HALOX 310
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
HALOX
MANUFACTURED BY:
1326 Summer Street
Hammond, IN 46320-2240
PRODUCT NAME: HALOX 310
Phone: 219-933-1560 (US Central) M-F 8:00 am - 5:00 pm
Emergency Phone: 219-845-0031
Chemtrec: 1-800-424-9300
Product Use: Corrosion inhibiting pigment, commonly used in the production of protective coating systems.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components % Composition ACGIH TLV: ACGIH STEL: OSHA PEL: OSHA TWA/STEL Units
STEL: are in:
mg/m3
Barium Carbonate 2.5 - 10% 0.5 (Ba) NE 0.5 (Ba) NE
513-77-9
EXPOSURE LIMIT STATEMENT
NE - None established
Ba - soluble compounds, as Ba
HMIS
1
HEALTH:
0
FLAMMABILITY:
0
REACTIVITY:
*
PERSONAL PROTECTION:
* Recommended personal protective measures are identified in Section 8.0 of this document.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
Spill materials and associated run-off should not be allowed to reach waterways.
This material is not flammable. However, if involved in a fire, may emit toxic fumes.
This material is a white, odorless powder.
Excessive airborne concentrations may obscure vision and present an inhalation and ingestion hazard.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT:
May cause moderate to severe irritation, inflammation of the mucous membranes, and tearing of the eyes.
SKIN CONTACT:
May cause irritation to skin through mechanical abrasion or physically irritating deposition.
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HALOX 310
INGESTION:
May cause irritation of gastrointestinal tract, nausea, and vomiting.
INHALATION:
May cause irritation to the upper respiratory tract, difficulty in breathing, nasal discharge, chest pain, wheezing and
coughing.
Routes of Exposure: Inhalation, ingestion, skin and eye contact.
POTENTIAL CHRONIC HEALTH EFFECTS:
Chronic exposures are considered negligible.
Medical conditions aggravated by exposure: Any pre-existing lung or pulmonary condition.
4. FIRST AID MEASURES
INHALATION:
Remove victim to fresh air. Restore breathing if necessary (AR, CPR). Seek medical attention if symptoms develop or
persist.
INGESTION:
If victim is alert, wash out mouth with water. Seek medical attention if symptoms develop or persist.
EYES:
Do not let victim rub eyes. Flush eyes well with water for at least 15 minutes. If irritation persists, seek medical attention.
SKIN:
Wash exposed area with soap and water. If irritation persists, seek medical attention.
5. FIRE FIGHTING MEASURES
FLASH POINT (?F) Not applicable.
OSHA FLAMMABILITY CLASSIFICATION: Not Applicable.
EXTINGUISHING MEDIA: This material is not flammable and will not react with commercially available extinguishing
media. Use appropriate media for surrounding fire.
SPECIAL FIREFIGHTING PROCEDURES: Firefighters should wear a positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing.
AUTOIGNITION TEMP (?F) Unknown
UNUSUAL FIRE AND EXPLOSION HAZARDS: None.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Always wear recommended personal protective equipment. The spill should first be contained and the area should be
cleaned by wet-sweeping or vacuum cleaning (HEPA filter). Limit foot and vehicular traffic to minimize mechanical
agitation and dispersion. Notify In-plant Spill Response Coordinator or appropriate party to determine any additional
requirements pertaining to spill response.
CONTAINMENT TECHNIQUES: This is a solid material and will not travel far from the spill location unless mechanically
agitated. Therefore, no specific containment techniques are recommended outside of restricting access to the spill
location.
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HALOX 310
SPILL RESPONSE EQUIPMENT:
?Vacuum, equipped with HEPA filter
?Broom, wet mop
?Dustpan, shovel or scoop
?Bags, drums or sacks for collection
SPILL RESPONSE PERSONAL PROTECTIVE EQUIPMENT:
?Chemical/safety impact goggles
?Rubber or leather gloves
?Cotton overalls
?If airborne concentrations cannot be controlled below the required or recommended exposure limits, respiratory
equipment, as per Section 8.0, may be required.
7. HANDLING AND STORAGE
HANDLING:
Always wear recommended personal protective equipment. Avoid dust generation.
STORAGE:
Store in a cool, dry, well-ventilated area away from sources of ignition. Keep containers tightly closed when not in use.
Use care when handling and storing containers to prevent damage.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: General mechanical ventilation is acceptable, as long as concentrations are maintained
below required/recommended limits. Where acceptable concentrations cannot be maintained by general mechanical
ventilation, local exhaust ventilation is recommended.
RESPIRATORY PROTECTION EQUIPMENT: NIOSH/MSHA approved respiratory protection is recommended for use in
airborne concentrations exceeding exposure limits identified in section 2. Where no required/recommended exposure
limits exist, personal protection measures should be incorporated when potential airborne concentrations may exceed 10
mg/m^3 total dust and 3 mg/m^3 respirable dust (particulate containing no asbestos and <1% crystalline silica).
PROTECTIVE GLOVES: Rubber or leather gloves and cotton coveralls are recommended to prevent direct skin contact.
EYE AND FACE PROTECTION: Wear safety glasses or goggles to protect against exposure.
OTHER PROTECTIVE EQUIPMENT: An emergency eye wash is recommended in the work area and should, at a
minimum, meet the requirements under ANSI Z.358.1 for location, design, and operation.
9. PHYSICAL AND CHEMICAL PROPERTIES
None established
Boiling Range/Point
None established
Freezing Point
Not applicable
Melting Point
Not applicable
Vapor Pressure
Not applicable
Vapor Density (AIR=1)
Powder
Physical State
White
Color
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HALOX 310
Not applicable
Percent Moisture
<0.02g/100cm3
Solubility in Water
Not applicable
% Volatile by Weight
Not applicable
Evaporation Rate
(Butyl Acetate=1)
24.5 lb/gal
Density
8.5 - 9.0
pH*
2.95
Specific Gravity (water=1)
*at 10% slurry by weight in water.
10. STABILITY AND REACTIVITY
STABILITY: Stable.
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS THERMAL DECOMPOSITION/COMBUSTION PRODUCTS: Calcium oxides, silica fumes, sulfur oxides,
barium oxides, zinc oxides, carbon dioxide, and carbon monoxide.
INCOMPATIBILITY (MATERIALS TO AVOID): Acids, strong oxidizers.
CONDITIONS TO AVOID: Incompatible materials, excess heat.
11. TOXICOLOGICAL INFORMATION
This product contains wollastonite. Wollastonite is listed by IARC as a Group 3
TOXICITY DATA:
carcinogen. Therefore, there is inadequate evidence of its carcinogenicity in humans
and inadequate or limited evidence in experimental animals.
No data at this time.
ACUTE ORAL LD50 (mg/kg):
No data at this time.
ACUTE INHALATION LC50:
No data at this time.
ACUTE DERMAL LD50 (mg/kg):
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: No data at this time
CHEMICAL FATE INFORMATION: No data at this time.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Re-blend spilled, unused, off-specification materials with other materials, where possible, in
support of waste minimization. Where this is not possible, dispose of material according to Federal (country-specific),
state, and local requirements.
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HALOX 310
EMPTY CONTAINERS: This product may be shipped in paper or nylon bags, steel drums, plastic or steel pails, or
intermediate bulk containers. All residual material should be emptied and the containers recycled where possible. Where
recycling is not possible, all containers should be disposed of in accordance with Federal (country-specific), state, and
local requirements.
14. TRANSPORT INFORMATION
Not Regulated
DOT SHIPPING NAME:
Not Regulated
AIR FREIGHT
TRANSPORTATION:
Not Regulated
OCEAN TRANSPORTATION:
15. REGULATORY INFORMATION
TSCA STATUS:
All components of this product are on the US TSCA Inventory.
CALIFORNIA PROPOSITION 65:
This product is not known to contain any chemicals known to the state of California to cause cancer or birth defects.
However, we do not conduct routine analysis for all listed materials.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES LIST:
This product does not contain greater than 1.0% of any chemical substance on the SARA Extremely Hazardous
Substance List.
SARA (311, 312) HAZARD CLASS:
None
SARA SECTION 313 TOXIC CHEMICALS:
Barium Compounds
2-3%
Zinc Compounds
2-3%
CANADIAN INVENTORY:
All components are on the Domestic Substance List (DSL).
EINECS REGULATIONS:
All components are on the European Inventory of Existing Commercial Chemical Substances (EINECS).
KOREAN CHEMICAL INVENTORY:
All components are on the Korean List of Existing Chemical Substances.
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HALOX 310
16. OTHER INFORMATION
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES:
The information in this document is believed to be correct as of the date issued. However, no warranty of merchantability,
fitness for any particular purpose, or any other warranty is expressed or is to be implied regarding the accuracy or
completeness of this information, the results to be obtained from the use of this information or the product, the safety of
this product, or the hazards related to its use. This information and product are furnished on the condition that the person
receiving them shall make his own determination as to the suitability of the product for his particular purpose and on the
condition that he assume the risk of his use thereof.
17. LABEL INFORMATION
NOTICE
SIGNAL WORD:
May cause eye, skin, or respiratory irritation.
TARGET ORGANS:
Do not let victim rub eyes. Flush eyes well with water for at least 15 minutes. If
EYES:
irritation persists, seek medical attention.
Wash exposed area with soap and water. If irritation persists, seek medical attention.
SKIN:
If victim is alert, wash out mouth with water. Seek medical attention if symptoms
INGESTION:
develop or persist.
Remove victim to fresh air. Restore breathing if necessary (AR, CPR). Seek medical
INHALATION:
attention if symptoms develop or persist.
Always wear recommended personal protective equipment. Avoid contact with skin,
HANDLING:
eyes and clothing.
Store in a cool, dry, well-ventilated area away from sources of ignition. Keep
STORAGE:
containers tightly closed when not in use. Use care when handling and storing
containers to prevent damage.
Collect and dispose in accordance with federal, state and local regulations.
IN CASE OF SPILL:
This material is not flammable and will not react with commercially available
EXTINGUISHING MEDIA:
extinguishing media. Use appropriate media for surrounding fire.
This product is not known to contain any chemicals known to the state of California to
CALIFORNIA PROPOSITION 65:
cause cancer or birth defects. However, we do not conduct routine analysis for all
listed materials.
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