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Material Safety Data Sheet
acc. to ISO 11014
Printing date 04/09/2009 Reviewed on 04/09/2009
1 Identification of substance
?Product details
?Trade name: Mix A Organochlorine Pesticides 525.2
?Article number: N9331014
?Application of the substance / the preparation Laboratory chemicals
?Manufacturer/Supplier:
PerkinElmer Life and Analytical Sciences
710 Bridgeport Avenue
Shelton, Connecticut 06484 USA
?Information department:
Technical Support
800-762-4000
?Emergency information:
CHEMTREC (within U.S.) 800 424-9300
CHEMTREC (from outside U.S.) 1(703)-527-3883
2 Composition/Data on components
?Description: Mixture of the substances listed below with nonhazardous additions.
?Hazardous components:
67-64-1 acetone 50-100%
?Additional Components
309-00-2 aldrin (ISO) < 0.1%
319-84-6 (1alpha,2alpha,3?4alpha,5?6?-1,2,3,4,5,6-hexachlorocyclohexane < 0.1%
319-85-7 (1alpha,2?3alpha,4?5alpha,6?-1,2,3,4,5,6-hexachlorocyclohexane < 0.1%
72-54-8 TDE < 0.1%
72-55-9 2,2-bis(p-chlorophenyl)-1,1-dichloroethylene < 0.1%
319-86-8 (1alpha,2alpha,3alpha,4?5alpha,6?-1,2,3,4,5,6-hexachlorocyclohexane < 0.1%
60-57-1 dieldrin (ISO) < 0.1%
50-29-3 DDT (common name not adopted by ISO) < 0.1%
115-29-7 endosulfan (ISO) < 0.1%
959-98-8 Endosulfan I < 0.1%
72-20-8 endrin (ISO) < 0.1%
7321-93-4 Endrin Aldehyde < 0.1%
53494-70-5 2Endrin ketone < 0.1%
58-89-9 -HCH or -BHC < 0.1%
76-44-8 heptachlor (ISO) < 0.1%
1024-57-3 heptachlor epoxide < 0.1%
72-43-5 methoxychlor < 0.1%
* 3 Hazards identification
?Hazard description:
Irritant
Highly flammable
(Contd. on page 2)
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Material Safety Data Sheet
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Trade name: Mix A Organochlorine Pesticides 525.2
(Contd. of page 1)
?WHMIS-symbols:
B2 - Flammable liquid
D2B - Toxic material causing other toxic effects
?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Highly flammable.
Irritating to eyes.
Vapours may cause drowsiness and dizziness.
?Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
?NFPA ratings (scale 0 - 4)
Health = 1
3 Fire = 3
1 0 Reactivity = 0
?HMIS-ratings (scale 0 - 4)
HEALTH 1 Health = 1
Fire = 3
FIRE 3
Reactivity = 0
REACTIVITY 0
* 4 First aid measures
?After inhalation: Supply fresh air; consult doctor in case of complaints.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire fighting measures
?Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Protective equipment: No special measures required.
* 6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
(Contd. on page 3)
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Material Safety Data Sheet
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Trade name: Mix A Organochlorine Pesticides 525.2
(Contd. of page 2)
Ensure adequate ventilation.
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: Store in a cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
67-64-1 acetone
EL () Short-term value: 500 ppm
Long-term value: 250 ppm
EV () Short-term value: 750 ppm
Long-term value: 500 ppm
?Additional information: The lists that were valid during the creation were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 4)
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Material Safety Data Sheet
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Trade name: Mix A Organochlorine Pesticides 525.2
(Contd. of page 3)
?Eye protection:
Tightly sealed goggles or safety glasses
9 Physical and chemical properties
?General Information
Liquid
Form:
Colorless
Color:
Characteristic
Odor:
?Change in condition
Melting point/Melting range: 94.7癈
Boiling point/Boiling range: Undetermined.
< 0癈
?Flash point:
465癈
?Ignition temperature:
Product is not selfigniting.
?Auto igniting:
Product is not explosive. However, formation of explosive air/vapor mixtures are
?Danger of explosion:
possible.
?Explosion limits:
2.6 Vol %
Lower:
13 Vol %
Upper:
233 hPa
?Vapor pressure at 20癈:
0.79 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Fully miscible.
Water:
?Solvent content:
99.7 %
Organic solvents:
0.1 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
67-64-1 acetone
Oral LD50 5800 mg/kg (rat)
(Contd. on page 5)
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Material Safety Data Sheet
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Trade name: Mix A Organochlorine Pesticides 525.2
(Contd. of page 4)
Dermal LD50 20000 mg/kg (rabbit)
58-89-9 -HCH or -BHC
Oral LD50 88 mg/kg (rat)
Dermal LD50 900 mg/kg (rat)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
12 Ecological information
?General notes:
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
?Recommended cleansing agent: Water, if necessary with cleansing agents.
14 Transport information
?DOT regulations:
3
?Hazard class:
UN1090
?Identification number:
II
?Packing group:
?Proper shipping name (technical name): ACETONE
3
?Label
?TDG (Transport dangerous goods):
3 Flammable liquids
?TDG class:
33
?Danger code (Kemler):
1090
?UN-Number:
II
?Packaging group:
(Contd. on page 6)
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Trade name: Mix A Organochlorine Pesticides 525.2
(Contd. of page 5)
3
?Label:
1090 ACETONE
?Description of goods:
?Maritime transport IMDG:
3
?IMDG Class:
1090
?UN Number:
3
?Label
II
?Packaging group:
F-E,S-D
?EMS Number:
No
?Marine pollutant:
ACETONE
?Propper shipping name:
?Air transport ICAO-TI and IATA-DGR:
3
?ICAO/IATA Class:
1090
?UN/ID Number:
3
?Label
II
?Packaging group:
ACETONE
?Proper shipping name:
15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
309-00-2 aldrin (ISO)
115-29-7 endosulfan (ISO)
72-20-8 endrin (ISO)
58-89-9 -HCH or -BHC
?Section 313 (Specific toxic chemical listings):
309-00-2 aldrin (ISO)
319-84-6 (1alpha,2alpha,3?4alpha,5?6?-1,2,3,4,5,6-hexachlorocyclohexane
58-89-9 -HCH or -BHC
76-44-8 heptachlor (ISO)
72-43-5 methoxychlor
?Proposition 65
?Chemicals known to cause cancer:
309-00-2 aldrin (ISO)
319-84-6 (1alpha,2alpha,3?4alpha,5?6?-1,2,3,4,5,6-hexachlorocyclohexane
319-85-7 (1alpha,2?3alpha,4?5alpha,6?-1,2,3,4,5,6-hexachlorocyclohexane
72-54-8 TDE
(Contd. on page 7)
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Material Safety Data Sheet
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Trade name: Mix A Organochlorine Pesticides 525.2
(Contd. of page 6)
72-55-9 2,2-bis(p-chlorophenyl)-1,1-dichloroethylene
319-86-8 (1alpha,2alpha,3alpha,4?5alpha,6?-1,2,3,4,5,6-hexachlorocyclohexane
60-57-1 dieldrin (ISO)
50-29-3 DDT (common name not adopted by ISO)
-HCH or -BHC
58-89-9
76-44-8 heptachlor (ISO)
1024-57-3 heptachlor epoxide
?Chemicals known to cause reproductive toxicity for females:
50-29-3 DDT (common name not adopted by ISO)
?Chemicals known to cause reproductive toxicity for males:
50-29-3 DDT (common name not adopted by ISO)
?Chemicals known to cause developmental toxicity:
50-29-3 DDT (common name not adopted by ISO)
72-20-8 endrin (ISO)
76-44-8 heptachlor (ISO)
?Cancerogenity categories
?EPA (Environmental Protection Agency)
67-64-1 acetone I
309-00-2 aldrin (ISO) B2
319-84-6 (1alpha,2alpha,3?4alpha,5?6?-1,2,3,4,5,6-hexachlorocyclohexane B2
319-85-7 (1alpha,2?3alpha,4?5alpha,6?-1,2,3,4,5,6-hexachlorocyclohexane C
72-54-8 TDE B2
72-55-9 2,2-bis(p-chlorophenyl)-1,1-dichloroethylene B2
60-57-1 dieldrin (ISO) B2
50-29-3 DDT (common name not adopted by ISO) B2
72-20-8 endrin (ISO) D
76-44-8 heptachlor (ISO) B2
1024-57-3 heptachlor epoxide B2
72-43-5 methoxychlor D
?IARC (International Agency for Research on Cancer)
309-00-2 aldrin (ISO) 3
319-84-6 (1alpha,2alpha,3?4alpha,5?6?-1,2,3,4,5,6-hexachlorocyclohexane 2B
319-85-7 (1alpha,2?3alpha,4?5alpha,6?-1,2,3,4,5,6-hexachlorocyclohexane 2B
60-57-1 dieldrin (ISO) 3
50-29-3 DDT (common name not adopted by ISO) 2B
72-20-8 endrin (ISO) 3
58-89-9 -HCH or -BHC 2B
76-44-8 heptachlor (ISO) 2B
1024-57-3 heptachlor epoxide 2B
72-43-5 methoxychlor 3
?NTP (National Toxicology Program)
319-84-6 (1alpha,2alpha,3?4alpha,5?6?-1,2,3,4,5,6-hexachlorocyclohexane R
(Contd. on page 8)
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Trade name: Mix A Organochlorine Pesticides 525.2
(Contd. of page 7)
319-85-7 (1alpha,2?3alpha,4?5alpha,6?-1,2,3,4,5,6-hexachlorocyclohexane R
50-29-3 DDT (common name not adopted by ISO) R
58-89-9 -HCH or -BHC R
?TLV (Threshold Limit Value established by ACGIH)
67-64-1 acetone A4
309-00-2 aldrin (ISO) A3
60-57-1 dieldrin (ISO) A4
50-29-3 DDT (common name not adopted by ISO) A3
115-29-7 endosulfan (ISO) A4
72-20-8 endrin (ISO) A4
58-89-9 -HCH or -BHC A3
76-44-8 heptachlor (ISO) A3
1024-57-3 heptachlor epoxide A3
72-43-5 methoxychlor A4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
309-00-2 aldrin (ISO)
60-57-1 dieldrin (ISO)
50-29-3 DDT (common name not adopted by ISO)
76-44-8 heptachlor (ISO)
1024-57-3 heptachlor epoxide
72-43-5 methoxychlor
?OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
?Canadian substance listings:
?Canadian Domestic Substances List (DSL)
67-64-1 acetone
58-89-9 -HCH or -BHC
72-43-5 methoxychlor
?Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
?Canadian Ingredient Disclosure list (limit 1%)
All ingredients are listed.
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Hazard symbols:
Irritant
Highly flammable
?Risk phrases:
Highly flammable.
Irritating to eyes.
Vapours may cause drowsiness and dizziness.
?Safety phrases:
Keep container in a well-ventilated place.
Keep away from sources of ignition - No smoking.
(Contd. on page 9)
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Trade name: Mix A Organochlorine Pesticides 525.2
(Contd. of page 8)
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
This material and its container must be disposed of as hazardous waste.
16 Other information
Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
?Department issuing MSDS: Safety and Health
?Contact:
With in the USA: 1-(800)-762-4000
Out side the USA: 1-(203)-712-8488
?* Data compared to the previous version altered.
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