Page : 1
MATERIAL SAFETY DATA SHEET Revised edition no : 4
According to Regulation (EC) 1907/ Date : 14 / 7 / 2009
2006 Supersedes : 29 / 3 / 2006
Delicate 31106246
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY
: Delicate
Trade name
: Liquid detergent.
Type of product
: Domestic.
Use
: ECOVER BELGIUM NV
Company identification
Industrieweg 3
2390 Malle Belgique-Belgie
: sds@ecover.com
e-mail:
: +32 (0)3 309 25 00
Phone
: +32 (0)3 311 72 70
Fax
: +32 (0)70 245 245 (Antipoison Centre Belgium)
Emergency phone nr
: See address above.
Responsible for placing on the
market
:-
-
2. HAZARDS IDENTIFICATION
: Not classified as dangerous product.
Hazards identification
Symptoms relating to use
: None under normal conditions.
- Inhalation
: Not expected to present a significant skin hazard under anticipated conditions of
- Skin contact
normal use.
Prolonged or repeated contact may cause skin to become dry.
: Not expected to present a significant eye contact hazard under anticipated
- Eye contact
conditions of normal use.
: Harmful if swallowed. Abdominal pain. Nausea.
- Ingestion
Vomiting.
3. COMPOSITION / INFORMATION ON INGREDIENTS
: Preparation.
Substance / Preparation
: This product is not hazardous but contains hazardous components.
Components
: Regulation (CE) No. 648/2004 of 31 March 2004 on detergents:
Composition
< 5% : - Nonionic surfactants - Soap
5% - 15% : - Anionic surfactants
Perfumes
LIMONENE.
2-BROMO-2-NITROPROPANE-1,3-DIOL
Substance name Contents CAS No EC No Index No Classification
Sodium Lauryl Ether Sulfate : Between 5 and 15 % 68891-38-3 POLYMER ----- Xi; R38-41
Soap : Between 1 and 5 % ----- ----- ----- Xi; R36
Alkyl Poly Glycoside C10-16 : Between 1 and 5 % 110615-47-9 POLYMER ----- Xi; R38-41
Sodium octyl sulfate : Between 0.1 and 1 % 142-31-4 205-535-5 ----- Xi; R38-41
Perfume : Between 0.01 and 0.1 % ----- ----- ----- R10
Xn; R65
Xi; R38
R43
N; R50-53
Limonene (D-) : Between 0.01 and 0.1 % 5989-27-5 227-813-5 601-029-00-7 R10
Xi; R38
R43
N; R50-53
ECOVER BELGIUM NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgique-Belgie
Page : 2
MATERIAL SAFETY DATA SHEET Revised edition no : 4
According to Regulation (EC) 1907/ Date : 14 / 7 / 2009
2006 Supersedes : 29 / 3 / 2006
Delicate 31106246
3. COMPOSITION / INFORMATION ON INGREDIENTS (continued)
Substance name Contents CAS No EC No Index No Classification
2-bromo-2-nitropropane-1,3-diol : Between 0.01 and 0.1 % 52-51-7 200-143-0 603-085-00-8 Xn; R21/22
Xi; R37/38-41
N; R50
: SODIUM LAURETH SULFATE
INCI
POTASSIUM COCOATE
LAURYL GLUCOSIDE
Sodium octyl sulfate
PARFUM
LIMONENE
2-BROMO-2-NITROPROPANE-1,3-DIOL
4. FIRST AID MEASURES
First aid measures
: Not relevant.
- Inhalation
: Rinse immediately with plenty of water.
- Skin contact
: Rinse immediately with plenty of water.
- Eye contact
: Drink promptly large quantities of milk, egg whites, gelatin solutions, or if these are
- Ingestion
not available, drink large quantities of water.
Do not induce vomiting.
: Treat symptomatically.
Note to physician
: No specific recommendations.
Workplace equipment
5. FIRE-FIGHTING MEASURES
: None.
Specific hazards
Extinguishing media
: All extinguishing media can be used.
- Suitable extinguishing media
: None.
- Unsuitable extinguishing media
: Exercise caution when fighting any chemical fire.
Protection against fire
See Heading 8.
6. ACCIDENTAL RELEASE MEASURES
: Spill area may be slippery.
Personal precautions
Equip cleanup crew with proper protection.
See Heading 8.
: Avoid release to the environment.
Environmental precautions
: Recover usable material in a clean closable container for reuse. Sweep up
Clean up methods
contaminated material and dispose of as chemical waste. Remove the remainder
with water.
7. HANDLING AND STORAGE
: Not expected to be a fire/explosion hazard under normal conditions of use.
Protection against fire
: Store in a cool and frost-free place.
Storage
: Wear waterproof gloves in case of frequent contact with undiluted product.
Handling
ECOVER BELGIUM NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgique-Belgie
Page : 3
MATERIAL SAFETY DATA SHEET Revised edition no : 4
According to Regulation (EC) 1907/ Date : 14 / 7 / 2009
2006 Supersedes : 29 / 3 / 2006
Delicate 31106246
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection
: No special clothing/skin protection equipment is recommended under normal
- Skin protection
conditions of use.
Wear waterproof gloves (preferably neoprene or nitrile rubber) in case of intensive
use or contact with undiluted product.
: Wear safety goggles when clearing accidentally released material and if there is a
- Eye protection
risk of splashing.
: Not relevant.
- Respiratory protection
Environment protection see ?6
9. PHYSICAL AND CHEMICAL PROPERTIES
: Liquid.
Physical state at 20 癈
: Slightly yellow.
Colour
: Citrus fruits.
Odour
: 8.25
pH value (concentrated product)
: 1,03 kg/l
Density
: 578 cP
Viscosity
: Complete.
Solubility in water
: > 100
Flash point [癈]
: 0.08
Volatile Organic Compounds (%)
: No data available.
Explosion limits
: None.
Oxidising properties
10. STABILITY AND REACTIVITY
: No decomposition under normal conditions of storage and use.
Stability and reactivity
: Do not store <0癈 and >40癈.
Conditions to avoid
: None.
Materials to avoid
: None under normal conditions.
Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
: 21.6
Eye irritatie (RBC test: Mean Indices
Ocular Irritancy)
: 49.5% (Sodiumdodecylsulphate= 100%)
Skin irritation (RBC test: Denaturation
Index)
Evaluation of the security for the
human health
: Not or only slightly irritant due to the composition.
- Dermal
: Not or only slightly irritant due to the composition.
- Ocular
: Hardly toxic (LD 50 rat-oral-theoretical 5000-15000 ppm).
- Ingestion
: This product contains sensitizing fragrance components > 100 ppm: see ?2 and
Sensitization
15.
: Contains only ELINCS or EINECS registered raw materials and does not contain
Note
any ingredients known to be mutagenic, carcinogenic, teratogenic or reproduction
toxic (R45,46,47,49,60,61,63,64, EU 97/C234, 67/548/EEC, 88/379/EEC, OSHA,
NTP, IARC/ARAB (cat 1-3)).
ECOVER BELGIUM NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgique-Belgie
Page : 4
MATERIAL SAFETY DATA SHEET Revised edition no : 4
According to Regulation (EC) 1907/ Date : 14 / 7 / 2009
2006 Supersedes : 29 / 3 / 2006
Delicate 31106246
12. ECOLOGICAL INFORMATION
Ecological effects information
: 97.1 Biodegradable.
Biodegradation [%] Sapromat
respirometry test (OECD 301 F)
: 84 Biodegradable.
Biodegradation: Coupled Unit test (
OECD 303A) %
: 500.5 Hardly toxic.
EC50 72h Algae (Selenastrum
capricornutum) [ppm] (OECD 201)
: 61.8 Slightly toxic
48 Hour EC50 Daphnia magna [ppm]
(OECD 202)
: Ecover products do not contain any bioaccumulating raw materials and no PCM or
Remarks
nitromusk perfume components. The surface active components used in this
product fulfill all of the biodegradability requirements of EC regulation 648/2004.
13. DISPOSAL CONSIDERATIONS
: Waste of this product is considered chemical waste. The legislation concerning
Product
disposal of waste can differ from one country/state to another. The disposal should
therefore be done according to national or local waste legislation. If in doubt, ask
the local waste management authority for advice (also see ?6 and ?8 when
disposing of).
: The empty packaging of this product is not subject to ADR. Cleaned empty
Packaging
packaging (including labels and caps) is fully recycable (HDPE + PP); they may be
collected selectively for recycling according to national or local waste legislation.
Uncleaned packaging should be disposed of as chemical waste.
14. TRANSPORT INFORMATION
: Not classified.
General information
15. REGULATORY INFORMATION
: None.
Symbol(s)
: None.
R Phrase(s)
: S2 : Keep out of the reach of children.
S Phrase(s)
: < 5% : - Nonionic surfactants - Soap
EEC Composition of detergents
5% - 15% : - Anionic surfactants
Perfumes
2-BROMO-2-NITROPROPANE-1,3-DIOL.
LIMONENE.
16. OTHER INFORMATION
: For correct use of this product: see Technical Data Sheet.
Training advice
List of relevant R phrases (heading 3) : R10 : Flammable.
R21/22 : Harmful in contact with skin and if swallowed.
R36 : Irritating to eyes.
R37/38 : Irritating to respiratory system and skin.
R38 : Irritating to skin.
R41 : Risk of serious damage to eyes.
R43 : May cause sensitization by skin contact.
R50 : Very toxic to aquatic organisms.
ECOVER BELGIUM NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgique-Belgie
Page : 5
MATERIAL SAFETY DATA SHEET Revised edition no : 4
According to Regulation (EC) 1907/ Date : 14 / 7 / 2009
2006 Supersedes : 29 / 3 / 2006
Delicate 31106246
16. OTHER INFORMATION (continued)
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65 : Harmful : may cause lung damage if swallowed.
: Gloxhuber C, K黱stler K, 1992. Anionic Surfactants, Surfactant Science Series 43,
Sources of key data used
ed M.Dekker.
MSDS and additional literature data of the respective suppliers.
Chemical cards, 12th edition, 1997, ed. MIA, VMCI, Samson
Comprehensive guide to chemical resistant best gloves for various amounts of
exposure, 1999, ver.3.5 www
: First version of this MSDS in this new format.
Revision
: 14 / 7 / 2009
Print date
The contents and format of this SDS are in accordance with Regulation (EC) No 1907/2006
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other
reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way
connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this
product. If the product is used as a component in another product, this MSDS information may not be applicable.
End of document
ECOVER BELGIUM NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgique-Belgie
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