Product Name: UV Ink Black
MSDS No.032-33U01KC
First issue: 2007/10/15
Safety Data Sheet Revised: 2008/02/13
Page 1 of 8
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
1.1. Identification of the substance or preparation
Product Name : UV Ink Black
Product Code : SPC-0371K-2
1.2. Use of the substance/preparation
General Use : For ink jet
Product Description : UV curable ink
1.3. Company/undertaking identification
MANUFACTURER
Company Name : Mimaki Engineering Co., Ltd
Address : 2182-3 Otsu, Shigeno, Tomi-shi, Nagano 389-0512 Japan
Telephone No. : +81-268-64-2413
Charge post : Inks and Media Division
Person in charge : Isao Tabayashi
E-mail address : tabayashi@mimaki.co.jp
IMPORTER/DISTRIBUTOR ESTABLISHED IN EU
Company Name : MIMAKI EUROPE B.V.
Address : Joan Muyskenweg 42-44, 1099CK Amsterdam
Telephone No. : +31-20-4627-640
Person in charge : Sakae Sagane
1.4. Emergency telephone
EMERGENCY : Mimaki Engineering Co., Ltd +81-268-64-2413
TELEPHONE : National Vaccine Information Center (NVIC)
NUMBER +31-30-274888
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW :
Xi Irritant
N Dangerous for the environment
Product Name: UV Ink Black
MSDS No.032-33U01KC
First issue: 2007/10/15
Safety Data Sheet Revised: 2008/02/13
Page 2 of 8
POTENTIAL HEALTH EFFECTS
Inhalation : R37 Irritating to respiratory system.
Eye : R36 Irritating to eyes.
Skin : R38 Irritating to skin.
Cancer-causing : Carbon Black; IARC Group 2B, is possibly carcinogenic to humans.
POTENTIAL ENVIROMENTAL EFFECTS
Aquatic organism : R51 Toxic to aquatic organism.
R53 May cause long-time adverse effects in the aquatic environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
EINECS Symbol Risk Chemical
No Chemical Name Wt% CAS No.
No. letters Phrase Formula
R36/37/38 Trade
1 Acrylates 40-50 Registered Registered Xi, N
-51/53 Secret
R36/37/38
2 Iso-octyl acrylate 10-20 29590-42-9 249-707-8 Xi, N C11H20O2
-50/53
not not Unspecifie
3 Carbon black <3 1333-86-4 215-609-9
classified classified d
2-Benzyl-2-dimethyla
C23H30
4 mino-4-morpholinobu <5 119313-12-1 404-360-3 N R50/53
N2O2
tyrophenone
2-Hydroxy-2-methylp R22,
5 <3 7473-98-5 231-272-0 Xn, N C10H12O2
ropiophenone 50/53
2,2-Dimethoxy-1,2-di
6 <5 24650-42-8 246-386-6 N R50/53 C16H16O3
phenylethan-1-one
*The wording of the symbol(s) and risk phrase(s) is specified in 16.OTHER INFORMATION.
No Chemical Name Index No. (91/155 EEC)
1 Acrylates 607-133-00-9
2 Iso-octyl acrylate 607-244-00-2
4 2-Benzyl-2-dimethylamino-4-morpholinobutyrophenone 606-047-00-9
Product Name: UV Ink Black
MSDS No.032-33U01KC
First issue: 2007/10/15
Safety Data Sheet Revised: 2008/02/13
Page 3 of 8
4. FIRST AID MEASURES
INHALATION : Remove the victim from the contamination immediately to flesh air.
Keep the victim warm and quiet and arrange for transport to the
nearest medical facility for examination and treatment by a
physician as soon as possible.
EYE : Gently rinse the affected eyes with clean water for at least 15minitus.
Remove contact lenses if easily possible.
And refer for medical attention.
SKIN : Remove all contaminated clothing, shoes and socks from the affected
areas as quickly as possible.
Wash the affected area under running water using a mild soap.
If irritation persists, arrange for transport to the nearest medical
facility for examination and treatment by a physician as soon as
possible.
INGESTION : Never give anything by mouth to someone who is unconscious or
convulsing.
If the victim is responsive, give him one or two glasses of water.
And refer for medical attention.
5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
: Dry chemical powder, form and carbon dioxide, water spray.
FIRE FIGHTING INSTRUCTIONS
: Fight fire from maximum distance.
Shut off fuel to fire if possible to do so without hazard.
Wear full fire-fighting turn-out gear (full bunker gear) and
respiratory protection (self-contained breathing apparatus).
6. ACCIDENTAL RELEASE MEASURES
Shut off all sources of ignition; No smoking or flames in area. Wear proper protective
equipment. Absorb spill with inert material (e.g., dry sand or earth), then place in closed
containers using non-sparking tools. Prevent spills from entering sewers, watercourses or low
areas. Do not wash away into shower or waterway.
Product Name: UV Ink Black
MSDS No.032-33U01KC
First issue: 2007/10/15
Safety Data Sheet Revised: 2008/02/13
Page 4 of 8
7. HANDLING AND STORAGE
HANDLING : Use only in the well-ventilated areas.
Make available in the work area emergency shower and eyes wash.
Avoid contact with skin or eyes.
Only use tools and equipment resistant to organic solvents.
Do not flush to sewer or waterways.
STORAGE : Store product in tightly closed original containers in dry and cool
place protected from sunlight fluorescent light, preferably at below 25
degree C on impermeable ground.
Keep away from sources of ignition.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Exposure limit values
No Chemical Name WEL Short term value WEL Long term value
1 Carbon black 7mg/m3 3.5mg/m3
8.2. Exposure controls
Occupational exposure controls
Engineering : Do not use in areas without adequate ventilation.
Controls
Personal Protection : Follow the general guidelines of good industrial hygiene.
Avoid any direct contact with the product.
Never breathe product vapor.
Respiratory : Chemical cartridge respirator with an organic vapor cartridge.
Protection
Hand Protection : Impermeable gloves.
Eye Protection : Chemical safety glasses.
Skin Protection : Long sleeve clothing, resistant to solvents.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. General information
Appearance - Physical state : liquid
- Color : Black
Odor : Characteristic
Product Name: UV Ink Black
MSDS No.032-33U01KC
First issue: 2007/10/15
Safety Data Sheet Revised: 2008/02/13
Page 5 of 8
9.2. Important health, safety and environmental information
pH : Not available
Boiling Point / Boiling Range : Not available
Flash Point : 131 degree C (Cleveland open cup)
Flammability(solid, gas) : Not available
Explosive Properties : Not available
Vapour Pressure : Not available
Density : 1.06
Solubility : Soluble (Organic solvent)
Water solubility : Insoluble
: 20 mPa s (25 degree C)
Viscosity
9.3. Other information
Melting Point / Melting Range : Not applicable
Auto-Ignition Temperature : Not available
Surface Tension : 31.5 mN/m (25 degree C)
10. STABILITY AND REACTIVITY
CONDITONS : Heat, sunlight (may result in polymerization)
TO AVOID
STABILITY : Stable under the usual handling conditions.
MATERIALS : Oxidizing agents, strong bases, and transition metals
TO AVOID (possible polymerization)
11. TOXICOLOGICAL INFORMATION
The product may cause a moderate irritation to the eyes, followed by burning sensation,
tearing, redness. Skin contact may result in delayed irritation and blistering.
No significant symptoms of any adverse health hazard are expected to occur by ingestion of
the product. Due to the low vapor pressure, inhalation is no primary route of entry.
Irritation of the respiratory tract may be caused by inhalation of product vapors or mists in
high concentration.
Product Name: UV Ink Black
MSDS No.032-33U01KC
First issue: 2007/10/15
Safety Data Sheet Revised: 2008/02/13
Page 6 of 8
12. ECOLOGICAL INFORMATION
REMARK : Toxic for fish
Water hazard class 2 (German Regulation)
(Self-assessment): hazardous for water.
Do not allow product to reach ground water, water course or sewage
system.
Danger to drinking water if even small quantities leak into the
ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organism.
13. DISPOSAL CONSIDERATIONS
Scrap materials may be disposed by licensed contractor or burn in an approved incinerator.
Comply with all EU, national and local regulations.
Do not dump this product into sewers, on the ground or into any body of water.
Follow national and local regulations.
14. TRANSPORT INFORMATIONS
Perform prevention of collapse of cargo surely.
Follow all regulation in your country.
LAND TRANSPORT
ADR, RID Class : 9 Miscellaneous dangerous substances and
articles.
Danger code (Kemler) : 90
:
Packing Group(PG)
UN Number : 3082
Hazard label :9
SEA TRANSPORT
IMDG Class : 3082
Marine Pollutant : No
Product Name: UV Ink Black
MSDS No.032-33U01KC
First issue: 2007/10/15
Safety Data Sheet Revised: 2008/02/13
Page 7 of 8
AIR TRANSPORT
ICAO/IATA Class :9
:
Packing Group(PG)
UN Number : 3082
15. REGULATORY INFORMATION
This product is classified as follows and labeled accordingly.
Please refer to any other EU, national and local measures.
Symbol
Xi Irritant
N Dangerous for the environment
Risk Phrase 36/37/38 Irritating to eyes, respiratory system and skin.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Safety Advise 23 Do not breathe gas/fumes/vapor/spray (appropriate wording to be
specified by the manufacturer).
24/25 Avoid contact with skin and eyes.
26 In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
29/56 Do not empty into drains, dispose of the material and its
container at hazardous or special waste collection point.
37 Wear suitable gloves.
Waterhazard class 2 (Self-assessment): hazardous for water.
Product Name: UV Ink Black
MSDS No.032-33U01KC
First issue: 2007/10/15
Safety Data Sheet Revised: 2008/02/13
Page 8 of 8
16. OTHER INFORMATION
From clause 3
Symbol letters : Xi Irritant
N Dangerous for the environment
Risk phrase : 22 Harmful if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
50/53 Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and dose not relates to use in
combination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon this
information.
Revision history
Version Date Content
1.0 2007/10/15 First issue
2.0 2007/12/18 No.14, 15 Addition of symbols
3.0 2008/02/13 No.1 Addition of the emergency telephone.
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