DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 1 of 14
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
DEODORANT AIR FRESHENER
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A DANGEROUS SUBSTANCE ACCORDING TO DIRECTIVE
67/548/EEC, POINT 4; AND HAZARDOUS ACCORDING TO OSHA 29 CFR
1910.1200 (USA).
SUPPLIER
Company: Double Class (M) Sdn Bhd
Address:
No.14, Jalan 4
Pandan Inidah
Kuala Lumpur, 55300
MYS
Telephone: +60 3 4280 9898
CONTACT
National Poisons Center of Malaysia
1800 888 099 (office hours)
MOLECULAR MASS
Molecular mass: Not Applicable
PRODUCT USE
Application is by spray atomisation from a hand held aerosol pack Application is by spray
atomisation from a hand held aerosol pack Deodorant.
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN INT HAZ %
ethanol 64-17-5 F+,Xi 36-47
EC NO: 200-578-6 R CODES: R11,R36
2-methyl-1,3-propanediol 2163-42-0 None 1-5
perfume 2-12
hydrocarbon propellant 68476-85-7. None 50-65
EC NO: 270-704-2 R CODES: R3,R12,R44
Section 3 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Gas.
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 2 of 14
Section 3 - PHYSICAL AND CHEMICAL PROPERTIES ...
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (癈): Not Available
Melting Range (癈): Not Available Specific Gravity (water=1): <1
Solubility in water (g/L): Miscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (癈): -81 (propellant)
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (癈): Not Available Decomposition Temp (癈): Not Available
State: COMPRESSED GAS
APPEARANCE
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
hydrocarbon propellant.
Flammable liquid with a fragrant odour; mixes with water
Section 4 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
RISK
Irritating to eyes.
Extremely flammable.
Risk of explosion if heated under confinement.
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Although ingestion is not thought to produce harmful effects (as classified
under EC Directives), the material may still be damaging to the health of the
individual, following ingestion, especially where pre-existing organ (e.g liver,
kidney) damage is evident. Present definitions of harmful or toxic substances
are generally based on doses producing mortality rather than those producing
morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce
nausea and vomiting. In an occupational setting however, ingestion of
insignificant quantities is not thought to be cause for concern.
EYE
Evidence exists, or practical experience predicts, that the material may cause
eye irritation in a substantial number of individuals and/or may produce
significant ocular lesions which are present twenty-four hours or more after
instillation into the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by
temporary redness (similar to windburn) of the conjunctiva (conjunctivitis);
temporary impairment of vision and/or other transient eye damage/ulceration may
occur.
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 3 of 14
Section 4 - HAZARDS IDENTIFICATION ...
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable gloves be used in an occupational setting.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Principal route of occupational exposure to the gas is by inhalation. Substance
accumulation, in the human body, may occur and may cause some concern following repeated
or long-term occupational exposure. Prolonged exposure to ethanol may cause damage to the
liver and cause scarring. It may also worsen damage caused by other agents. Large amounts
of ethanol taken in pregnancy may result in "foetal alcohol syndrome", characterised by
delay in mental and physical development, learning difficulties, behavioural problems and
small head size. A small number of people develop allergic reactions to ethanol, which
include eye infections, skin swelling, shortness of breath, and itchy rashes with
blisters. Constant or exposure over long periods to mixed hydrocarbons may produce stupor
with dizziness, weakness and visual disturbance, weight loss and anaemia, and reduced
liver and kidney function. Skin exposure may result in drying and cracking and redness of
the skin. Chronic exposure to lighter hydrocarbons can cause nerve damage, peripheral
neuropathy, bone marrow dysfunction and psychiatric disorders as well as damage the liver
and kidneys.
Section 5 - FIRST AID MEASURES
SWALLOWED
Not considered a normal route of entry.
If spontaneous vomiting appears imminent or occurs, hold patient's head down,
lower than their hips to help avoid possible aspiration of vomitus.
?If swallowed do NOT induce vomiting.
?If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
?Observe the patient carefully.
?Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
?Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
?Seek medical advice.
Avoid giving milk or oils.
Avoid giving alcohol.
EYE
If aerosols come in contact with the eyes:
?Immediately hold the eyelids apart and flush the eye continuously for at least
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 4 of 14
Section 5 - FIRST AID MEASURES ...
15 minutes with fresh running water.
?Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
?Transport to hospital or doctor without delay.
?Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If solids or aerosol mists are deposited upon the skin:
?Flush skin and hair with running water (and soap if available).
?Remove any adhering solids with industrial skin cleansing cream.
?DO NOT use solvents.
?Seek medical attention in the event of irritation.
INHALED
If aerosols, fumes or combustion products are inhaled:
?Remove to fresh air.
?Lay patient down. Keep warm and rested.
?Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
?If breathing is shallow or has stopped, ensure clear airway and apply
resuscitation, preferably with a demand valve resuscitator, bag-valve mask
device, or pocket mask as trained. Perform CPR if necessary.
?Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
For acute or short term repeated exposures to ethanol:
?Acute ingestion in non-tolerant patients usually responds to supportive care
with special attention to prevention of aspiration, replacement of fluid and
correction of nutritional deficiencies (magnesium, thiamine pyrodoxine, Vitamins
C K)
?Give 50% dextrose (50-100 ml) IV to obtunded patients following blood draw for
glucose determination.
?Comatose patients should be treated with initial attention to airway,
breathing, circulation and drugs of immediate importance (glucose, thiamine)
?Decontamination is probably unnecessary more than 1 hour after a single
observed ingestion. Cathartics and charcoal may be given but are probably not
effective in single ingestions.
?Fructose administration is contra-indicated due to side effects.
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
?Primary threat to life, from pure petroleum distillate ingestion and/or
inhalation, is respiratory failure.
?Patients should be quickly evaluated for signs of respiratory distress (e.g.
cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen.
Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm
Hg) should be intubated.
?Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported;
intravenous lines and cardiac monitors should be established in obviously
symptomatic patients. The lungs excrete inhaled solvents, so that
hyperventilation improves clearance.
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 5 of 14
Section 5 - FIRST AID MEASURES ...
?A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
?Epinephrine (adrenalin) is not recommended for treatment of bronchospasm
because of potential myocardial sensitisation to catecholamines. Inhaled
cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred
agents, with aminophylline a second choice.
?Lavage is indicated in patients who require decontamination; ensure use of
cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical
Toxicology]
Section 6 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
SMALL FIRE:
?Water spray, dry chemical or CO2
LARGE FIRE:
?Water spray or fog.
FIRE FIGHTING
?Alert Fire Brigade and tell them location and nature of hazard.
?May be violently or explosively reactive.
?Wear breathing apparatus plus protective gloves.
?Prevent, by any means available, spillage from entering drains or water
course.
?If safe, switch off electrical equipment until vapour fire hazard removed.
?Use water delivered as a fine spray to control fire and cool adjacent area.
?DO NOT approach containers suspected to be hot.
?Cool fire exposed containers with water spray from a protected location.
?If safe to do so, remove containers from path of fire.
?Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 100 metres in all directions.
FIRE/EXPLOSION HAZARD
?Liquid and vapour are flammable.
?Moderate fire hazard when exposed to heat or flame.
?Vapour forms an explosive mixture with air.
?Moderate explosion hazard when exposed to heat or flame.
?Vapour may travel a considerable distance to source of ignition.
?Heating may cause expansion or decomposition leading to violent rupture of
containers.
?Aerosol cans may explode on exposure to naked flame.
?Rupturing containers may rocket and scatter burning materials.
?Hazards may not be restricted to pressure effects.
?May emit acrid, poisonous or corrosive fumes.
?On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include
carbon dioxide (CO2)
other pyrolysis products typical of burning organic material
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 6 of 14
Section 6 - FIRE FIGHTING MEASURES ...
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result
Section 7 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
?Clean up all spills immediately.
?Avoid breathing vapours and contact with skin and eyes.
?Wear protective clothing, impervious gloves and safety glasses.
?Shut off all possible sources of ignition and increase ventilation.
?Wipe up.
?If safe, damaged cans should be placed in a container outdoors, away from all
ignition sources, until pressure has dissipated.
?Undamaged cans should be gathered and stowed safely.
MAJOR SPILLS
?Clear area of personnel and move upwind.
?Alert Fire Brigade and tell them location and nature of hazard.
?May be violently or explosively reactive.
?Wear breathing apparatus plus protective gloves.
?Prevent, by any means available, spillage from entering drains or water
courses
?No smoking, naked lights or ignition sources.
?Increase ventilation.
?Stop leak if safe to do so.
?Water spray or fog may be used to disperse / absorb vapour.
?Absorb or cover spill with sand, earth, inert materials or vermiculite.
?If safe, damaged cans should be placed in a container outdoors, away from
ignition sources, until pressure has dissipated.
?Undamaged cans should be gathered and stowed safely.
?Collect residues and seal in labelled drums for disposal.
PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
direction distance
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 7 of 14
Section 7 - ACCIDENTAL RELEASE MEASURES ...
From IERG (Canada/Australia)
Isolation Distance -
Downwind Protection Distance 8 metres
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk
of harmful exposure. This zone assumes that random changes in wind direction
confines the vapour plume to an area within 30 degrees on either side of the
predominant wind direction, resulting in a crosswind protective action distance
equal to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with
those closest to the spill and working away from the site in the downwind
direction. Within the protective action zone a level of vapour concentration
may exist resulting in nearly all unprotected persons becoming incapacitated
and unable to take protective action and/or incurring serious or irreversible
health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the
incident, within which a high probability of localised wind reversal may
expose nearly all persons without appropriate protection to life-threatening
concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less,
such as a drum (jerrican or box with inner containers). Larger packages leaking
less than 200 litres and compressed gas leaking from a small cylinder are also
considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of
greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne"
compressed gas cylinder.
5 Guide 126 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
Section 8 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
?Avoid all personal contact, including inhalation.
?Wear protective clothing when risk of exposure occurs.
?Use in a well-ventilated area.
?Prevent concentration in hollows and sumps.
?DO NOT enter confined spaces until atmosphere has been checked.
?Avoid smoking, naked lights or ignition sources.
?Avoid contact with incompatible materials.
?When handling, DO NOT eat, drink or smoke.
?DO NOT incinerate or puncture aerosol cans.
?DO NOT spray directly on humans, exposed food or food utensils.
?Avoid physical damage to containers.
?Always wash hands with soap and water after handling.
?Work clothes should be laundered separately.
?Use good occupational work practice.
?Observe manufacturer's storing and handling recommendations.
?Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 8 of 14
Section 8 - HANDLING AND STORAGE ...
SUITABLE CONTAINER
?Aerosol dispenser.
?Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
Incompatible with aluminium. DO NOT heat above 49 deg. C. in aluminium
equipment.
Avoid reaction with oxidising agents
STORAGE REQUIREMENTS
Store in an upright position.
Outside or detached storage is preferred.
Store below 38 deg. C.
Keep dry to avoid corrosion of cans. Corrosion may result in container
perforation and internal pressure may eject contents of can
?Store in original containers in approved flammable liquid storage area.
?DO NOT store in pits, depressions, basements or areas where vapours may be
trapped.
?No smoking, naked lights, heat or ignition sources.
?Keep containers securely sealed. Contents under pressure.
?Store away from incompatible materials.
?Store in a cool, dry, well ventilated area.
?Avoid storage at temperatures higher than 40 deg C.
?Store in an upright position.
?Protect containers against physical damage.
?Check regularly for spills and leaks.
?Observe manufacturer's storing and handling recommendations.
Section 9 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
ODOUR SAFETY FACTOR (OSF)
OSF=0.16 (hydrocarbon propellant)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 9 of 14
Section 9 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
activities
B 26-550 As "A" for 50-90% of
persons being distracted
C 1-26 As "A" for less than 50%
of persons being
distracted
D 0.18-1 10-50% of persons aware
of being tested perceive
by smell that the
Exposure Standard is
being reached
E <0.18 As "D" for less than 10%
of persons aware of being
tested
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m?: 1828.8834 mg/m?br>
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m?Mixture Conc: (%)
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m? (%)
hydrocarbon propellant 638.96 1150.1226 61.0
ethanol 361.04 678.7609 36.0
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
At the "Composite Exposure Standard for Mixture" (TWA) (mg/m?: 97 mg/m?br>
REPRODUCTIVE HEALTH GUIDELINES
Established occupational exposure limits frequently do not take into
consideration reproductive end points that are clearly below the thresholds for
other toxic effects. Occupational reproductive guidelines (ORGs) have been
suggested as an additional standard. These have been established after a
literature search for the reproductive no-observed-adverse effect-level (NOAEL)
and the lowest-observed-adverse-effect-level (LOAEL). In addition the US EPA's
procedures for risk assessment for hazard identification and dose-response
assessment as applied by NIOSH were used in the creation of such limits.
TLV
Ingredient ORG UF Endpoint CR Adeq
ethanol 1880 mg/m? NA NA NA Yes
These exposure guidelines have been derived from a screening level of risk
assessment and should not be construed as unequivocally safe limits. ORGS
represent an 8-hour time-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 10 of 14
Section 9 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996)
INGREDIENT DATA
ETHANOL:
TLV TWA: 1000 ppm A4 [ACGIH]
TLV TWA: 1000 ppm, 1880 mg/m? A4
NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as
causing Cancer in humans
ES TWA: 1000 ppm, 1880 mg/m?br>
OES TWA: 1000 ppm, 1920 mg/m?br>
MAK value: 500 ppm, 960 mg/m?br>
MAK Category II Peak Limitation: For substances with systemic effects and with a
half-life in humans of less than two hours.
Allows excursions of 2 times the MAK value, for 30 minutes (on average), four
times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
Odour Threshold Value: 49-716 ppm (detection), 101 ppm (recognition)
IDLH Level: 3300 ppm (lower explosive limit)
Eye and respiratory tract irritation do not appear to occur at exposure
levels of less than 5000 ppm and the TLV-TWA is thought to provide an
adequate margin of safety against such effects.
Experiments in man show that inhalation of 1000 ppm caused slight symptoms
of poisoning and 5000 ppm caused strong stupor and morbid sleepiness.
Subjects exposed to 5000 ppm to 10000 ppm experienced smarting of the
eyes and nose and coughing. Symptoms disappeared within minutes.
Inhalation also causes local irritating effects to the eyes and
upper respiratory tract, headaches, sensation of heat intraocular
tension, stupor, fatigue and a need to sleep.
At 15000 ppm there was continuous lachrymation and coughing.
2-METHYL-1,3-PROPANEDIOL:
No exposure limits set by NOHSC or ACGIH
HYDROCARBON PROPELLANT:
hydrocarbon propellant, as liquified petroleum gas
TLV TWA: 1000 ppm, 1800 mg/m?br>
ES TWA: 1000 ppm, 1800 mg/m?br>
OES TWA: 1000 ppm, 1750 mg/m? STEL: 1250 ppm, 2180 mg/m?br>
PERSONAL PROTECTION
EYE
?Safety glasses with side shields.
?Chemical goggles.
?Contact lenses pose a special hazard; soft lenses may absorb irritants and all
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 11 of 14
Section 9 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
lenses concentrate them. DO NOT wear contact lenses.
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE:
For potentially moderate exposures:
Wear general protective gloves, eg. light weight rubber gloves.
For potentially heavy exposures:
Wear chemical protective gloves, eg. PVC. and safety footwear.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
?Overalls.
?Skin cleansing cream.
?Eyewash unit.
?Do not spray on hot surfaces.
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Substance
________________________________________
ethanol
BUTYL A
NITRILE+PVC A
PE/EVAL/PE A
NEOPRENE A
NITRILE A
PVC B
NATURAL+NEOPRENE C
NATURAL RUBBER C
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove,
a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis,
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
of gloves which might otherwise be unsuitable following long-term or frequent
use. A qualified practitioner should be consulted.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor Half-Face Respirator Full-Face Respirator
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ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 12 of 14
Section 9 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
5 x ES Air-line* A-2
- A-PAPR-2
10 x ES - A-3
10+ x ES - Air-line**
* - Continuous Flow; ** - Continuous-flow or positive pressure demand
^ - Full-face
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain
adequate protection.
Provide adequate ventilation in warehouse or closed storage areas.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
?Elevated temperatures.
?Presence of open flame.
?Product is considered stable.
?Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
Deodorant Air Freshener
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
ETHANOL:
TOXICITY IRRITATION
Oral (rat) LD50: 7060 mg/kg Skin (rabbit):20 mg/24hr-moderate
Oral (human) LDLo: 1400 mg/kg Skin (rabbit):400 mg (open)-mild
Oral (man) TDLo: 50 mg/kg Eye (rabbit):100mg/24hr-moderate
Oral (man) TDLo: 1.40 mg/kg Eye (rabbit): 500 mg SEVERE
Oral (woman) TDLo: 256 mg/kg/12 wks
Inhalation (rat) LC50: 20,000 ppm/10h
2-METHYL-1,3-PROPANEDIOL:
TOXICITY IRRITATION
Oral (rat) LD50: > 5000 mg/kg Skin (rabbit): Non Irritant
Dermal (rabbit) LD50: > 2,000 mg/kg Eye (rabbit): Non Irritant [ARCO]
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Section 11 - TOXICOLOGICAL INFORMATION ...
HYDROCARBON PROPELLANT:
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
?Consult State Land Waste Management Authority for disposal.
?Discharge contents of damaged aerosol cans at an approved site.
?Allow small quantities to evaporate.
?DO NOT incinerate or puncture aerosol cans.
?Bury residues and emptied aerosol cans at an approved site.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name: AEROSOLS
Hazard Class: 2.1
UN/NA Number: 1950
Packing Group: None
Labels Required: flammable gas
Additional Shipping Information:
International Transport Regulations:
IMO: 2.1
Section 15 - REGULATORY INFORMATION
RISK
Irritating to eyes.
Extremely flammable.
Risk of explosion if heated under confinement.
SAFETY
Do not breathe gas/ fumes/ vapour/ spray.
Wear eye/ face protection.
Use only in well ventilated areas.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
If you feel unwell contact Doctor or Poisons Information Centre (show the label
if possible).
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DEODORANT AIR FRESHENER
ChemWatch Material Safety Data Sheet CHEMWATCH 4811-19
Issue Date: Tue 14-Sep-2004 CD 2004/3 Page 14 of 14
Section 15 - REGULATORY INFORMATION ...
REGULATIONS
No data available for ethanol as (CAS: 64-17-5). (CAS: 2163-42-0).
(CAS: 68476-85-7). (CAS: 68476-86-8).
Section 16 - OTHER INFORMATION
This product contains non-depleting Ozone Substances
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Tue 14-Sep-2004
Print Date: Wed 15-Sep-2004
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