Section l Product Information/Preparation Information
Identity: SupremeGreen Toss-Ins Product Use: Holding tank deodorant
Manufacturer's Name Emergency Telephone Number
Thetford Corporation (734) 769-6000; (800) 424-9300 (CHEMTREC-24 hrs)
Address Telephone Number for Information (734) 769-6000
7101 Jackson Road
Date Prepared Prepared By Janis M. Thomson
Ann Arbor, Michigan 48103 26-Aug-05
Section ll - Hazardous Ingredients/Identity Information
Hazardous Components CAS # OSHA PEL ACGIH Other Limits
Bronopol 52-51-7 None established
Sodium chloride 7647-14-5 None established
5 mg/m3 dust
Silicon Dioxide 112926-00-8
Section III - Hazards Identification and Toxological Information
Emergency Overview:
Warning! Corrosive to the skin. Toxic if ingested. Causes eye irritation.
Route(s) of Entry:
Inhalation: Not an inhalation hazard.
Skin Contact: Corrosive.
Eye contact: Causes irritation - redness and swelling.
Ingestion: Toxic. Elevated blood pressure if ingested.
Chronic effects:
Carcinogenicity: Not carcinogenic.
Teratogenicity: Not teratogenic.
Mutagenicity: Not mutagenic.
Sensitization to Material: None known.
Synergistic materials: Surfactants cause the product to become toxic by ingestion.
LD50: >50 mg/kg (oral, rat) LC50:
Toxological Information:
LD50: LC50:
Section IV - First Aid Procedures:
Inhalation: Not applicable.
Ingestion: Do not induce vomiting. Drink 2 glasses of water. Get medical attention immediately.
Skin: Flush contacted area with large amounts of water. Wash with soap and water. Wash clothing before reuse.
Eyes: Flush contacted area with large amounts of water. Irrigate eyes for a minimum of 15 minutes. Get medical attention
immediately.
Section V - Fire and Explosion Hazard Data
Flash Point (Method used) Flammable Limits by Volume LEL UEL
Not below 200癋 (93癈) N/A N/A N/A
Extinguishing Media Hazardous Combustion Products
Water, dry chemical, carbon dioxide or foam Formaldehyde, bromine, oxides of carbon and nitrogen
Special Fire fighting Procedures Auto-ignition Temperature Sensitivity to Static Discharge
None. Not available Not available
Unusual Fire and Explosion Hazards Conditions of Flammability
None Not flammable
Explosion Data Sensitivity to Mechanical Impact
None Not available
Material Safety Data Sheet - Form Number: 50042 PAGE 2
Section VI - Personal Protective Equipment
Respiratory Protection:
Not required.
Engineering Controls:
Maintain adequate ventilation.
Protective Gloves: Eye Protection:
Rubber gloves. Safety glasses or safety goggles.
Other Protective Clothing or Equipment:
Protective clothing to avoid skin contact. Eyewash station and safety shower.
Work/Hygienic Practices
Avoid unnecessary contact. Avoid breathing dust. Wash thoroughly after handling.
Section Vll - Accidental Release Measures/Preventative Measures
Steps to be Taken in Case Material is Released or Spilled:
Minimize dusting and prevent distribution of airborne dust. Sweep up and collect in suitable containers. Mop area with plenty of clean, cold
water.
Waste Disposal Method
Dispose of in accordance with federal, state and local regulations.
Precautions to be Taken in Handling and Storing
Do not store above 100?F (38癈). Keep container closed when not in use.
Other Precautions
Avoid skin contact and/or inhalation of dust. Do not get in eyes. Wash thoroughly after handling.
Section Vlll - Physical/Chemical Characteristics
Boiling Point Specific Gravity (H20 = 1) Physical State
Not applicable Solid
Not applicable
Vapor Pressure (mm Hg) Melting Point Odor Threshold
Not determined
Not determined Not applicable
Vapor Density (AIR = 1) Evaporation Rate (Butyl Acetate = 1) Freezing Point
Not determined Not established None
Not determined
Solubility in Water pH Coeff. Water/Oil Dist.
93% 10% solution 6 - 7.5 Not determined
Appearance and Odor
Green powder with pine odor
Section IX - Reactivity Hazards
Stability Hazardous Polymerization
Stable May Occur
X
Unstable Will Not Occur
X
Incompatibility (Materials to Avoid)
Alkalis, amines, metal
Hazardous Decomposition or Byproducts
Thermal decomposition may produce formaldehyde, bromine, oxides of carbon and nitrogen
Conditions to Avoid
Elevated temperatures
Section XI - Shipping Information
Transportation Status: Proper Shipping Name: Class:
ORM D
US DOT: Consumer Commodity
Regulated
Canadian TDG: Regulated ORM D
Consumer Commodity
Regulated under other modes of transportation as UN2923 limited quantities. Consult the individual regulations, IATA via air, IMDG via water
and TDG in Canada, for shipping information.