Page 1/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 28.09.2009
* 1 Identification of substance:
?Product details:
?Trade name: Supergel + Dispenser Pump 5L
?Article number: V2179
?Application of the substance / the preparation Hand cleaning agent
?Manufacturer/Supplier:
Barnes Group KENT Limited
Pitreavie Crescent
Pitreavie Business Park
Dunfermline
Fife
KY11 8UQ
Tel: 01383 737393
Fax: 01383 620079
Monday - Thursday 8.30am - 5.30pm, Friday 9.00am - 3.00pm
?Informing department: Product Safety Department
?Emergency information: fullertonj@kenteurope.com
* 2 Hazards identification
?Hazard designation: Not applicable.
?Information pertaining to particular dangers for man and environment
The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of
the EU" in the latest valid version.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information
furnished by supplier companies.
?GHS label elements
Contains chloroxylenol. May produce an allergic reaction.
* 3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
Aqua >40%
Polyethylene beads <5%
CAS: 8051-30-7 Coco amide <5%
CAS: 8028-48-6 Orange Terpenes <5%
EINECS: 232-433-8 ? Xi, ? N; R 10-38-50/53
@
G @
D
Warning: ~ 2.6/3; ~ 4.1.C/1; ~ 3.2/2
CAS: 68439-45-2 Alcohol Ethoxylate Surfactant <5%
@
? Xi; R 36/38
G
Warning: ~ 3.2/2, 3.3/2
CAS: 1119-40-0 dimethyl glutarate <2%
EINECS: 214-277-2
CAS: 106-65-0 dimethyl succinate <2%
EINECS: 203-419-9
CAS: 627-93-0 dimethyl adipate <2%
EINECS: 211-020-6
CAS: 4722-98-9 Monoethanolaimine lauryl suphate <2%
Carbomer <2%
CAS: 61790-81-6 Peg 75 Lanolin <5%
(Contd. on page 2)
GB
Page 2/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 28.09.2009
Trade name: Supergel + Dispenser Pump 5L
(Contd. of page 1)
CAS: 1321-23-9 chloroxylenol <0.5%
EINECS: 215-316-6 ? Xn, ? Xi; R 22-36/38-43
@
G @
G
Warning: ~ 3.1.O/4, 3.2/2, 3.3/2, 3.4.S/1
CAS: 141-43-5 ethanolamine <1%
EINECS: 205-483-3 ? C, ? Xn; R 20/21/22-34
@
A G
@
Danger: ~ 3.2/1B
Warning: ~ 3.1.O/4, 3.1.D/4, 3.1.I/4
CAS: 122-99-6 2-Phenoxyethanol <1%
EINECS: 204-589-7 ? Xn, ? Xi; R 22-36
@
G @
G
Warning: ~ 3.1.O/4, 3.3/2
CAS: 52-51-7 bronopol (INN) <1%
EINECS: 200-143-0 ? Xn, ? Xi, ? N; R 21/22-37/38-41-50
G
@ @
G D
@
Danger: ~ 3.3/1
Warning: ~ 4.1.A/1; ~ 3.1.O/4, 3.1.D/4, 3.8/3; 3.2/2
CAS: 99-76-3 methyl 4-hydroxybenzoate <1%
EINECS: 202-785-7
CAS: 94-13-3 propyl 4-hydroxybenzoate <1%
EINECS: 202-307-7
?????????????????????????????????????????????? <1%
?Additional information For the wording of the listed risk phrases refer to section 16.
* 4 First aid measures
?After skin contact Rinse with warm water.
?After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
?After swallowing
Do not induce vomiting; instantly call for medical help.
Rinse out mouth and then drink plenty of water.
5 Fire fighting measures
?Suitable extinguishing agents
CO2, extinguishing powder or water haze. Fight larger fires with water haze or alcohol-resistant foam.
?Special hazards caused by the material, its products of combustion or resulting gases:
Carbon monoxide and carbon dioxide
?Protective equipment: Do not inhale explosion gases or combustion gases.
6 Accidental release measures
?Person-related safety precautions: Particular danger of slipping on leaked/spilled product.
?Measures for environmental protection:
Inform respective authorities in case product reaches water or sewage system.
Do not allow to enter drainage system, surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
?Additional information: No dangerous materials are released.
* 7 Handling and storage
?Handling
?Information for safe handling: Store in cool, dry place in tightly closed containers.
?Information about protection against explosions and fires: No special measures required.
?Storage
?Requirements to be met by storerooms and containers: Store in cool location.
?Information about storage in one common storage facility: Not required.
(Contd. on page 3)
GB
Page 3/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 28.09.2009
Trade name: Supergel + Dispenser Pump 5L
(Contd. of page 2)
?Further information about storage conditions:
Store in cool, dry conditions in well sealed containers.
Protect from heat and direct sunlight.
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Take off immediately all contaminated clothing
Avoid contact with the eyes.
Do not eat, drink or smoke while working.
?Breathing equipment: Not required.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
?Eye protection: Safety glasses
* 9 Physical and chemical properties:
?General Information
Form: Fluid
Viscous
Colour: Yellow
Odour: Fruit-like
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
?Flash point: Not applicable
?Self-inflammability: Product is not selfigniting.
?Danger of explosion: Product is not explosive.
?Density at 20癈 0.99 g/cm?br>
?Solubility in / Miscibility with
Water: Soluble
?pH-value at 20癈: <10
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Materials to be avoided: Strong oxidising agents
?Dangerous reactions No dangerous reactions known
(Contd. on page 4)
GB
Page 4/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 28.09.2009
Trade name: Supergel + Dispenser Pump 5L
(Contd. of page 3)
?Dangerous products of decomposition: Carbon monoxide and carbon dioxide
11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
ethanolamine
Oral LD50 2050 mg/kg (rat)
Dermal LD50 1000 mg/kg (rabbit)
bronopol (INN)
Oral LD50 305 mg/kg (rat)
methyl 4-hydroxybenzoate
Oral LD50 2280 mg/kg (rat)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritant effect.
?Sensitization: Sensitization possible by skin contact.
?Additional toxicological information:
The product is not subject to classification according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
When used and handled according to specifications, the product does not have any harmful effects according to our experience and
the information provided to us.
* 12 Ecological information:
?Additional ecological information:
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
?Product:
?Recommendation
Can be deposited with household garbage after consulting with the operator of the waste disposal facility and the pertinent
authorities and under adherence to the necessary technical regulations.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: n/a
?Maritime transport IMDG:
?IMDG Class: n/a
?Marine pollutant: No
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: n/a
?UN "Model Regulation": n/a
GB
(Contd. on page 5)
Page 5/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 28.09.2009
Trade name: Supergel + Dispenser Pump 5L
(Contd. of page 4)
* 15 Regulatory information
?Designation according to EC guidelines:
Observe the normal safety regulations when handling chemicals
The product is not subject to identification regulations under EC Directives and the Ordinance on Hazardous Materials (GefStoffV).
?Safety phrases:
25 Avoid contact with eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
?Special designation of certain preparations:
Contains chloroxylenol. May produce an allergic reaction.
?National regulations
?Technical instructions (air):
Class Share in %
Water 35.0
NK 6.8
?Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
21/22 Harmful in contact with skin and if swallowed.
22 Harmful if swallowed.
34 Causes burns.
36 Irritating to eyes.
36/38 Irritating to eyes and skin.
37/38 Irritating to respiratory system and skin.
38 Irritating to skin.
41 Risk of serious damage to eyes.
43 May cause sensitisation by skin contact.
50 Very toxic to aquatic organisms.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Department issuing data specification sheet: Environment protection department
?Contact: Marketing Department
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous
Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
GB
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