Anitec
Material Safety Data Sheet N EWSPAPER COM PANY
Guardian Plate Finisher
1. Chemical Product and Company Identification
: Guardian Plate Finisher
Common Name
336
MSDS#
Version 2.53
: PCD 6318; CIN 10099612; E-0014.300
Synonym
Validation Date 2000-09-06
: 300 5781; 300 5782; 300 5783
Catalogue number
Responsible Name Kodak Polychrome
: Industrial applications. Graphic Arts Imaging.
Area of Application
Graphics
: Anitec Newspaper Company
Supplier
383 Dwight Street
Holyoke, MA 01040
USA
Tel. (413) 538-9624
Emergency telephone : In Case of Emergency (medical/roadside) (24hrs) CALL 1-800-451-8346
number
: Kodak Polychrome Graphics, Environmental Solutions Department;
For other EHS
11465 Johns Creek Parkway, #260, Duluth, GA 30097; USA
Information
Phone: 1-877-574-7274 ext. 511, Additional phone: (770) 232-2133
E-mail: PEP@kpgraphics.com, Fax: (770) 232-2150;
2. Composition, Information on Ingredients
Name CAS # % by Weight Exposure Limits
1) Water 7732-18-5 90-95 Not available.
2) Sodium hexametaphosphate 10124-56-8 1-5 Not available.
3) Polyvinyl pyrrolidon 9003-39-8 1-5 Not available.
TWA: 10 (mg/m3)
4) Glycerol 56-81-5 <1
5) Sodium citrate 68-04-2 <1 Not available.
3. Hazards Identification
: Liquid.
Physical State and
Appearance
Emergency Overview CAUTION
:
MAY CAUSE EYE AND SKIN IRRITATION.
Avoid contact with eyes, skin, and clothing. Harmful if swallowed
: Absorbed through skin. Eye contact.
Routes of Entry
Potential Acute Health Effects
Eyes : Slightly hazardous in case of eye contact (irritant).
: Sensitization of the product: Not available.
Skin
Slightly hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling,
reddening, or, occasionally, blistering.
Inhalation : Slightly hazardous in case of inhalation.
Ingestion : Hazardous in case of ingestion.
: CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Polyvinyl pyrrolidon].
Potential Chronic
MUTAGENIC EFFECTS: Not available.
Health Effects
TERATOGENIC EFFECTS: Not available.
Medical Conditions : Repeated or prolonged exposure is not known to aggravate medical condition.
Aggravated by
Overexposure:
See Toxicological Information (section 11)
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Guardian Plate Finisher
4. First Aid Measures
: Check for and remove any contact lenses. In case of contact with eyes, rinse immediately with plenty of
Eye Contact
water. Seek medical attention.
: After contact with skin, wash immediately with plenty of water. If irritation persists, seek medical attention.
Skin Contact
Inhalation : Allow the victim to rest in a well-ventilated area. If irritation persists, seek medical attention.
: Have conscious person drink several glasses of water or milk. INDUCE VOMITING by sticking finger in
Ingestion
throat. Seek medical attention.
5. Fire Fighting Measures
: Non-flammable.
Flammability of the
Product
: Not available.
Auto-Ignition
Temperature
: carbon oxides (CO, CO2) nitrogen oxides (NO, NO2...) sulfur oxides (SO2, SO3...) sulfur oxides (SO2,
Hazardous thermal
SO3...) Phosphorus oxides
(de)composition
products
: Not considered to be flammable.
Fire Hazards in
Presence of Various
Substances
: Risks of explosion of the product in presence of mechanical impact: Not available.
Explosion Hazards in
Risks of explosion of the product in presence of static discharge: Not available.
Presence of Various
Substances
: Use DRY chemicals, CO2, water spray or foam.
Fire Fighting Media
and Instructions
: Be sure to use an approved/certified respirator or equivalent.
Protective Clothing
(Fire)
: May emit toxic fumes under fire conditions.
Special Remarks on
Fire Hazards
6. Accidental Release Measures
: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste
Small Spill and Leak
disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of
according to local and regional authority requirements.
: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish
Large Spill and Leak
cleaning by spreading water on the contaminated surface and dispose of according to local and regional
authority requirements.
7. Handling and Storage
: Do not ingest. Avoid contact with eyes, skin, and clothing. Ventilation is normally required when handling
Handling
or using this product. Wash thoroughly after handling.
Storage : Store at room temperature 25癈 (77癋) or lower. Prevent from freezing
8. Exposure Controls, Personal Protection
: Use good general ventilation(>10 air changes/hour) and engineering controls (local exhaust, filter's,
Engineering Controls
process enclosures if necessary) to maintain airborne levels below ACGIH Threshold Limit Values (TLV)
and OSHA Permissible Exposure Limits(PEL). Ensure that eyewash station and safety shower is proximal
to the work-station location.
Personal Protection
Eyes : Splash goggles.
Body : Lab coat.
Respiratory : Wear appropriate respirator when ventilation is inadequate.
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Guardian Plate Finisher
Hands : Gloves (impervious).
Feet : Not applicable.
:
Protective Clothing
(Pictograms)
: Splash goggles. Lab coat. Gloves (impervious). Ventilation is normally required when handling or using
Personal Protection in
this product (typically 10 air changes per hour).
Case of a Large Spill
Exposure Limits
Product Name
Not available.
1) Water
Not available.
2) Sodium hexametaphosphate
Not available.
3) Polyvinyl pyrrolidon
TWA: 10 (mg/m3)
4) Glycerol
Not available.
5) Sodium citrate
Consult local authorities for acceptable exposure limits.
9. Physical and Chemical Properties
: Liquid. : Not available.
Physical State and Odor
Appearance
: Not applicable.
Molecular Weight
: Colorless.
Color
: Not applicable.
Molecular Formula
: 5.5 [Acidic.]
pH (1% Soln/Water)
: >100癈 (212癋)
Boiling/Condensation
Point
: <0癈 (32癋)
Melting/Freezing Point
: 1.05 (Water = 1)
Specific Gravity
Vapor Pressure : 2.4 kPa (@ 20癈)
: 0.6 (Air = 1)
Vapor Density
: 90 to 95% (w/w).
Volatility
:
VOC by EPA Method
24
: 47.94 g/l (0.4 lbs/Gal.).
VOC Calculated
: Not available.
Ionicity (in Water)
: See solubility in cold water
Dispersion Properties
: Easily soluble in cold water
Solubility
10. Stability and Reactivity
Stability and Reactivity The product is stable.
:
Conditions of Instability : Not available.
Incompatibility with strong oxidising agents
:
Various Substances
Hazardous : carbon oxides (CO, CO2) nitrogen oxides (NO, NO2...) sulfur oxides (SO2, SO3...) sulfur oxides (SO2,
Decomposition Products SO3...) Phosphorus oxides
: Will not occur.
Hazardous
Polymerization
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Guardian Plate Finisher
11. Toxicological Information
: Water:
Toxicity to Animals
ORAL (LD50): Acute: >90000 mg/kg [Rat].
Sodium hexametaphosphate:
ORAL (LD50): Acute: 6200 mg/kg [Rat].
Polyvinyl pyrrolidon:
ORAL (LD50): Acute: 100000 mg/kg [Rat].
Glycerol:
ORAL (LD50): Acute: 12600 mg/kg [Rat].
Sodium hydrogen sulfate
LD50: Not available.
LC50: Not available.
Sodium citrate:
ORAL (LD50): Acute: 11700 mg/kg [Rat].
: CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Polyvinyl pyrrolidon].
Chronic Effects on
Humans
: Hazardous in case of ingestion.
Other Toxic Effects on
Slightly hazardous in case of skin contact (irritant), of inhalation.
Humans
12. Ecological Information
: Not available.
Ecotoxicity
: The product itself and its products of degradation are not toxic.
Toxicity of the Products
of Biodegradation
13. Disposal Considerations
: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Waste Information
Consult your local or regional authorities.
14. Transport Information
: Not a DOT controlled material (United States).
DOT Classification
Not applicable.
Not applicable.
Not applicable.
: Not regulated as a marine pollutant.
Marine Pollutant
: Not applicable.
Special Provisions for
Transport
: Not controlled under TDG (Canada).
TDG Classification
: Not controlled under ADR (Europe).
ADR/RID Classification
: Not controlled under IMDG.
IMO/IMDG
Classification Not applicable.
Not applicable.
Not applicable.
: Not controlled under IATA.
ICAO/IATA
Classification
Not applicable.
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Guardian Plate Finisher
Not applicable.
15. Regulatory Information
Not controlled under the HCS (United States).
:
HCS Classification
: TSCA 8(b) inventory: Water; Sodium hexametaphosphate; Polyvinyl pyrrolidon; Glycerol; Sodium
U.S. Federal Regulations
hydrogen sulfate; Sodium citrate
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Sodium
hexametaphosphate: immediate health hazard; Sodium hydrogen sulfate: immediate health hazard
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
International
Regulations
WHMIS : CLASS D-2B: Material causing other toxic effects (TOXIC).
(Canada)
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
CEPA DSL: Water; Sodium hexametaphosphate; Polyvinyl pyrrolidon; Glycerol; Sodium hydrogen sulfate;
Sodium citrate
:
DSCL (EEC) This product is not classified according to the EU regulations.
:
International WGK 1
Lists
:
State Regulations Pennsylvania RTK: All required components of this product are identified
Massachusetts RTK: All required components of this product are identified
New Jersey: All required components of this product are identified
California prop. 65: WARNING!. This product may contain chemicals known to the state of California to
cause cancer (<1 ppm arsenc,, lead) or reproductive toxicity (<1 ppm lead).
16. Other Information
: MAY CAUSE EYE AND SKIN IRRITATION.
Label Requirements
Hazardous Material : * 1 National Fire
Health
Fire Hazard
0
Information System 0 Protection
Fire Hazard
(U.S.A.) Association (U.S.A.) 1 0
Health Reactivity
0
Reactivity
Specific Hazard
B
Personal Protection
: Not available.
References
: Not available.
Other Special
Considerations
Validated by Kodak Polychrome Graphics on 2000-09-06. Verified by Kodak Polychrome Graphics.
Printed 2000-09-06.
In Case of Emergency CALL 1-800-451-8346
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be
used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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