Material Safety Data Sheet
Printed: 08.11.2004
Revised: 03.11.2004
Lithofin KF Cement Residue Remover
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1 Identification of substance:
Product details:
Trade name: Lithofin KF Cement Residue Remover
Application of the substance / the preparation Cleaning agent/ Cleaner
Distributor:
GranQuartz, L. P.
P.O. Box 2206
Tucker, GA 30085-2206/USA
Information Department:
see above
Emergency Information:
information department
24-Hour Emergency Telephone Number:
1-800-255-3924 (USA & Canada) or 813-248-0585
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2 Composition/Data on components:
Chemical characterization
Description:
Mixture of the substances listed below with non hazardous additions.
Dangerous components:
7664-38-2 phosphoric acid 10-25 %
RTECS: TB 6300000
164-18-6 formic acid < 2.5 %
RTECS: LQ 4900000
110-65-6 but-2-yne-1,4-diol < 2.5 %
RTECS: ES 0525000
Additional information
For the wording of the listed risk phrases refer to section 16.
TSCA
7732-18-5 water, distilled, conductivity or of similar purity
7664-38-2 phosphoric acid
164-18-6 formic acid
110-65-6 but-2-yne-1,4-diol
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3 Hazards identification
Hazard description: Irritant
Information pertaining to particular dangers for man and environment
Irritating to eyes and skin.
Classification system
The classification is in line with internationally approved calculation standards. It is expanded,
however, by information from technical literature and by information furnished by supplier companies.
NFPA ratings (scale 0-4)
Health = 1
Fire = 0
Reactivity = 0
Special: Acid
Additional information:
1
Material Safety Data Sheet
Printed: 08.11.2004
Revised: 03.11.2004
Lithofin KF Cement Residue Remover
This preparation is despite of the extreme ph-value of < 2 only classified as irritant, since there are
special limits for the corrosive substances contained according to annex I of Directive 67/548/EEC.
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4 First aid measures
General information
Immediately remove any clothing soiled by the product.
After inhalation
Supply fresh air; consult doctor in case of complaints.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
After eye contact
First check the victim for contact lenses and remove if present.
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Do not induce vomiting
Drink plenty of water, but never give anything to an unconscious person.
Seek medical treatment.
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5 Fire fighting measures
Suitable extinguishing agents
The product is not combustible and does not support combustion.
Use fire fighting measures that suit the environment.
Special hazards caused by the material, its products of combustion or resulting gases:
No hazards known
Protective equipment:
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter the sewage system.
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6 Accidental release measures
Person-related safety precautions:
Ensure adequate ventilation
Wear protective clothing.
Keep unprotected persons away.
Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Do not allow to penetrate the ground/soil.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Send for recovery or disposal in suitable receptacles.
Dispose contaminated material as waste according to item 13.
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7 Handling and storage
Handling
Information for safe handling:
Use only in well ventilated areas.
Avoid contact with eyes and skin.
Avoid inhalation of vapours.
Information about protection against explosions and fires:
No special measures required.
Storage
2
Material Safety Data Sheet
Printed: 08.11.2004
Revised: 03.11.2004
Lithofin KF Cement Residue Remover
Requirements to be met by storerooms and receptacles:
Store receptacles tightly closed at a cool and dry place with sufficient ventilation
Provide acid-resistant floor.
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from feed.
Do not store together with alkalis (caustic solutions).
Store away from metals.
Further information about storage conditions:
Keep receptacle tightly sealed.
Storage class 8 Corrosive products (VCI)
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8 Exposure controls and personal protection
Additional information about design of technical systems:
No further data; see item 7.
Components with limit values that require monitoring at the workplace:
7664-38-2 phosphoric acid
PEL: 1 mg/m?br>
REL: short-term value: 3 mg/m?br>
long-term value: 1 mg/m?br>
TLV: short-term value: 3 mg/m?br>
long-term value: 1 mg/m?br>
Additional information:
The lists that were valid during the creation were used as basis.
Personal protective equipment
General protective and hygienic measures
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
The usual protective measures based on the application have to be followed.
All protective equipment used shall be according to 29 CFR.1910 Subpart I Personal Protective
Equipment
Breathing equipment:
Not necessary if room is well-ventilated.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements
or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's
use.
Always use a NIOSH or European Standard EN 149 approved respirator when
necessary.
Short term filter device:
Gas filter: E (colour code yellow)
Protection of hands:
Acid resistant gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
After use of gloves apply skin-cleaning agents and skin cosmetics.
Material of gloves
Polychloropren rubber (CR)
Butyl rubber, BR
Nitrile rubber, NBR
Natural rubber, NR
Fluorocarbon rubber (FKM)
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
3
Material Safety Data Sheet
Printed: 08.11.2004
Revised: 03.11.2004
Lithofin KF Cement Residue Remover
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
Eye protection: Tightly sealed goggles.
Body protection: Acid resistant protective clothing
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9 Physical and chemical properties:
General Information
General Information
Form: Fluid
Color: Orange
Odor: Pleasant
Value/Range Unit Method
Change in condition
Melting point/Melting range: undetermined
Boiling point/Boiling range: > 90 ?C
Flash point: Not applicable
Auto igniting: Product is not self igniting.
Danger of explosion: Product does not present an explosion hazard.
Density: at 20?C ~ 1.1 g/cm?br>
Solubility in / Miscibility with Water: Soluble
pH-value: at 20?C < 2 in delivery state
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10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Dangerous reactions Reacts with metals forming hydrogen
Dangerous products of decomposition:
No dangerous decomposition products known
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11 Toxicological information
Acute toxicity:
LD/LC50 values that are relevant for classification:
No toxicity data are available for the product itself.
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internationally approved calculation methods for
preparations: Irritant
After swallowing: irritations of mucous membranes in the mouth, pharynx, oesophagus and
gastrointestinal tract.
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12 Ecological information:
Ecotoxical effects:
4
Material Safety Data Sheet
Printed: 08.11.2004
Revised: 03.11.2004
Lithofin KF Cement Residue Remover
Acquatic toxicity:
Presently there are no ecotoxicological values available.
Remark: Harmful effects possible due to shift of pH value.
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
Danger to drinking water is possible if large quantities leak into the ground or into water course.
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13 Disposal considerations
Product:
Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
Disposal according to instructions of local authorities.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
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14 Transport information
DOT regulations:
Hazard class: 8
Identification number: UN1760
?Packing group: III
Proper shipping name (technical name):
CORROSIVE LIQUID, N.O.S. (PHOSPHORIC ACID, FORMIC ACID)
Label 8
Land transport ADR/RID (cross-border)
ADR/RID class: 8 (C9) Corrosive substances
Danger code (Kemler): 8
UN-Number: 1760
Packaging group: III
Description of goods: 1760 CORROSIVE LIQUID, N.O.S. (PHOSPHORIC ACID, FORMIC
ACID)
Maritime transport IMDG:
IMDG Class: 8
UN Number: 1760
Label 8
Packaging group: III
EMS Number: F-A,S-B
Marine pollutant: No
Propper shipping name: CORROSIVE LIQUID, N.O.S. (PHOSPHORIC ACID, FORMIC ACID)
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 8
UN/ID Number: 1760
Label 8
Packaging group: III
Proper shipping name: CORROSIVE LIQUID, N.O.S. (PHOSPHORIC ACID, FORMIC ACID)
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15 Regulations
Cancerogenity categories
EPA (Environmental Protection Agency)
5
Material Safety Data Sheet
Printed: 08.11.2004
Revised: 03.11.2004
Lithofin KF Cement Residue Remover
void
IARC (International Agency for Research on Cancer)
void
NTP (National Toxicology Program)
void
TLV (Threshold Limit Value established by ACGIH)
void
MAK (German Maximum Workplace Concentration)
void
NIOSH-Ca (National Institute for Occupational Safety and Health)
void
OSHA-Ca (Occupational Safety & Health Administration)
void
Markings according to EU guidelines:
Code letter and hazard designation of product: Irritant
Risk phrases: Irritating to eyes and skin.
Safety phrases:
Keep out of the reach of children.
Avoid contact with eyes.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable gloves.
If swallowed, seek medical advice immediately and show this container or label.
If swallowed, rinse mouth with water (only if the person is conscious)
Regulation or reporting requirements USA
Sara section 355
not listed
Sara section 313
7664-38-2 phosphoric acid
164-18-6 formic acid
Prop. 65 - Cancer
not listed
Prop. 65 - Repr. tox.
not listed
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16 Other information:
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
Department issuing MSDS:
KFT-Chemieservice Marienstr. 3 D-64347 Griesheim
Postfach 1451 D-64345 Griesheim
Tel.: +49-6155-823241
Fax: +49-6155-823246
Contact: Angelika Torges
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