (PEL) during industrial hygiene sampling of workers at Grace production facilities. We
believe that the highest potential for exposure exists at our production facilities due to the high volume
of product produced and handled. In addition a wet sieving analysis combined with x-ray
diffractometry has been conducted on vermiculite. Results indicate that respirable quartz is not
present above the 0.1% by weight limit established by the Occupational Safety and Health
Administration (OSHA) for carcinogens. OSHA stats that if the hazardous substance is contained in
the product below 0.1% by weight and exposures do no exceed permissible exposure limits, then the
hazards do not apply.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Solid
Physical State:
Brown or Grey free flowing aggregate
Appearance/Odor:
Not Determined
Odor Threshold: (ppm)
Not Applicable
pH:
Unknown
Vapor Pressure: (Mm Hg)
Unknown
Vapor Density: (Air = 1)
Negligible
Solubility In Water:
Not Applicable
Specific Gravity: (Water = 1)
Not Applicable
Evaporation Rate: (Butyl Acetate = 1)
Not Applicable
Boiling Point:
Not Applicable
Viscosity:
4 鈥? 10 PCF
Bulk Density: (Pounds/Cubic Foot)(Pcf)
Not Available
% Volatiles (gr/L): (70掳F) (21掳C)
SECTION 10 - STABILITY AND REACTIVITY
Stable
Chemical Stability:
Vermiculite is often used as a chemical absorbent. When contact with
Conditions To Avoid:
highly reactive chemicals or chemicals that can off-gas at temperatures
above room temperature (such as Hydrogen peroxide solutions) care
should be taken to neutralize or make these materials inert prior to
absorption. If possible consult the MSDS or supplier of the material
being absorbed.
Will not polymerize.
Hazardous
Polymerization:
Hazardous Decomposition None known for this product.
Products:
www.graceconstruction.com Page 3 of 5 06/29/04
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Zonolite庐 Masonry Insulation
MSDS ID Number: Z-01630 MSDS Date: 05/17/2004
SECTION 11 - TOXICOLOGICAL INFORMATION
Ingredient(No data unless listed.) CAS Number LD50 and LC50
Carcinogenicity:
Ingredient IARC IARC IARC NTP NTP OSHA
Group 1 Group 2A Group 2B Known Suspect
Quartz Yes No No Yes Yes Yes
Vermiculite No No No No No No
Not applicable.
Mutagenicity:
Not applicable.
Teratogenicity:
Not applicable.
Reproductive Toxicity:
SECTION 12 - ECOLOGICAL INFORMATION
No data available for product.
Environmental Fate:
No data available for product.
Ecotoxicity:
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal Procedures:
Consult all regulations (federal, state, provincial, local) or a qualified waste disposal firm when
characterizing waste for disposal. According to EPA (40 CFR 搂 261), waste of this product is not
defined as hazardous. Dispose of waste in accordance with all applicable regulations.
According to US EPA (40 CFR 搂 261.3) waste of this product is not defined as hazardous.
SECTION 14 - TRANSPORTATION INFORMATION
Not Applicable
Proper Shipping Name:
Not Applicable
UN/NA Number:
Nonhazardous
Domestic Hazard Class:
Vermiculite, other thin Vermiculite
Surface Freight Classification:
Not Applicable
Label/Placard Required:
SECTION 15 - REGULATORY INFORMATION
REGULATORY CHEMICAL LISTS:
CERCLA (Comprehensive Response Compensation and Liability Act):
(None present unless listed below)
Chemical Name CAS # Wt % CERCLA RQ
SARA Title III (Superfund Amendments and Reauthorization Act)
SARA Section 312/Tier I & II Hazard Categories:
Health Immediate (acute) No
Health Delayed (chronic) No
Flammable No
Reactive No
Pressure No
302 Reportable Ingredients (Identification Threshold 1%.):
Chemical Name CAS # Wt % SARA 302 TPQ
313 Reportable Ingredients (Chemicals present below reporting threshold are exempt):
Chemical Name CAS # Wt %
National Volatile Organic Compound Emission Standards For Architectural Coatings:
Not Applicable
Volatile Organic Content: (gr/L)
D-2B
WHMIS Classification(s):
www.graceconstruction.com Page 4 of 5 06/29/04
W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Zonolite庐 Masonry Insulation
MSDS ID Number: Z-01630 MSDS Date: 05/17/2004
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR). This MSDS contains all the information required by the CPR.
State Regulatory Information:
California Proposition 65: WARNING! This product contains substances known to the state of California to
cause cancer, birth defects or other reproductive harm.
Massachusetts Hazardous Substance List(Identification threshold 0.001%(1ppm)):
Chemical Name CAS # Wt %
Quartz 014808-60-7 1
New Jersey Hazardous Substance List(Identification threshold (0.1%)):
Chemical Name CAS # Wt %
Pennsylvania Hazardous Substance List(Identification threshold 0.01%):
Chemical Name CAS # Wt %
CHEMICAL INVENTORY STATUS:
All chemicals in this product are listed or exempt from listing in the following countries:
US CANADA EUROPE AUSTRALIA JAPAN KOREA PHILIPPINES
TSCA DSL NDSL EINECS/ELINCS AICS ENCS ECL PICCS
Yes Yes Yes Yes Yes Yes Yes Yes
SECTION 16 - OTHER INFORMATION
Non-Hazardous Ingredient Disclosure:
Chemical Name CAS Number
EH&S Department
Prepared by:
EH&S Department
Approved by:
05/17/2004
Approved Date:
Disclaimer:
"The data included herein are presented in accordance with various environment, health and safety regulations.
It is the responsibility of a recipient of the data to remain currently informed on chemical hazard information, to
design and update its own program and to comply with all national, federal, state and local laws and regulations
applicable to safety, occupational health, right-to-know and environmental protection."
www.graceconstruction.com Page 5 of 5 06/29/04
|