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Hazard Alert Code:
X-DUTY CLEANER MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) Revision No: 5 Chemwatch 4635-05
Issue Date: 23-Mar-2007 CD 2007/3
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: X-DUTY CLEANER
PRODUCT USE
Cleaner for tile, stone, paving and grout.
SUPPLIER
Company: Dry-Treat Inc
Address:
1201 Orange Street, Suite 600 One Commerce Center
Willmington
DE, 19801
USA
Telephone: +1 866 667 5119
Telephone: +61 2 9954 3211
Emergency Tel: Outside USA +1 (813) 248 0585
Emergency Tel: CHEM-TEL (800) 255-3924
Fax: +61 2 9954 3162
HAZARD RATINGS
Min Max
Flammability: 1
Toxicity: 2
Body Contact: 2 Min/Nil=0
Low=1
Reactivity: 1 Moderate=2
High=3
Chronic: 2 Extreme=4
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK SAFETY
Irritating to eyes and skin. Do not breathe gas/ fumes/ vapour/ spray.
May cause SENSITISATION by skin contact. Use only in well ventilated areas.
Very toxic to aquatic organisms may cause long-term adverse
Keep container in a well ventilated place.
effects in the aquatic environment.
HARMFUL - May cause lung damage if swallowed. Avoid exposure - obtain special instructions before use.
To clean the floor and all objects contaminated by this material use
Vapours may cause drowsiness and dizziness.
water.
Inhalation skin contact and/or ingestion may produce health
Keep container tightly closed.
damage*.
Cumulative effects may result following exposure*. This material and its container must be disposed of in a safe way.
May produce discomfort of the respiratory system*. Keep away from food drink and animal feeding stuffs.
Limited evidence of a carcinogenic effect*. Take off immediately all contaminated clothing.
In case of contact with eyes rinse with plenty of water and contact
May be harmful to the foetus/ embryo*.
Doctor or Poisons Information Centre.
If swallowed IMMEDIATELY contact Doctor or Poisons Information
* (limited evidence).
Centre (show this container or label).
Use appropriate container to avoid environment contamination.
Avoid release to the environment. Refer to special instructions/
safety data sheets.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
N-methyl-2-pyrrolidone 872-50-4 30-60
d-limonene 5989-27-5 10-30
surfactants 10-30
Section 4 - FIRST AID MEASURES
SWALLOWED
If swallowed do NOT induce vomiting.
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Hazard Alert Code:
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Chemwatch Material Safety Data Sheet (REVIEW) Revision No: 5 Chemwatch 4635-05
Issue Date: 23-Mar-2007 CD 2007/3
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent
aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
EYE
If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the
upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
INHALED
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as
trained. Perform CPR if necessary.
Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
FIRE FIGHTING
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.
Avoid spraying water onto liquid pools.
Do not approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
May emit acrid smoke.
Mists containing combustible materials may be explosive.
Other combustion products include:.
carbon dioxide (CO2).
nitrogen oxides (NOx).
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
HAZCHEM
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
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Chemwatch Material Safety Data Sheet (REVIEW) Revision No: 5 Chemwatch 4635-05
Issue Date: 23-Mar-2007 CD 2007/3
Moderate hazard.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
No smoking, naked lights or ignition sources.
Increase ventilation.
Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite.
Collect solid residues and seal in labelled drums for disposal.
Wash area and prevent runoff into drains.
If contamination of drains or waterways occurs, advise emergency services.
SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
+ X + X 0 +
X: Must not be stored together
O: May be stored together with specific preventions
+: May be stored together
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
Avoid generating and breathing mist.
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
Avoid smoking, naked lights or ignition sources.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Keep containers securely sealed when not in use.
Avoid physical damage to containers.
Always wash hands with soap and water after handling.
Work clothes should be laundered separately.
Use good occupational work practice.
Observe manufacturer's storing and handling recommendations.
Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.
SUITABLE CONTAINER
Metal can or drum
Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
TWA TWA STEL STEL Peak Peak TWA
Source Material
ppm mg/m? ppm mg/m? ppm mg/m? F/CC
Australia Exposure N-methyl-2-pyrrolidone (1-Methyl-2-
25 103 75 309
Standards pyrrolidone)
The following materials had no OELs on our records
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Hazard Alert Code:
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Chemwatch Material Safety Data Sheet (REVIEW) Revision No: 5 Chemwatch 4635-05
Issue Date: 23-Mar-2007 CD 2007/3
?d-limonene: CAS:5989-27-5 CAS:138-86-3
MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
N-METHYL-2-PYRROLIDONE:
Reports of skin and eye irritation and chronic headaches have been
reported in workers exposed to 1-methyl-2-pyrrolidone. The Australian ES
is based on a 10-fold uncertainty factor of the no-observable-adverse-
effect level (NOAEL) of 24 ppm where adverse respiratory effects were
observed in a 4-week inhalation study in rats.
D-LIMONENE:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically
occupational exposure standards for these irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be protected against even minor sensory irritation
and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-
observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach,
typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from
irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a
five-category system based on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be
consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to
that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
cause inflammation
cause increased susceptibility to other irritants and infectious agents
lead to permanent injury or dysfunction
permit greater absorption of hazardous substances and
acclimate the worker to the irritant warning properties of these substances thus increasing the risk of overexposure.
CEL TWA: 30 ppm, 165.6 mg/m3 (compare WEEL-TWA*)
A Workplace Environmental Exposure Level* has been established by AIHA
(American Industrial Hygiene Association) who have produced the following
rationale:
D-limonene is not acutely toxic. In its pure form it is not a sensitiser
but is irritating to the skin. Although there is clear evidence of
carcinogenicity in male rats, the effect has been attributed to an
alpha-2u-globin (a2u-G) renal toxicity which is both species and gender
specific. Humans do not synthesise a2u-G, and metabolism studies indicate
that 75% to 95% of d-limonene is excreted in 2-3 days with different
metabolites identified between humans and rats. In a 2-year study, liver
effects were noted in male mice at 500 mg/kg and reduced survival was noted
in female rats at 600 mg/kg. The no observable effect levels (NOELs) were
250 and 300 mg/kg, respectively. A WEEL of 30 ppm is recommended to
protect against these effects.
PERSONAL PROTECTION
EYE
Safety glasses with side shields; or as required,
Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,
describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of
lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid
personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye
redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59]
HANDS/FEET
DO NOT use this product to clean the skin.
OTHER
Overalls.
Barrier cream
Eyewash unit.
ENGINEERING CONTROLS
Use in a well-ventilated area.
General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances.
If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate
ventilation in warehouse or closed storage areas.
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Chemwatch Material Safety Data Sheet (REVIEW) Revision No: 5 Chemwatch 4635-05
Issue Date: 23-Mar-2007 CD 2007/3
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Very light yellow, clear liquid with solvent odour; dispersible in water. USA VOC content: < 20 g/litre
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not applicable Boiling Range (癈): Not available
Melting Range (癈): Not available. Specific Gravity (water=1): 1.015
Solubility in water (g/L): Miscible pH (as supplied): Not applicable
pH (1% solution): Not applicable. Vapour Pressure (kPa): Not available
Volatile Component (%vol): Not available Evaporation Rate: Not available
Relative Vapour Density (air=1): >1 Flash Point (癈): >61
Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available
Autoignition Temp (癈): Not available Decomposition Temp (癈): Not available.
State: Liquid Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
Presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration may cause potentially lethal chemical
pneumonitis.
EYE
The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.
SKIN
Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.
The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness,
swelling, the production of vesicles, scaling and thickening of the skin. Repeated exposures may produce severe ulceration.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the same as for inhalation.
INHALED
The vapour is discomforting.
Inhalation of vapour is more likely at higher than normal temperatures.
Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with
headache and dizziness, slowing of reflexes, fatigue and inco-ordination.
Not considered an irritant through normal use.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational
exposure.
Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.
Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS].
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
d-limonene IARC:3
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: d-limonene
Category: The substance is classified by IARC as Group 3: NOT classifiable as to its
carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in
animal testing.
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
N-METHYL-2-PYRROLIDONE:
DO NOT discharge into sewer or waterways.
log Kow: -0.44-0.1
D-LIMONENE:
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Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not
contaminate water when cleaning equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
Substances containing unsaturated carbons are ubiquitous in indoor environments. They result from many sources (see below). Most
are reactive with environmental ozone and many produce stable products which are thought to adversely affect human health.The
potential for surfaces in an enclosed space to facilitate reactions should be considered.
Unsaturated substances (Reactive Major Stable Products produced following
Source of unsaturated substances
Emissions) reaction with ozone.
Methacrolein, methyl vinyl ketone, nitrogen
Isoprene, nitric oxide, squalene,
dioxide, acetone, 6MHQ, geranyl acetone,
Occupants (exhaled breath, ski oils, unsaturated sterols, oleic acid and other
4OPA, formaldehyde, nonanol, decanal, 9-
personal care products) unsaturated fatty acids, unsaturated
oxo-nonanoic acid, azelaic acid, nonanoic
oxidation products
acid.
Formaldehyde, 4-AMC, pinoaldehyde, pinic
Soft woods, wood flooring, including
Isoprene, limonene, alpha-pinene, other acid, pinonic acid, formic acid,
cypress, cedar and silver fir boards,
terpenes and sesquiterpenes methacrolein, methyl vinyl ketone, SOAs
houseplants
including ultrafine particles
4-Phenylcyclohexene, 4-vinylcyclohexene,
Formaldehyde, acetaldehyde,
Carpets and carpet backing styrene, 2-ethylhexyl acrylate, unsaturated
benzaldehyde, hexanal, nonanal, 2-nonenal
fatty acids and esters
Propanal, hexanal, nonanal, 2-heptenal, 2-
Linoleum and paints/polishes containing
Linoleic acid, linolenic acid nonenal, 2-decenal, 1-pentene-3-one,
linseed oil
propionic acid, n-butyric acid
Latex paint Residual monomers Formaldehyde
Formaldehyde, acetaldehyde,
glycoaldehyde, formic acid, acetic acid,
Limonene, alpha-pinene, terpinolene,
hydrogen and organic peroxides, acetone,
Certain cleaning products, polishes, waxes, alpha-terpineol, linalool, linalyl acetate and
benzaldehyde, 4-hydroxy-4-methyl-5-
air fresheners other terpinoids, longifolene and other
hexen-1-al, 5-ethenyl-dihydro-5-methyl-2
sesquiterpenes
(3H)-furanone, 4-AMC, SOAs including
ultrafine particles
Formaldehyde, methacrolein, methyl vinyl
Natural rubber adhesive Isoprene, terpenes
ketone
Photocopier toner, printed paper, styrene
Styrene Formaldehyde, benzaldehyde
polymers
Formaldehyde, benzaldehyde, hexanal,
Environmental tobacco smoke Styrene, acrolein, nicotine glyoxal, N-methylformamide,
nicotinaldehyde, cotinine
Acetone, geranyl acetone, 6MHO, 40PA,
Squalene, unsaturated sterols, oleic acid
Soiled clothing, fabrics, bedding formaldehyde, nonanal, decanal, 9-oxo-
and other saturated fatty acids
nonanoic acid, azelaic acid, nonanoic acid
Formaldehyde, nonanal, and other
Unsaturated fatty acids from plant waxes, aldehydes; azelaic acid; nonanoic acid; 9-
Soiled particle filters leaf litter, and other vegetative debris; soot; oxo-nonanoic acid and other oxo-acids;
diesel particles compounds with mixed functional groups
(=O, -OH, and -COOH)
Unsaturated fatty acids and esters,
Ventilation ducts and duct liners C5 to C10 aldehydes
unsaturated oils, neoprene
"Urban grime" Polycyclic aromatic hydrocarbons Oxidized polycyclic aromatic hydrocarbons
Formaldehyde, 4-AMC, acetone, 4-
Perfumes, colognes, essential oils (e.g. Limonene, alpha-pinene, linalool, linalyl hydroxy-4-methyl-5-hexen-1-al, 5-ethenyl-
lavender, eucalyptus, tea tree) acetate, terpinene-4-ol, gamma-terpinene dihydro-5-methyl-2(3H) furanone, SOAs
including ultrafine particles
Formaldehyde, 4-AMC, pinonaldehyde,
acetone, pinic acid, pinonic acid, formic
Overall home emissions Limonene, alpha-pinene, styrene
acid, benzaldehyde, SOAs including
ultrafine particles
Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA, 4-oxopentanal, SOA, Secondary
Organic Aerosols
Reference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of waters after release in calm sea conditions.
This is expected to evaporate and enter the atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to be spread over a fairly wide area of sea floor.
Marine sediments may be either aerobic or anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the hydrocarbons may be degradable under
anaerobic conditions although such degradation in benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while under anaerobic processes it will produce water,
methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for bioaccumulation may be high. Toxic effects are often
observed in species such as blue mussel, daphnia, freshwater green algae, marine copepods and amphipods.
DO NOT discharge into sewer or waterways.
LD50 Colinus virginianus (Bobwhite quail, 16 weeks old) oral >2000 mg/kg
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LC50 Colinus virginianus (Bobwhite quail, 10 day old) dietary >5620 ppm/8 days
LC50 Colinus virginianus (Bobwhite quail, 14 day old) dietary >5000 ppm/8 days
LC50 Anas platyrhynchos (Mallard duck, 14 day old) dietary >5000 ppm/8 days
LC50 Oncorhynchus mykiss (Rainbow trout) 80 ppm/96 hr (95% confidence limit: 71.4-88.7 ppm); static /92% AI formulated product
LC50 Oncorhynchus mykiss (Rainbow trout) 568 ppm/96 hr (95% confidence limit: 437-852 ppm); static /4.0% AI formulated product
EC50 Daphnia magna (Water flea, <24 hr old; intoxication, immobilization) 17 ppm/48 hr (95% confidence limit: 11-33 ppm);
static /4.0% AI formulated product
LC50 Pimephales promelas (Fathead minnow) 966 ppm/96 hr (95% confidence limit: 740-1652 ppm); static /4.0% AI formulated
product
LC50 Pimephales promelas (Fathead minnow) 38.5 mg/L/96 hr; flow through /from table/ LC50
Leuciscus idus (Golden orfe) 32 mg/L/48 hr /Conditions of bioassay not specified in source examined
The acute toxicity of d-limonene ranges from slight to high for aquatic organisms. The lowest acute toxicity values (EC50 or LC50)
identified were approximately 0.4 mg/litre for Daphnia (US EPA, 1990b) and 0.7 mg/litre for fish (US EPA, 1990a,b). The no-observed-
effect concentration (NOEC) for
green algae is approximately 4 mg/litre (US EPA, 1990a). The acute toxicity (EC50 or LC50) of dipentene to Daphnia and fish is about
50-70 times lower than that for d-limonene (US EPA, 1990b). No studies were identified on the chronic toxicity of limonene to aquatic
organisms.
Section 13 - DISPOSAL CONSIDERATIONS
Consult manufacturer for recycling options and recycle where possible .
Consult State Land Waste Management Authority for disposal.
Incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: COMBUSTIBLE LIQUID (bulk storage only)
HAZCHEM:
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
REGULATIONS
X- Duty Cleaner (CAS: None):
No regulations applicable
N- methyl- 2- pyrrolidone (CAS: 872- 50- 4) is found on the following regulatory
lists;
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Schedule 5
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Schedule 6
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume
List
OECD Representative List of High Production Volume (HPV) Chemicals
d- limonene (CAS: 5989- 27- 5) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Schedule 6
International Agency for Research on Cancer (IARC) Carcinogens
OECD Representative List of High Production Volume (HPV) Chemicals
OSPAR List of Substances of Possible Concern
d- limonene (CAS: 138- 86- 3) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) -
Schedule 6
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
OECD Representative List of High Production Volume (HPV) Chemicals
No data available for N- methyl- 2- pyrrolidone as CAS: 26138- 58- 9.
Section 16 - OTHER INFORMATION
Ingredients with multiple CAS Nos
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Chemwatch Material Safety Data Sheet (REVIEW) Revision No: 5 Chemwatch 4635-05
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Ingredient Name CAS
N-methyl-2-pyrrolidone 872-50-4, 26138-58-9
d-limonene 5989-27-5, 138-86-3
REPRODUCTIVE HEALTH GUIDELINES
Ingredient ORG UF Endpoint CR Adeq TLV
N-methyl-2-pyrrolidone 0.91 mg/m3 1000 D NA -
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of vapour components/concentrations: Composite Exposure Standard for Mixture (TWA)
(mg/m3): 165.6 mg/m?If the breathing zone concentration of ANY of the components listed below is exceeded, "Worst Case"
considerations deem the individual to be overexposed. Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m? (%)
d-limonene 30.00 165.6000 30.0
Operations which produce a spray/mist or fume/dust, introduce particulates to the breathing zone. If the breathing zone concentration
of ANY of the components listed below is exceeded, "Worst Case" considerations deem the individual to be overexposed. At the
"Composite Exposure Standard for Mixture" (TWA) (mg/m3): 165.6 mg/m?br>
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent
review by the Chemwatch Classification committee using available literature references.
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under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572
4700.
Issue Date: 23-Mar-2007
Print Date: 11-Oct-2007
http://full.chemwatch.net/chemgold/msds.exe?fontsize=&print=Y&rCode=N&prefna... 11/10/2007
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