Material Safety Data Sheet
ULTRASIL 75
Section 1. Chemical product and company identification
: ULTRASIL 75
Trade name
: Mucous membrane antiseptic
Product use
: Ecolab Food and Beverage
Supplier
5105 Tomken Road
Mississauga ON L4W 2X5
1-800-352-5326
: 989327
Code
Date of issue 05-December-2008
EMERGENCY HEALTH INFORMATION: 1-800-328-0026
Outside United States and Canada CALL 1-651-222-5352 (in USA)
Section 2. Composition, information on ingredients
Name CAS number % by weight
nitric acid 7697-37-2 15 - 40
phosphoric acid 7664-38-2 15 - 40
Section 3. Hazards identification
Physical state : Liquid. [Liquid.]
Emergency : DANGER !
overview
CAUSES RESPIRATORY TRACT, DIGESTIVE TRACT, EYE AND SKIN BURNS.
MAY BE HARMFUL IF SWALLOWED.
OXIDISER.
CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
Do not ingest. Do not get in eyes, on skin or on clothing. Do not breathe vapour or mist.
Avoid all possible sources of ignition (spark or flame). Keep away from heat and direct
sunlight. Decomposes on heating. Keep container closed. Use only with adequate
ventilation. Wash thoroughly after handling.
: Skin contact, Eye contact, Inhalation, Ingestion
Routes of entry
Potential acute health effects
Eyes : Corrosive to eyes.
Skin : Corrosive to the skin.
: Corrosive to the respiratory system.
Inhalation
: Causes burns to mouth, throat and stomach. May be harmful if swallowed.
Ingestion
See toxicological information (section 11)
Section 4. First-aid measures
Eye contact : In case of contact, immediately flush eyes with cool running water. Remove contact lenses and
continue flushing with plenty of water for at least 15 minutes. Get medical attention
immediately.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
Skin contact
removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Inhalation : If inhaled, remove to fresh air. If exposed person is not breathing, give artificial respiration or
oxygen applied by trained personnel. Get medical attention immediately.
Ingestion : If material has been swallowed and the exposed person is conscious, give small quantities of
water to drink. Do not induce vomiting. Never give anything by mouth to an unconscious
person. Get medical attention immediately.
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ULTRASIL 75
Section 5. Fire-fighting measures
:
Auto-ignition temperature Not available.
:
Flash point > 100癈
:
Flammable limits Not available.
Hazardous thermal : Decomposition products may include the following materials:
nitrogen oxides
decomposition products
phosphorus oxides
: Use an extinguishing agent suitable for the surrounding fire.
Fire-fighting media and
Move containers from fire area if this can be done without risk. Use water
instructions
spray to keep fire-exposed containers cool. Dyke area of fire to prevent runoff.
Contact with combustible material may cause fire. This material increases the
risk of fire and may aid combustion. In a fire or if heated, a pressure increase
will occur and the container may burst.
Special protective equipment for : Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
fire-fighters
mode.
Risk of explosion of the product in the presence of mechanical impact: Not available.
Risk of explosion of the product in the presence of static discharge: Not available.
Section 6. Accidental release measures
Personal : Immediately contact emergency personnel. Stop leak if without risk. Eliminate all ignition
sources. Use suitable protective equipment. Keep unnecessary personnel away. Do not touch
precautions
or walk through spilt material.
Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers,
precautions
waterways, soil or air).
Methods for : If emergency personnel are unavailable, contain spilt material. For small spills, add absorbent
(soil may be used in the absence of other suitable materials), scoop up material and place in a
cleaning up
sealable, liquid-proof container for disposal. For small spills, add absorbent (soil may be used
in the absence of other suitable materials) and use a non-sparking or explosion-proof means to
transfer material to a sealable, appropriate container for disposal. For large spills, dyke spilt
material or otherwise contain it to ensure runoff does not reach a waterway. Place spilt material
in an appropriate container for disposal.
Section 7. Handling and storage
Handling : Do not ingest. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Keep
container closed. Keep only in the original container. Avoid contact with combustible materials.
Do not mix with bleach or other chlorinated products ?will cause chlorine gas. Use only with
adequate ventilation. Wash thoroughly after handling.
Storage : Keep out of reach of children. Keep container in a cool, well-ventilated area. Keep container
tightly closed.
Store between the following temperatures: -30 and 50癈
Section 8. Exposure controls/personal protection
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. Provide suitable facilities for quick drenching or flushing of the eyes and body in
case of contact or splash hazard.
Personal protection :
Eyes : Use chemical splash goggles. For continued or severe exposure wear a face shield over the
goggles.
Hands : Use chemical-resistant, impervious gloves.
Skin : Use synthetic apron, other protective equipment as necessary to prevent skin contact.
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ULTRASIL 75
Respiratory : Wear appropriate respirator when ventilation is inadequate and occupational exposure limits
are exceeded.
Name Exposure limits
nitric acid CA Alberta Provincial (Canada, 6/2008).
15 min OEL: 10 mg/m?15 minute(s).
15 min OEL: 4 ppm 15 minute(s).
8 hrs OEL: 5.2 mg/m?8 hour(s).
8 hrs OEL: 2 ppm 8 hour(s).
CA British Columbia Provincial (Canada, 6/2008).
STEL: 4 ppm 15 minute(s).
TWA: 2 ppm 8 hour(s).
CA Ontario Provincial (Canada, 6/2008).
STEV: 10 mg/m?15 minute(s).
STEV: 4 ppm 15 minute(s).
TWAEV: 5 mg/m?8 hour(s).
TWAEV: 2 ppm 8 hour(s).
CA Quebec Provincial (Canada, 6/2008).
STEV: 10 mg/m?15 minute(s).
STEV: 4 ppm 15 minute(s).
TWAEV: 5.2 mg/m?8 hour(s).
TWAEV: 2 ppm 8 hour(s).
ACGIH TLV (United States, 1/2008).
STEL: 10 mg/m?15 minute(s).
STEL: 4 ppm 15 minute(s).
TWA: 5.2 mg/m?8 hour(s).
TWA: 2 ppm 8 hour(s).
phosphoric acid CA Alberta Provincial (Canada, 6/2008).
8 hrs OEL: 1 mg/m?8 hour(s).
15 min OEL: 3 mg/m?15 minute(s).
CA British Columbia Provincial (Canada, 6/2008).
STEL: 3 mg/m?15 minute(s).
TWA: 1 mg/m?8 hour(s).
CA Ontario Provincial (Canada, 6/2008).
STEV: 3 mg/m?15 minute(s).
TWAEV: 1 mg/m?8 hour(s).
CA Quebec Provincial (Canada, 6/2008).
STEV: 3 mg/m?15 minute(s).
TWAEV: 1 mg/m?8 hour(s).
ACGIH TLV (United States, 1/2008).
STEL: 3 mg/m?15 minute(s).
TWA: 1 mg/m?8 hour(s).
Section 9. Physical and chemical properties
: Liquid. [Liquid.]
Physical state
: Clear.
Colour
: Faint odour.
Odour
: 1.4 to 1.6 [Conc. (% w/w): 100%]
pH
: Not available.
Boiling/condensation point
: Not available.
Melting/freezing point
Relative density : 1.35 to 1.36
: Not available.
Vapour pressure
: Not available.
Vapour density
: Not available.
Odour threshold
: Not available.
Evaporation rate
LogKow : Not available.
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ULTRASIL 75
Section 10. Stability and reactivity
: The product is stable. Under normal conditions of storage and use, hazardous
Stability
polymerisation will not occur.
: Not available.
Conditions of instability
: Highly reactive with alkalis.
Reactivity
Reactive with metals.
Slightly reactive to reactive with organic materials.
Decomposes on heating.
Do not mix with bleach or other chlorinated products ?will cause chlorine gas.
: Under normal conditions of storage and use, hazardous decomposition products
Hazardous decomposition
should not be produced.
products
: Under normal conditions of storage and use, hazardous polymerisation will not
Hazardous polymerisation
occur.
Section 11. Toxicological information
Potential acute health effects
: Corrosive to eyes.
Eyes
: Corrosive to the skin.
Skin
: Corrosive to the respiratory system.
Inhalation
: Causes burns to mouth, throat and stomach. May be harmful if swallowed.
Ingestion
Potential chronic health effects
Carcinogenic effects : No known significant effects or critical hazards.
NTP
Ingredient name ACGIH IARC OSHA
Not applicable.
:
Mutagenic effects No known significant effects or critical hazards.
Teratogenic effects : No known significant effects or critical hazards.
Reproductive effects : No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Sensitization to Product
Synergistic products : Not available.
(toxicologically)
Toxicity data
Ingredient name Test Route Result Species
phosphoric acid LD50 Oral 1.25 gm/kg Mouse - Male
LD50 Oral 1.25 gm/kg Rat
nitric acid LDLo Oral 430 mg/kg Human
: Contains material which may cause damage to the following organs: lungs, mucous
Target organs
membranes, upper respiratory tract, teeth.
Section 12. Ecological information
Ecotoxicity
Ingredient name Species Period
Not available.
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ULTRASIL 75
Section 13. Disposal considerations
Waste disposal : The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements.
Consult your local or regional authorities.
Section 14. Transport information
Certain shipping modes or package sizes may have exceptions from the transport
regulations. The classification provided may not reflect those exceptions and may
not apply to all shipping modes or package sizes.
UN Classification
UN3264
UN number
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (nitric acid)
Proper shipping name
8
Class
Not
applicable. Packing group II
See shipping documents for specific transportation information.
Section 15. Regulatory information
WHMIS : Class C: Oxidising material.
Class E: Corrosive material
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
Section 16. Other information
Date of issue : 05-December-2008.
Responsible name : Regulatory Affairs
1-800-352-5326
Date of previous issue : 31-January-2006.
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product
in the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.
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