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MSDS Material Safety Data Sheet
CAS

5466-77-3

File Name: 5466-77.asp

Safety data sheet


Page: 1/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 29.01.2008 Version: 1.2
Product: Uvinul* MC 80
(30055079/SDS_COS_EU/EN)
Date of print 27.02.2008




1. Substance/preparation and company identification

Uvinul* MC 80
Use: cosmetic ingredient


Company:
BASF SE
67056 Ludwigshafen
GERMANY
Care Chemicals
Telephone: +49 621 60-28444
Telefax number: +49 621 60-28189
E-mail address: EM-Masterdata@basf.com

Emergency information:
Telephone: +49 180 2273-112
Telefax number: +49 621 60-92664



2. Hazard identification
No particular hazards known.



3. Composition/information on ingredients

Chemical nature

INCI Name: Ethylhexyl Methoxycinnamate

2-ethylhexyl 4-methoxycinnamate
CAS Number: 5466-77-3
EC-Number: 226-775-7
Page: 2/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 29.01.2008 Version: 1.2
Product: Uvinul* MC 80
(30055079/SDS_COS_EU/EN)
Date of print 27.02.2008



4. First-aid measures

General advice:
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:
Rinse mouth and then drink plenty of water.

Note to physician:
Treatment: Symptomatic treatment (decontamination, vital functions).


5. Fire-fighting measures

Suitable extinguishing media:
carbon dioxide, dry extinguishing media, foam

Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.



6. Accidental release measures
Personal precautions:
Ensure adequate ventilation.

Environmental precautions:
Do not empty into drains.

Methods for cleaning up or taking up:
For large amounts: Dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material.
Dispose of absorbed material in accordance with regulations.
Page: 3/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 29.01.2008 Version: 1.2
Product: Uvinul* MC 80
(30055079/SDS_COS_EU/EN)
Date of print 27.02.2008



7. Handling and storage

Handling
Ensure thorough ventilation of stores and work areas. Sealed containers should be protected against
heat as this results in pressure build-up.

Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy. If exposed to fire, keep containers cool by spraying with water.

Storage
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Keep in a cool place away from heat sources. Keep container in a well-ventilated place.


8. Exposure controls and personal protection


Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Gas filter for gases/vapours of organic
compounds (boiling point >65 癈, e. g. EN 14387 Type A)

Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice.



9. Physical and chemical properties

Form: liquid
Colour: slightly yellow
Odour: almost odourless

pH value: approx. 7

solidification temperature: < -25 癈
Page: 4/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 29.01.2008 Version: 1.2
Product: Uvinul* MC 80
(30055079/SDS_COS_EU/EN)
Date of print 27.02.2008


Boiling range: 198 - 200 癈
(4 mbar)

Flash point: 114 癈

Vapour pressure: approx. 4 mbar
(200 癈)

Density: 1.008 - 1.014 g/cm3
(20 癈)

Solubility (qualitative) solvent(s): organic solvents
soluble
Partitioning coefficient n-octanol/water (log Pow): 5.8 (calculated)
(25 癈)



10. Stability and reactivity
Conditions to avoid:
Avoid sources of ignition.

Hazardous reactions:
No hazardous reactions if stored and handled as prescribed/indicated.


Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.


11. Toxicological information

Acute toxicity

Assessment of acute toxicity:
Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact.

LD50 rat (oral): > 5,000 mg/kg (BASF-Test)

LD50 rat (dermal): > 5,000 mg/kg
Literature data.

Irritation

Assessment of irritating effects:
Not irritating to the skin. Not irritating to the eyes.

Primary skin irritation rabbit: non-irritant (Draize test)

Primary irritations of the mucous membrane rabbit: non-irritant (Draize test)

Sensitization
Page: 5/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 29.01.2008 Version: 1.2
Product: Uvinul* MC 80
(30055079/SDS_COS_EU/EN)
Date of print 27.02.2008



Assessment of sensitization:
Skin sensitizing effects were not observed in animal studies.

Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406)

Genetic toxicity

Assessment of mutagenicity:
No mutagenic effect was found in various tests with bacteria, microorganims and mammalian cell
culture. The substance was not mutagenic in studies with mammals.

Reproductive toxicity

Assessment of reproduction toxicity:
Repeated oral uptake of the substance did not cause damage to the reproductive organs.

Developmental toxicity

Assessment of teratogenicity:
No indications of a developmental toxic / teratogenic effect were seen in animal studies.


12. Ecological information

Ecotoxicity

Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms. No toxic
effects occur within the range of solubility. The inhibition of the degradation activity of activated
sludge is not anticipated when introduced to biological treatment plants in appropriate low
concentrations.

Toxicity to fish:
LC50 (96 h) 1,216.1 mg/l, Brachydanio rerio (OECD Guideline 203, static)
Tested above maximum solubility. The statement of the toxic effect relates to the analytically
determined concentration. No toxic effects occur within the range of solubility.

Aquatic invertebrates:
EC50 (48 h) > 0.0271 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)
The statement of the toxic effect relates to the analytically determined concentration. The product
has low solubility in the test medium. An eluate has been tested. No toxic effects occur within the
range of solubility.

Aquatic plants:
EC50 (72 h) > 100 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static)
The details of the toxic effect relate to the nominal concentration. No toxic effects occur within the
range of solubility.

Microorganisms/Effect on activated sludge:
EC10 (16 h) > 10,000 mg/l, Pseudomonas putida (DIN EN ISO 10712, aerobic)
The details of the toxic effect relate to the nominal concentration. The product has low solubility in
the test medium. An eluate has been tested. No toxic effects occur within the range of solubility.
Page: 6/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 29.01.2008 Version: 1.2
Product: Uvinul* MC 80
(30055079/SDS_COS_EU/EN)
Date of print 27.02.2008



EC20 (30 min) > 1,000 mg/l, activated sludge, domestic (DIN EN ISO 8192-OECD 209-
88/302/EEC,P. C, aerobic)

Persistence and degradability

Assessment biodegradation and elimination (H2O):
Readily biodegradable (according to OECD criteria).

Elimination information:
70 - 80 % BOD of the ThOD (28 d) (OECD Guideline 301 F) (aerobic, activated sludge, domestic,
non-adapted)

Bioaccumulation potential

Bioaccumulation potential:
Accumulation in organisms is expected.


13. Disposal considerations

Observe national and local legal requirements.



14. Transport information

Land transport

ADR
Not classified as a dangerous good under transport regulations

RID
Not classified as a dangerous good under transport regulations


Inland waterway transport
ADNR
Not classified as a dangerous good under transport regulations



Sea transport
IMDG
Not classified as a dangerous good under transport regulations



Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
Page: 7/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 29.01.2008 Version: 1.2
Product: Uvinul* MC 80
(30055079/SDS_COS_EU/EN)
Date of print 27.02.2008




15. Regulatory information

Regulations of the European union (Labelling) / National legislation/Regulations

The product does not require a hazard warning label in accordance with EC Directives.

Other regulations


16. Other information


Vertical lines in the left hand margin indicate an amendment from the previous version.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.

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